Limitations of Racah-Wigner Algebra in S[sub n]-Invariant Theoretic Modelling of NMR Spin Dynamics via Dual Tensorial Sets
Francis P. Temme, Theodore E. Simos, George Maroulis
Augmented quasiparticle (QP) mapping techniques for indistinguishable point sets, based on (Liouvillian tensorial) democratic recoupling (DR), are shown to induce a full 1:1 invariant‐labelling of the underlying (disjoint) projective mapping subspaces. This theoretical simple reducibility SR‐driven view of dual group algebras underlies certain parallel limitations of Jucys graph recoupling and (in consequence) standard Racah‐Wigner (R‐W) algebras for tensorial point sets once it is applied to indistinguishable point sets. The explicit invariants (for labelling of all disjoint carrier subspaces) and their cardinality are central to automorphic dual (symmetry) tensorial formalisms, because they provide the essential quantal‐completeness condition for DR Liouvillian tensorial sets. By drawing on augmented‐QP properties [2002, Int. J. Quantum Chem. 89, 429; 1993, Physica A 198 245]—beyond the classic Hilbert boson‐pattern overview of Louck & Biedenharn [1979, Permutation group in physics ..,Springer] of simple carrier space projective mapping—a definitive theoretical basis is derived for Atiyah and Sutcliffe's recent assertions [2002, Proc. Roy Soc., Lond. A 458, 1089], concerning the specific limitations of graph recoupling theory to distinct point sets. Direct insight is obtained into the central question of why general index ‘n’ matrix formulations of multi‐invariant DR tensorial set‐based, (automorphic) spin problems are not amenable to analytic treatment—even utilising indirect Lévi‐Civitá‐based cyclic‐commutation (R‐W) approaches, e.g. of [Lévy‐Leblond, Lévy‐Nahas, 1965, J. Math. Phys. 6, 1372], unless the tensorial system is constrained to a mono‐invariant form. The importance of this (DR) tensorial‐set work comes from its focus on the specialised nature of indistinguishable point sets in (multi)invariant theoretic views of quantum dynamical spin physics.
AIP conference proceedings•Jan 1, 2007•0 citations