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Zeitschrift für Physik D Atoms Molecules and Clusters

Theoretical study of Na(4p2P) + Na(3s2S) and Cd(5p3P0) + Na(3s2S) collisions and their role in the energy transfer between Cd.* and Na

S. Magnier, Celestino Angeli, Giovanni Granucci, Françoise Masnou-Seeuws, M. Allegrini, Maurizio Persico

Published Dec 1, 1997• 2 citations
Publisher
DOI
10.1007/s004600050136

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Article

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Transfer of excitation from cadmium to sodium atoms was investigated in anheat pipe oven illuminated by a pulsed laser tuned on the intercombinationtransition of cadmium. A rich emission spectrum with cadmium as well assodium lines was observed. Intramultiplet mixing distributes the initialexcited level population 5p3P1 to the nearby fine structurelevels 5p3P0,2 of the same multiplet. We have experimentalevidence that the energy transfer pathway is from Cd (5p3PJ) to Na(4p2PJ) which is collisionally rapidly converted toNa(3d2DJ), from which the strongest emission was observed.PACS No.: 34.90+q

Canadian Journal of Physics•Oct 1, 1998•0 citations
Transfer of excitation from cadmium to sodium atoms was investigated in anheat pipe oven illuminated by a pulsed laser tuned on the intercombinationtransition of cadmium. A rich emission spectrum with cadmium as well assodium lines was observed. Intramultiplet mixing distributes the initialexcited level population 5p3P1 to the nearby fine structurelevels 5p3P0,2 of the same multiplet. We have experimentalevidence that the energy transfer pathway is from Cd (5p3PJ) to Na(4p2PJ) which is collisionally rapidly converted toNa(3d2DJ), from which the strongest emission was observed.PACS No.: 34.90+q