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Physical Review A

Energy shifts of bound states in strong radiation fields

Ju Gao, Dong‐Sheng Guo

Published Jun 1, 1993• 4 citations
Publisher

Abstract

By applying a Lie-algebra method [Phys. Rev. A 42, 4302 (1990); 47, 5213(E) (1993)], we obtain analytical solutions and energy eigenvalues for a charged harmonic oscillator interacting with a single-mode photon field. The energy shifts of bound states of the harmonic oscillator due to the radiation field is also derived. By a variational method, we show that any bound state in a central potential which satisfies a power law can be treated as a harmonic oscillator around its average radial position. With this idea, we generalize the energy-shift formula obtained for a harmonic oscillator to the hydrogen-atom case. Our result shows that the energy shifts depend on the principal quantum number according to an inverse-square law.

DOI
10.1103/physreva.47.5080

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By applying a Lie-algebra method [Phys. Rev. A 42, 4302 (1990); 47, 5213(E) (1993)], we obtain analytical solutions and energy eigenvalues for a charged harmonic oscillator interacting with a single-mode photon field. The energy shifts of bound states of the harmonic oscillator due to the radiation field is also derived. By a variational method, we show that any bound state in a central potential which satisfies a power law can be treated as a harmonic oscillator around its average radial position. With this idea, we generalize the energy-shift formula obtained for a harmonic oscillator to the hydrogen-atom case. Our result shows that the energy shifts depend on the principal quantum number according to an inverse-square law.
The interaction of an atomic system with a single mode of a quantized electromagnetic field is investigated in the dipole approximation. Two approximations that are almost always made in this analysis are the neglect of the diamagnetic term in the Hamiltonian and the dropping of the rotating-wave approximation (RWA) terms that correspond to processes that do not conserve energy. Both approximations involve the neglect of terms that are of the same order of magnitude so that consistency demands that they be considered together. It is demonstrated that, in the dipole approximation, a minor modification of the usual application of quantum electrodynamics to any atomic system can exactly incorporate the effects of the diamagnetic term into a new frequency of the electromagnetic cavity mode; this frequency is slightly different from that of the empty cavity. This result is then applied to the specific case of a charged harmonic oscillator interacting with a single mode. For this simple model an analytic solution can then be found that includes the effects of the diamagnetic term and does not use the RWA. It is found that, for off resonance, the normal modes of the coupled system oscillate at shifted frequencies which are in agreement with the second-order perturbation-theory calculation of the Lamb shift. When the cavity mode is tuned to the atomic oscillator frequency, the perturbation-theory Lamb-shift calculation is no longer valid, and the exact solution derived in this paper predicts a resonant Lamb shift that is significantly larger than the off-resonant single-mode Lamb shift. Furthermore, the frequency spectrum is qualitatively changed from the single frequency of the free atomic system to a doublet spectrum. An analytic solution of this harmonic-oscillator problem can also be found when the RWA terms are dropped from the Hamiltonian. Comparison of the two solutions reveals that the RWA terms contribute a frequency shift of magnitude independent of the field intensity in the simple case of a charged harmonic oscillator.When trajectories of the exact and RWA solutions are compared in phase space, it is found that one effect of the RWA terms is to lift a twofold degeneracy of the phase-space orbits that occurs when the RWA terms are neglected. The harmonic-oscillator problem has several features in common with the interaction of a two-level atom with a single quantized field mode. Both Hamiltonians exhibit inversion symmetry and hence have parity as a good quantum number. Both Hamiltonians contain RWA terms. When these RWA terms are neglected, both Hamiltonians have a new constant of motion that can be identified with the total number of excitations in the combined system.
