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Physical Review

Quasi-Classical Theory of the Nonspinning Electron

Ralph Schiller

Published Feb 1, 1962• 89 citations
Publisher

Abstract

We develop a modified Hamiltonian-Jacobi theory of classical mechanics following the early work of Van Vleck. This modified Hamiltonian-Jacobi theory, or quasi-classical theory, permits us to exhibit in classical mechanics many features that in the past have been exclusively associated with quantum mechanics. We deal with classical wave functions, classical operators, classical "eigenvalue" equations, a classical "sum over paths" formulation of classical mechanics, and with classical creation and destruction operators. Following Van Vleck, one can derive the WKB approximate solutions to the Schr\"odinger equation from the solutions of the classical Hamilton-Jacobi equation. If we apply the methods of Keller to the nonrelativistic and relativistic Kepler problem, we derive eigenvalues from the requirement of single-valuedness imposed on the WKB solutions. It turns out that the energy eigenvalues are those given by the Schr\"odinger equation and the Klein-Gordon equation, respectively. In the particular case of the harmonic oscillator there exists a canonical transformation which transforms the quasi-classical equation into an exact equation of quantum mechanics. We conjecture that if the WKB approximation and the Schr\"odinger equation predict the same eigenvalues, then there always exists a canonical transformation which transforms the quasi-classical equation into the corresponding Schr\"odinger equation. Finally we derive the quasi-classical equations in momentum space.

DOI
10.1103/physrev.125.1100

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We develop a modified Hamiltonian-Jacobi theory of classical mechanics following the early work of Van Vleck. This modified Hamiltonian-Jacobi theory, or quasi-classical theory, permits us to exhibit in classical mechanics many features that in the past have been exclusively associated with quantum mechanics. We deal with classical wave functions, classical operators, classical "eigenvalue" equations, a classical "sum over paths" formulation of classical mechanics, and with classical creation and destruction operators. Following Van Vleck, one can derive the WKB approximate solutions to the Schr"odinger equation from the solutions of the classical Hamilton-Jacobi equation. If we apply the methods of Keller to the nonrelativistic and relativistic Kepler problem, we derive eigenvalues from the requirement of single-valuedness imposed on the WKB solutions. It turns out that the energy eigenvalues are those given by the Schr"odinger equation and the Klein-Gordon equation, respectively. In the particular case of the harmonic oscillator there exists a canonical transformation which transforms the quasi-classical equation into an exact equation of quantum mechanics. We conjecture that if the WKB approximation and the Schr"odinger equation predict the same eigenvalues, then there always exists a canonical transformation which transforms the quasi-classical equation into the corresponding Schr"odinger equation. Finally we derive the quasi-classical equations in momentum space.
The quasi-classical theory is the theory of the WKB approximation as defined by Van Vleck. This approximate wave theory is invariant under canonical transformations. We derive the transformation laws for wave functions and operators in this theory. The connection problem of the ordinary configuration space is discussed from the point of view of Van Vleck. The usual method of WKB quantization is then contrasted with another method of quantization in a classical configuration space of creation and destruction operators. In this new configuration space we find that, for some problems, the quasi-classical solutions are exact solutions of the Schr\"odinger equation. Finally, we show that the canonical transformations of the quasi-classical theory may be put into one-to-one correspondence with a group of approximate unitary transformations.
The quasi-classical spin theory is a modified Hamilton-Jacobi theory for a classical relativistic dipole whose space-time trajectory is coupled to its spin motion. The equations of this quasi-classical theory are almost identical with the second-order (squared) Dirac equation, and, in fact, form a new WKB approximation to the second-order Dirac equation. We quantize this theory by requiring that a classical spinor "wave function" be continuous and single valued, and that it satisfy an eigenvalue equation. We find for a particle in a uniform magnetic field, and in a Coulomb field, that this quasi-classical theory predicts the same energy and angular momentum eigenvalues as the Dirac theory. The quasi-classical theory is invariant under Lorentz transformation, spin rotations, and charge conjugation. The spinor wave functions are form invariant with respect to arbitrary canonical transformations.
We derive a modified Hamilton-Jacobi theory for a classical spinning dipole and show that this classical theory can be put in a form almost identical with the Pauli spin theory. We quantize this theory by requiring that a classical spinor "wave function" be continuous and single-valued, and that it satisfy the usual energy eigenvalue equation. In this manner we deduce the correct energy levels for a hydrogen atom in an external magnetic field. We derive the integral kernel for the Pauli equation from this classical model and discuss the properties of our spinor solutions under canonical transformation. We exhibit the charge-conjugate solution to the classical spin equation.
In this paper, we develop quantum mechanics of quasi-one-dimensional systems upon the framework of the quantum-mechanical Hamilton–Jacobi theory. We will show that the Schrödinger point of view and the Hamilton–Jacobi point of view are fully equivalent in their description of physical systems, but differ in their descriptive manner. As a main result of this, a wavefunction in Hamilton–Jacobi theory can be decomposed into travelling waves in any point in space, not only asymptotically. Using the quasi-linearization technique, we derive quantum correction functions in every order of . The quantum correction functions will remove the turning-point singularity that plagues the WKB-series expansion already in zeroth order and thus provide an extremely good approximation to the full solution of the Schrödinger equation. In the language of quantum action it is also possible to elegantly solve the connection problem without asymptotic approximations. The use of quantum action further allows us to derive an equation by which the Maslov index is directly calculable without any approximations. Stationary quantum trajectories will also be considered and thoroughly discussed.
Hamilton-Jacobi theory is a fundamental subject of classical mechanics and has also an important role in the development of quantum mechanics. Its conceptual framework results from the advantages of transformation theory and, for this reason, relates to the features of the generating function of canonical transformations connecting a specific Hamiltonian H to a new Hamiltonian K chosen to simplify Hamilton's equations of motion. Usually, the choice is between K=0 and a cyclic K depending on the new conjugate momenta only. Here, we investigate more general representations of the new Hamiltonian. Furthermore, it is pointed out that the two common alternatives of K=0 and a cyclic K should be distinguished in more detail. An attempt is made to clearly discern the two regimes for the harmonic oscillator and, not surprisingly, some correspondences to the quantum harmonic oscillator appear. Thanks to this preparatory work, generalized coordinates and momenta associated with the Hamilton's principal function S (i.e., K=0) are used to determine dependences in the Hamilton's characteristic function W (i.e., cyclic K). The procedure leads to the Schrodinger's equation where the Hamilton's characteristic function plays the role of the Schrodinger's wave function, whereas the first integral invariant of Poincare' takes the place of the reduced Planck constant. This finding advances the pedagogical value of the Hamilton-Jacobi theory in view of an introduction to Schrodinger's wave mechanics without the tools of quantum mechanics.