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Annalen der Physik

Crossover from BCS‐superconductivity to Bose‐condensation

M. Drechsler, W. Zwerger

Published Jan 1, 1992• 175 citations
Publisher

Abstract

Abstract Starting from a model of free Fermions in two dimensions with an arbitrary strong effective interaction, we derive a Ginzburg‐Landau theory describing the crossover from BCS‐superconductivity to Bose‐condensation. We find a smooth crossover from the standard BCS‐limit to a Gross‐Pitaevski type equation for the order parameter in a Bose superfluid. The mean field transition temperature exhibits a maximum at a coupling strength, where the behaviour crosses over from BCS to Bose like with corresponding values of 2 Δ0/Tc ≈ 5 which are characteristic for high Tc superconductors.

DOI
10.1002/andp.19925040105

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Abstract Starting from a model of free Fermions in two dimensions with an arbitrary strong effective interaction, we derive a Ginzburg‐Landau theory describing the crossover from BCS‐superconductivity to Bose‐condensation. We find a smooth crossover from the standard BCS‐limit to a Gross‐Pitaevski type equation for the order parameter in a Bose superfluid. The mean field transition temperature exhibits a maximum at a coupling strength, where the behaviour crosses over from BCS to Bose like with corresponding values of 2 Δ0/Tc ≈ 5 which are characteristic for high Tc superconductors.
We generalize the standard attractive Hubbard, having an on-site pair creation operator Qi = ai|ai|, to one with n components Qiα = aiα|aiα|, a = 1, 2, ... , n.In the limit n -> co we obtain the Ginzburg-Landau functional.On this basis we explore the crossover from weak (BCS) to strong coupling (Bose-Einstein condensation) superconductivity.The associated self-consistent equations for the Ginzburg-Landau parameters are similar to those of the T-matrix approach.The evolution of the band structure with increasing interaction strength is studied and correlated with the behavior of the pair propagator and the transition temperature.We find that the pairing interaction creates a new band which moves downwards in energy as the interaction strength increases and separates into a lower Hubbard band when the interaction strength becomes comparable to the band width.In the strong coupling regime, a third band with small spectral weight is also found in between the lower and upper Hubbard bands.
A standard perturbative expansion around the mean-field solution is used to derive the low-energy effective action for superconductors at T=0.T=0.T=0. Taking into account the density fluctuations at the outset we get the effective action where the density $\ensuremath{\rho}$ is the conjugated momentum to the phase $\ensuremath{\theta}$ of the order parameter. In the hydrodynamic regime, the dynamics of the superconductor is described by a time-dependent nonlinear Schr\"odinger (TDNLS) equation for the field $\ensuremath{\Psi}(x)=\sqrt{\ensuremath{\rho}/2}{e}^{i\ensuremath{\theta}}.$ The evolution of the density fluctuations in the crossover from weak-coupling (BCS) to strong-coupling (Bose condensation of localized pairs) superconductivity is discussed for the attractive Hubbard model. In the bosonic limit, the TDNLS equation reduces to the Gross-Pitaevskii equation for the order parameter, as in the standard description of superfluidity. The conditions under which a phase-only action can be derived in the presence of a long-range interaction to describe the physics of the superconductivity of ``bad metals'' are discussed.
We use a functional integral formulation to study the finite temperature crossover from cooperative Cooper pairing to independent bound state formation and condensation. We show the inadequacy of mean field results for normal state properties obtained at the saddle point level as the coupling increases. The importance of quantum (temporal) fluctuations is pointed out and an interpolation scheme for Tc{\mathit{T}}_{\mathit{c}}Tc​ is derived from this point of view. The time-dependent Ginzburg-Landau (TDGL) equation near Tc{\mathit{T}}_{\mathit{c}}Tc​ is shown to describe a damped mode in the BCS limit, and a propagating one in the Bose limit. A singular point is identified at intermediate coupling where a simple TDGL description fails.
For the Cooper/BCS model interaction in superconductors (SCs) it is shown: a) how BCS-Bose crossover picture transition temperatures Tc, defined self-consistently by both the gap and fermion-number equations, require unphysically large couplings to differ significantly from the Tc of ordinary BCS theory defined without the number equation since here the chemical potential is assumed equal to the Fermi energy; how although ignoring either hole- or electron-Cooper-pairs in the recent "complete boson-fermion model": b) one obtains the precise BCS gap equation for all temperatures T, but c) only half the zero-temperature BCS condensation energy emerges. Results (b) and (c) are also expected to hold for neutral-fermion superfluids (SFs)--such as liquid 3^33He, neutron matter and trapped ultra-cold fermion atomic gases--where the pair-forming two-fermion interaction of course differs from the Cooper/BCS one for SCs.
We review the study of the superfluid phase transition in a system of fermions whose interaction can be tuned continuously along the crossover from Bardeen–Cooper–Schrieffer (BCS) superconducting phase to a Bose–Einstein condensate (BEC), also in the presence of a spin–orbit coupling. Below a critical temperature the system is characterized by an order parameter. Generally a mean field approximation cannot reproduce the correct behavior of the critical temperature Tc over the whole crossover. We analyze the crucial role of quantum fluctuations beyond the mean-field approach useful to find Tc along the crossover in the presence of a spin–orbit coupling, within a path integral approach. A formal and detailed derivation for the set of equations useful to derive Tc is performed in the presence of Rashba, Dresselhaus and Zeeman couplings. In particular in the case of only Rashba coupling, for which the spin–orbit effects are more relevant, the two-body bound state exists for any value of the interaction, namely in the full crossover. As a result the effective masses of the emerging bosonic excitations are finite also in the BCS regime.
The Ginzburg-Landau theory of a trapped Fermi gas with a BEC-BCS crossover is derived by the path-integral method. In addition to the standard Ginzburg-Landau equation, a second equation describing the total atom density is obtained. These two coupled equations are necessary to describe both homogeneous and inhomogeneous systems. The Ginzburg-Landau theory is valid near the transition temperature Tc{T}_{c}Tc​ on both sides of the crossover. In the weakly interacting BEC region, it is also accurate at zero temperature where the Ginzburg-Landau equation can be mapped onto the Gross-Pitaevskii (GP) equation. The applicability of GP equation at finite temperature is discussed. On the BEC side, the fluctuation of the order parameter is studied and the renormalization to the molecule coupling constant is obtained.