Euler angles often are used to describe the orientation of a secondary system rotated relative to a primary system by generating two auxiliary systems and the secondary with three rotations. We use basis vectors to show that the auxiliary systems of the y-convention Euler angles (used in quantum mechanics) are the cylindrical and spherical systems associated with the primary Cartesian system. We then apply Euler angle geometry to obtain an improved expression (and understanding) of the Wigner D-function addition theorem and related geometrical issues. We introduce helicity vectors and express vector spherical harmonics as combinations of Wigner D-functions to show that the D-function addition theorem is implicit within expansions of rotated vector spherical harmonics. As example applications of the Wigner D-function, we obtain an addition theorem for vector spherical harmonics and then simplify a dyadic Green function (related to Mie theory) describing inelastic light scattering from a laser-irradiated spherical droplet containing a fluorescing molecule.
Euler angles often are used to describe the orientation of a secondary system rotated relative to a primary system by generating two auxiliary systems and the secondary with three rotations. We use basis vectors to show that the auxiliary systems of the y-convention Euler angles (used in quantum mechanics) are the cylindrical and spherical systems associated with the primary Cartesian system. We then apply Euler angle geometry to obtain an improved expression (and understanding) of the Wigner D-function addition theorem and related geometrical issues. We introduce helicity vectors and express vector spherical harmonics as combinations of Wigner D-functions to show that the D-function addition theorem is implicit within expansions of rotated vector spherical harmonics. As example applications of the Wigner D-function, we obtain an addition theorem for vector spherical harmonics and then simplify a dyadic Green function (related to Mie theory) describing inelastic light scattering from a laser-irradiated spherical droplet containing a fluorescing molecule.
Angular momentum theory provides a mathematical foundation for the rotation of the eigenvectors of the angular momentum operator, the spherical harmonics functions. A useful property of spherical harmonics is that their rotation in 3D space corresponds to rotation in the virtual space of their azimuthal degrees of freedom. In addition to that, spherical harmonics functions that have different orbital indices do not mix. Given that spherical harmonics functions have known rotation properties, and that any arbitrary function can be expanded in a series of spherical harmonics, this property allows the rotation of an electrostatic potential when it is expanded in the series of spherical harmonics. In this chapter, the exponential form of the rotation operator, the rotation matrix for a 3D rotation of the coordinate system, and the principles of rotation of vectors and functions are described. The chapter provides a detailed self-contained introduction to the theory of angular momentum, derives the commutative properties of the angular momentum operator, and explains shift operators, while minimizing references to quantum mechanics and entirely avoiding group theory.
A general expression for spherical harmonics as an explicit function of the angle coordinates is derived using standard methods of group-representation theory. This expression is more useful to physicists than a corresponding expression available in the mathematical literature for two reasons: (1) Its normalization is the one most commonly used by physicists, rather than one of several other normalization conventions used mainly by mathematicians. (2) Its form is especially convenient for use in the operator equations which occur in quantum mechanics. Furthermore, the derivation serves the pedagogical purpose of providing a simple illustration of the methods of group-representation theory. A set of relations useful in solving the Dirac equation are listed, both because their verification provides an example of the utility of the expression derived, and because the form in which these relations are stated in the literature is apt to result in confusion stemming from the various different normalization conventions in use.
To lay a foundation for the study and use of rotation operators in graduate quantum mechanics and in research, a thorough discussion is presented of rotations in Euclidean three space (R3 ) and of their effect on kets in the Hilbert space of a single particle. The Wigner D-matrices are obtained and used to rotate spherical harmonics. An extensive ready-reference appendix of the properties of these matrices, expressed in a consistent notation, is provided. Careful attention is paid throughout to various conventions (e.g. active versus passive viewpoints) that are used in the literature.
We introduce a quantum phase space representation for the orientation state of extended quantum objects, using the Euler angles and their conjugate momenta as phase space coordinates. It exhibits the same properties as the standard Wigner function and thus provides an intuitive framework for discussing quantum effects and semiclassical approximations in the rotational motion. Examples illustrating the viability of this quasi-probability distribution include the phase space description of a molecular alignment effect.
The interplay between quantum orientation entanglement and Wigner rotation plays a fundamental role in understanding the behavior of spin angular momentum in quantum states. To analyze the quantum orientation entanglement of the relativistic helicity states interpolating between the Jacob-Wick helicity and the light-front helicity, we examine the relative angle between the particle's momentum direction and the spin orientation for the interpolating helicity states. For this analysis, we introduce a novel method for expanding the interpolating helicity states in terms of the Jacob-Wick helicity. The corresponding probabilistic coefficients follow the structure of the Wigner d-matrix elements, which we use for the interpretation of the quantum orientation entanglement manifested in the angular distributions of the interpolating scattering helicity amplitudes. As an explicit demonstration, we compute the interpolating helicity amplitudes for the pair production of spin-1 (vector) particles in the annihilation of two spin-0 (scalar) particles, focusing primarily on their contact interaction. In particular, we identify the critical interpolation angle that bifurcates the dynamical branches between the instant-form dynamics and the light-front dynamics and discuss the underlying orientation entanglement in the interpolating helicity amplitudes.
A comprehensive study is presented on the Weyl-Wigner formalism for rotation-angle and angular-momentum variables: the elements of kinematics are extended, the elements of dynamics are established, and the implications of rotational perodicity and angular-momentum quantization are investigated. Particular attention is paid to discreteness, and two of its consequences are emphasized: the importance of evenness and oddness, and the need to use two difference operators in a discrete domain, whereas one differential operator suffices in a continuous domain. These consequences are shown to strongly distinguish the Weyl-Wigner formalism for rotation-angle and angular-momentum variables from the well-known Weyl-Wigner formalism for Cartesian-position and linear-momentum variables. The point is made clear that the first of these formalisms cannot be regarded as a trivial and straightforward extension of the second. The rotational Wigner function is derived as the only bilinear form of the state vector that is real, has the natural invariances for rotational motion, and yields the correct distributions for the rotation-angle and angular-momentum variables as well as the appropriate expression for the transition probability between states. The conditions for its uniqueness are thus established. Its properties are described in detail and, in particular, its uniform boundedness is demonstrated. The rotational Wigner function and the associated correspondence between quantum operators and classical-like functions, as well as the relations they obey, are explored and are written so as to clearly exhibit the distinct contributions of evenness and oddness in the discrete domain of the angular-momentum eigenvalues, thus providing a most natural way to account for periodicity.Using the derivative, which acts on the continuous rotation-angle variable, and the forward and backward differences, which act on the discrete angular-momentum variable, the equation of motion for the rotational Wigner function is established. This equation is detailed for the following Hamiltonian forms: those that depend only on the angular-momentum variable, including, in particular, the free rotator, and those that are in the cosine of the rotation-angle variable. It is verified that the Weyl-Wigner formalism for rotation-angle and angular-momentum variables has the correct nonperiodic limit and that it properly reduces to the Weyl-Wigner formalism for Cartesian-position and linear-momentum variables. In order to illustrate the formalism, a careful analysis is carried out for the rotational Wigner function representing the energy eigenstates of a hindered rotator whose Hamiltonian is the sum of a term in the absolute value of the angular-momentum variable with a term in the cosine of the rotation-angle variable. For this hindered rotator, and within the approximation of a large absolute value of the angular-momentum variable, the equation of motion for the rotational Wigner function is solved for its stationary solutions, and the time-independent Schr\"odinger equation is also solved.