Although the problem of electromagnetic radiation by a quantum harmonic oscillator is considered in textbooks on quantum mechanics, some of its aspects have remained unclear until now. By this, we mean that usually the initial quantum states of both the oscillator and the field are assumed to be characterized by a definite energy level of the oscillator and definite occupation numbers of the field modes. In connection with growing interest in squeezed states, it would be interesting to analyze the general case when the initial states of both subsystems are arbitrary superpositions of energy eigenstates. This problem was considered in other work, where the power of the spontaneous emission was calculated in the case of an arbitrary oscillator's initial state, but the field was initially in a vacuum state. In the present article, we calculate the rate of the oscillator average energy, squeezing, and correlation parameter change under the influence of an arbitrary external radiation field. Some other problems relating to the interaction between quantum particles (atoms) or oscillators where the electromagnetic radiation is an arbitrary (in particular squeezed) state were investigated.
The behavior of a nonlinear oscillator (NO) coupled to a radiation field is investigated. The NO considered is an angular momentum oscillator, of energy $\ensuremath{\hbar}\ensuremath{\omega}{L}_{3}$, that describes the collective effect of a number of identical two-level (or spin-\textonehalf{}) systems under given idealized conditions, a large total angular momentum quantum number L0{L}_{0}L0​ corresponding to a large number of two-level systems. The field is described by a set of modes. Free decay---with the NO initially excited and the radiation field in the ground state---and forced oscillation---with the NO subject to a prescribed resonant driving field---are studied. The analysis is performed both classically and quantum mechanically, using the classical and Heisenberg equations of motion, respectively, so as to display explicitly the difference in the results. Interest in the comparison between the two formalisms is motivated by the expectation that for large L0{L}_{0}L0​, the NO should behave essentially classically, except near its highest-energy state in the absence of a driving field. The general equations of motion are reduced to equations for the NO variables only. In the classical analysis of free decay, expressions for the energy and oscillating coordinates are derived. The decay time is shown to approach infinity as L3(0){L}_{3}(0)L3​(0) approaches L0{L}_{0}L0​ (the limiting condition being that of unstable equilibrium) and the radiative frequency shift is shown to be approximately proportional to L3(t){L}_{3}(t)L3​(t). It is also shown that use of the rotating-wave approximation alters qualitatively the expression for the frequency shift. In the classical analysis of forced oscillation, approximate results are obtained for a weak driving field and a strong driving field, the NO being initially in the ground state. The weakfield results exhibit a monotonic approach of L3(t){L}_{3}(t)L3​(t) to a constant (negative) value---or steady state---at which the power absorbed equals the power radiated; in the strong-field case, L3(t){L}_{3}(t)L3​(t) oscillates periodically between the limits $\ifmmode\pm\else\textpm\fi{}{L}_{0}$, the coupling to the radiation field having negligible effect on the frequency of this oscillation. In the quantum-mechanical analysis, the equations of motion become simplified for L0=12{L}_{0}=\frac{1}{2}L0​=21​, and this case is treated first. The free-decay results are essentially similar to those of the Weisskopf-Wigner theory, exhibiting an exponential decay of 〈L3(t)〉〈{L}_{3}(t)〉〈L3​(t)〉 and a radiative frequency shift in the oscillating coordinates. Under forced oscillation, with $〈{L}_{3}(0)〉=\ensuremath{-}{L}_{0}, 〈{L}_{3}(t)〉$ approaches a constant value either monotonically, if the driving field is sufficiently weak, or by means of a damped oscillation, if the driving field is strong. For L0>12{L}_{0}>\frac{1}{2}L0​>21​, the free decay is treated by a method that involves the derivation of a set of expressions for the kthk\mathrm{th}kth derivative of 〈L3(t)〉〈{L}_{3}(t)〉〈L3​(t)〉 as an expectation value of a polynomial in L3{L}_{3}L3​ of order k+1k+1k+1. This set, together with the eigenvalue equation for L3{L}_{3}L3​, is shown to lead to a solution for all the moments of L3{L}_{3}L3​. The method is used to obtain complete solutions for several low values of L0{L}_{0}L0​, and also to obtain initial derivatives of 〈L3(t)〉〈{L}_{3}(t)〉〈L3​(t)〉 as polynomials in L0{L}_{0}L0​ for 〈L3(0)〉=L0〈{L}_{3}(0)〉={L}_{0}〈L3​(0)〉=L0​. For large L0{L}_{0}L0​, a comparison of classical and quantum-mechanical equations shows that only the condition $〈{L}_{3}(0)〉\ensuremath{\approx}{L}_{0}$ requires quantum-mechanical treatment, and that for a short time only. The free-decay problem with initial condition 〈L3(0)〉=L0〈{L}_{3}(0)〉={L}_{0}〈L3​(0)〉=L0​ solved quantum mechanically up to such a time t1{t}_{1}t1​ by means of the initial derivatives previously derived, and then this solution if used to provide initial conditions determining a classical solution for $t\ensuremath{\ge}{t}_{1}$. The statistical aspects introduced by the quantum mechanics are preserved in the classical solution, and their significance is discussed, with several examples, comparison is also made with a nonstatistical approximation. In the case of forced oscillation, the behavior of 〈L3(t)〉〈{L}_{3}(t)〉〈L3​(t)〉---for arbitrary L0{L}_{0}L0​---is examined in detail for a strong field, and turns out to be described by a damped oscillation, the existence of the damping being independent of L0{L}_{0}L0​. The apparent inconsistency of this result with the expectation that a large system subject to strong forces should behave classically is discussed, and 〈L23(t)〉〈{L}_{2}^{3}(t)〉〈L23​(t)〉 is examined. It is concluded that in a single experiment, the NO energy oscillates approximately like the classical energy, without damping; quantum mechanics introduces, however, a slight randomness (or unpredictability) in the frequency of this oscillation, because of the coupling with the radiation field. Since 〈L3(t)〉〈{L}_{3}(t)〉〈L3​(t)〉 describes the average over an ensemble of which each member consists of a NO coupled to a radiation field, the random frequency variation among the members accounts for the damping of the average. The usefulness of the combination of classical and quantum-mechanical analyses in achieving and interpreting theoretical results for a class of phenomena involving the collective interaction between a number of atoms and a radiation field is pointed out.
Here a special case of perturbation in quantum harmonic oscillator is studied. Here we assume the perturbed potential to be a Harmonic Oscillator that has been shifted in the position space.We construct the new creation and annihilation operators for the new Hamiltonian to find out its energy eigenstates. What is interesting about the solution of this system is that we find out that the ground state of this system is a coherent state of the ground state of the original harmonic oscillator. We know that the Hamiltonian of electromagnetic field is similar to that of the harmonic oscillator where the electric field and magnetic field are expressed in terms of time evolution of annihilation and creation operators. According to the quantum electromagnetic field theory, photon states are expressed as the coherent states of the ground states of the unperturbed harmonic oscillator.In the previous research works,it has been established how coherent states provide a better picture of Electric field compared to the energy eigenstates. This paper mainly deals with why the coherent states provide a more complete picture of electric and magnetic field theory compared to just energy eigenstates. Here we find how our perturbation act as a coherent state generator and adds a new term in the Hamiltonian. The Perturbation is thought to arise from the only available interaction i.e. observation. The perturbation also explains how observation leads to coherence of photon states. We will find out how the new perturbation affects the time evolution of electromagnetic field. This also explains how the classical electromagnetic field theory takes into account the factor of observation, due to which the classical laws are in perfect agreement with the quantum laws.
The interaction of electrons with strong laser fields is usually treated with semiclassical theory, where the laser is represented by an external field. There are analytic solutions for the free electron wave functions, which incorporate the interaction with the laser field exactly, but the joint effect of the atomic binding potential presents an obstacle for the analysis. Moreover, the radiation is a dynamical system, the number of photons changes during the interactions. Thus, it is legitimate to ask how can one treat the high order processes nonperturbatively, in such a way that the electron-atom interaction and the quantized nature of radiation be simultaneously taken into account? An analytic method is proposed to answer this question in the framework of nonrelativistic quantum electrodynamics. As an application, a quantum optical generalization of the strong-field Kramers-Heisenberg formula is derived for describing high-harmonic generation. Our formalism is suitable to analyse, among various quantal effects, the possible role of arbitrary photon statistics of the incoming field. The present paper is dedicated to the memory of Prof. Dr. Fritz Ehlotzky, who had significantly contributed to the theory of strong-field phenomena over many decades.