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Journal of Physics A Mathematical and General

The operator method of the approximate description of the quantum and classical systems

И. Д. Феранчук, L I Komarov

Published Nov 11, 1984• 30 citations
Publisher

Abstract

Systematic theory of the operator method (OM) of the approximate solution of the Schrodinger equation is considered. The eigenfunctions and eigenvalues for various one- and many-dimensional systems are calculated and the arguments of the convergence of the OM perturbation series are discussed. It is also shown that OM permits one to develop the absolute convergent approximation in the theory of nonlinear oscillations of the classical systems.

DOI
10.1088/0305-4470/17/16/014

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Systematic theory of the operator method (OM) of the approximate solution of the Schrodinger equation is considered. The eigenfunctions and eigenvalues for various one- and many-dimensional systems are calculated and the arguments of the convergence of the OM perturbation series are discussed. It is also shown that OM permits one to develop the absolute convergent approximation in the theory of nonlinear oscillations of the classical systems.
Nonperturbative method for description of quantum systems - the operator method (OM) \nand the conception of the uniformly suitable estimation (USE) are considered for the series of real physical systems. It is shown that the OM zeroth-order approximation permits one to find the analytical approximation for eigenfunctions and eigenvalues with high accuracy \nwithin the entire range of the Hamiltonian parameters and any quantum numbers. The \nOM subsequent approximations converge rapidly to the exact solutions of the Schrödinger equation. The generalization of OM for the quantum statistics is also developed.
The starting point in a quantum mechanical problem is the construction of a Schrödinger equation. We try to solve it exactly to obtain wave function. A Schrödinger equation is exactly solvable only for a certain number of simple potentials. In most of the cases the Schrödinger equation cannot be solved exactly. The solution of the Schrödinger equation for the real systems is usually complicated and often exact solutions are very difficult to find or solutions not exist. Examples include as anharmonic oscillator, hydrogen atom in an electric field, a plane rotator in the presence of an applied electric field and so on. Therefore, we need to rely on approximation methods. The simple and most interesting and powerful approximate method is the perturbation theory developed by Schrödinger in 1926 [1]. Earlier Lord Rayleigh [2] analysed harmonic vibrations of a string perturbed by small inhomogeneities. The work of Rayleigh was pointed out by Schrödinger. Consequently, the method is also called Rayleigh-Schrödinger perturbation theory. This method is powerful for determining the changes in the discrete energy values and the associated eigenfunctions of a system due to a weak perturbation, provided the eigenpairs of the undisturbed system are available. The approximations obtained from the perturbation theory are used to calculate energy level diagrams and to understand the splitting and assignments of atomic and molecular spectra [35]. The perturbation theory has been proven to be useful in several fields of theoretical physics and also in chemistry. It provides considerable insight into various phenomena. The main disadvantage of this method is that in certain problems the perturbation series converges slowly or diverges.
Abstract The theory of perturbations of electronic systems has been considered by various writers, and the method is the basis of the solution of most quantum problems. It therefore seems desirable that the theory should be placed on a firm footing, and this necessitates the discussion of the convergence of the series of perturbations, which up to the present has been avoided. This investigation is all the more necessary since the wave equation of the Stark Effect has no solution of the form assumed by Schrödinger in his original discussion of the perturbation theory. Dirac’s theory leads to a system of linear differential equations in an infinite number of variables, and 2 is devoted to the discussion of the existence theorem for such a system by a matrix method. In 3 the application is made to the perturbation theory in the case of perturbations satisfying the conditions assumed in 2. In 4 the theory is extended so as to include more general types of disturbances. It is shown that, though the series of perturbations does not in general converge, yet it usually possesses the same asymptotic character as in the classical theory, and its use can therefore be justified.
A new approach to the eigenvalue problem in quantum mechanics is proposed. This approach is based on three propositions: 1) a perturbation theory which does not require knowledge of the entire eigenvalue spectrum of the unperturbed problem and which uses a nonlinearization procedure (leaving some latitude in the choice of a zeroth order approximation); 2) a relationship between the perturbation theory and a variational principle, namely that any variational calculation is none other than the first two terms of some nontrivial perturbation theory which, when developed further, can reveal the accuracy of the variational calculations and can refine them by an iterative procedure; 3) Dyson's argument, which serves as a criterion for the reasonableness of the choice of a zeroth order approximation (the unperturbed problem). The realization of this perturbation theory in a k-dimensional space is equivalent to the solution of a k-dimensional electrostatic problem with a variable dielectric permittivity. In the one-dimensional case and in cases which reduce to the one-dimensional case, all the corrections are written in quadratures. It is shown that the construction of an ordinary perturbation theory (in which the zeroth order approximation is an exactly solvable problem) within the framework of this perturbation theory is a purely algebraic procedure, which reduces to the solution of some simple recurrence relations. An approximation analogous to the leading logarithmic approximation of quantum field theory is constructed. Some standard problems of quantum mechanics—the anharmonic oscillator, the Zeeman effect, and the Stark effect—are treated as examples. It is shown that this new approach makes it possible to develop systematically a theory for strong coupling and large perturbations.
Abstract We consider the Schrödinger equation with pseudo-Gaussian potential and point out that it is basically made up by a term representing the harmonic oscillator potential and an additional term, which is actually a power series that converges rapidly. Based on this observation the system can be considered as a perturbation of harmonic oscillator. The perturbation method is used to approximate the energy levels of pseudo- Gaussian oscillator. The results are compared with those obtained in the analytic and numeric case.
We obtain a complete series solution of stationary Schrödinger's equation in the general quantum systems. It is exact in the sense that any approximation means is not used, or that the whole corrections or contributions from all order perturbations are involved if the perturbation concept is introduced. Furthermore, the useful forms of our exact solution and a new expression the complete Green operator are given out. As a universal and analytical solution, it is helpful for the theoretical derivations and practical calculations in quantum theory.