We show that the leading low-temperature behavior of the nth cluster coefficient bn can be calculated without sloving the n-body problem, and that there is a lnT term in the expansion. We illustrate these results particularly for the case of b3.
The quantum theory of the third virial coefficient C is discussed. Three types of intermolecular pair forces must be distinguished. (1) No bound or low-lying two- and/or three-body states exist. The first four terms of the low-temperature expansion of CBE are obtained. They depend on the scattering length, the effective range, and a third length which cannot be inferred from scattering data. The limitations of the applicability of such expansions are discussed, both for He4 and He3, by means of a comparison of the corresponding expansion for the second virial coefficient B with detailed numerical results known for specific potentials. (2) Existence of a near zero energy level both for the two- and the three-body system. It is shown how in this case the actual potentials may be replaced by suitably matched boundary conditions on the two- and the three-body wave functions near the respective coordinate origins. It is first explained how the method applies to B. Then the leading term of C is explicitly determined. (3) Existence of strongly bound two- and three-body states. An approximate expression for C is given by treating the single atoms and the binary and ternary compounds as a system of three ideal gases in chemical equilibrium.
Quantum corrections to the properties of a homogeneous interacting Bose gas at zero temperature can be calculated as a low-density expansion in powers of ρa3, where ρ is the number density and a is the S-wave scattering length. We calculate the ground state energy density to second order in ρa3. The coefficient of the ρa3 correction has a logarithmic term that was calculated in 1959. We present the first calculation of the constant under the logarithm. The constant depends not only on a, but also on an extra parameter that describes the low energy 3→3 scattering of the bosons. In the case of alkali atoms, we argue that the second order quantum correction is dominated by the logarithmic term, where the argument of the logarithm is ρaℓV2, and ℓV is the length scale set by the van der Waals potential.