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Chemical Physics Letters

Dynamics of minimum energy uncertainty gaussian wave packets in non-harmonic bound systems

Jürgen Brickmann, Peter Russegger

Published Jun 1, 1982• 9 citations
Publisher
DOI
10.1016/0009-2614(82)80049-3

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American Journal of Physics•Jan 12, 2010•2 citations
We derive closed form expressions of weak relativistic corrections to the wave-packet dynamics of the quantum harmonic oscillator within a perturbative framework. General expressions are derived for the leading-order relativistic contributions to wave-packet parameters, such as the time-dependent widths, variances, and uncertainty relations. Specific calculations are performed for unsqueezed, minimum-uncertainty Gaussian wave packets, valid up to leading order in (1/c21/c^{2}1/c2). When applied to electron wave packets, the results indicate that relativistic effects become non-negligible for keV-scale harmonic confinement energies: the deviations in variances reach 0.15%−1.5%0.15\% - 1.5\%0.15%−1.5% for an electron wave packet confined within the 1−10keV1-10 \mathrm{keV}1−10keV energy range. We also show that the standard saturation of the uncertainty relation remains unaffected by the leading-order relativistic effect.
I reexamine Heisenberg’s uncertainty relation for two- and three-dimensional wave packets with fixed angular momentum quantum numbers m or ℓ. A simple proof shows that the product of the average extent Δr and Δp of a two-dimensional wave packet in position and momentum space is bounded from below by ΔrΔp≥ℏ(|m|+1). The minimum uncertainty is attained by modified Gaussian wave packets that are special eigenstates of the two-dimensional isotropic harmonic oscillator, which include the ground states of electrons in a uniform magnetic field. Similarly, the inequality ΔrΔp≥ℏ(ℓ+3/2) holds for three-dimensional wave packets with fixed total angular momentum ℓ and the equality holds for a Gaussian radial profile. I also discuss some applications of these uncertainty relations.