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American Journal of Physics

Relationship of the commutation rules to classical-like representations of quantum angular momenta addition

A. Morales, Alejandro Amaya-Tapia

Published Nov 1, 1999• 0 citations
Publisher

Abstract

We perform an analysis of a graphical representation for the addition of two angular momenta, focusing our attention on the angle δ between the xy components of two angular momenta. Then we propose a new complete set of commuting observables, which differ from the usual sets that are connected by the Clebsch–Gordan coefficients. This set shows that the angle δ can be a well-defined variable in quantum mechanics. An empirical analysis of the graphical representations of the angular momenta relations, which may include the angle δ, followed by quantum mechanical considerations, leads to the vanishing of certain quantum angular momentum commutators for specific states. Therefore, although the commutators are not null in general, the quantum addition of angular momenta may be represented using classical-like diagrams.

DOI
10.1119/1.19177

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We perform an analysis of a graphical representation for the addition of two angular momenta, focusing our attention on the angle δ between the xy components of two angular momenta. Then we propose a new complete set of commuting observables, which differ from the usual sets that are connected by the Clebsch–Gordan coefficients. This set shows that the angle δ can be a well-defined variable in quantum mechanics. An empirical analysis of the graphical representations of the angular momenta relations, which may include the angle δ, followed by quantum mechanical considerations, leads to the vanishing of certain quantum angular momentum commutators for specific states. Therefore, although the commutators are not null in general, the quantum addition of angular momenta may be represented using classical-like diagrams.
This chapter discusses the addition of angular momenta in the physicist’s way. From the considerations it follows that there are several ways to construct complete systems of commuting angular momentum observables. Belonging to two complete sets (two different ‘couplings’) of commuting angular momentum observables, there must exist a unitary transformation. For more than two angular momenta there will be more sets and more unitary transformations between the different couplings. The matrix elements of these transformations are called ‘recoupling coefficients’. They can be expressed by sums over products of Clebsch-Gordan coefficients (CGCs); this is to be expected from the fact that repeated coupling of two angular momenta generates any desired coupling scheme. It also is to be expected that the transformations between different coupling schemes become rapidly more complicated with growing numbers of subsystems. A powerful and elegant graphical representation for CGCs exists which can be used in the calculations of coupling of angular momenta.
Abstract Angular momentum in classical mechanics is given by a vector. The plane perpendicular to this vector, in accordance to central field theory, determines the space in which particle motion takes place. No such simple picture exists in quantum mechanics. The states of a particle in a central field are proportional to spherical harmonics which do not define any plane of motion. In the first part of this paper we discuss the angular distribution of particle position and compare it to the classical probabilistic approach. In the second part, the matter of addition of angular momenta is discussed. In classical mechanics this means addition of vectors, while in quantum mechanics Clebsch–Gordan coefficients have to be used. We have found classical approximations to quantum coefficients and the limit of their applicability. This analysis gives a basis for the so-called ‘vector addition model’ used in some elementary textbooks on atomic physics. It can help to better understand the addition of angular momenta in quantum mechanics.
The addition theorem of angular momentum states that the angular momentum operator of a coupled state is the vector sum of the angular momentum operators of the uncoupled states. Given that, the eigenfunction of the angular momentum of a system in the coupled state can be represented as a linear combination of eigenfunctions of the system in its uncoupled state and, in turn, the eigenfunctions of the uncoupled state are a direct product of eigenfunctions of the individual particles. Clebsch-Gordan coefficients emerge as an overlap integral in the series expansion of the coupled state in the basis of uncoupled states. This chapter provides a detailed derivation of the addition theorem of angular momentum, including obtaining the lower and upper boundaries of the quantum numbers, deriving the orthonormality conditions for Clebsch-Gordan coefficients, and using shift operators to generate the members of a multiplet. It also derives a general expression for the evaluation of Clebsch-Gordan coefficients, provides a detailed analysis of the addition of angular momenta and electron spin to build the resulting Clebsch-Gordan matrix, and shows that a rotation transformation of the direct product of eigenfunctions of the angular momentum and spin leads to the recurrence relations for the Wigner matrix.
We extend the canonical commutation relations (CCR) in quantum mechanics to the case where appropriate dynamical variables are angular momenta and angles. It is found that projection operators of the resultant Weyl algebra provide us with a new and powerful way of characterizing minimum-uncertainty states, including those obtained by Carruthers and Nieto. The uniqueness theorem of the Schr\"odinger representation remains valid for extended CCR in a simple case. Finally, a wide range of applicability of our method is suggested.
This chapter presents key results on angular momentum in quantum mechanics, beginning with a theorem on the simultaneous diagonalization of commuting operators. The eigenvalues and eigenstates of both the total angular momentum operator and its z-component are derived. For a quantum rotator in the p-state with zero magnetic quantum number, it is shown that the most probable trajectory lies in a plane containing the z-axis, and the angular momentum vector is perpendicular to it. The procedure for angular momentum addition is explained in detail, including the use of Clebsch–Gordan coefficients to perform the explicit decomposition of tensor products of irreducible representations. The Bloch sphere representation of qubit spin states is introduced. The chapter then provides an experimental background to the discovery of spin, introduces the Pauli matrices, and demonstrates how they act on spin states. It concludes with the formulation of the Pauli equation, which incorporates spin into the framework of nonrelativistic quantum mechanics. Metadata/Keywords: angular momentum, simultaneous diagonalization, magnetic quantum number, Clebsch–Gordan coefficients, spin, Pauli matrices, Bloch sphere, spin states, tensor product, Pauli equation
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.