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International Symposium on Molecular Spectroscopy (ISMS)

SYMPATHETIC SIDEBAND COOLING OF CaH+

René Rugango, Kenneth R. Brown

Published Jun 19, 2014• 0 citations
Publisher

Abstract

We demonstrate sympathetic Doppler cooling and our progress towards sideband cooling of a CaH$^{+}$ ion co-trapped with a Ca$^{+}$ atomic ion in a linear Paul trap. Molecular ions are generally difficult to laser cool due to a lack of closed electronic transitions as a result of vibrational and rotational states. Despite this challenge, they can be cooled indirectly through their Coulombic interaction with a fluorescent atomic ion that is being directly laser cooled. Ions are firstly Doppler cooled to get to the Lamb-Dicke regime, where the ion motion is small relative to the excitation wavelength and then sideband cooled reaching temperatures below 1 $\mu$K. All the ions' axial modes (center of mass and breathing mode) and radial modes ( two center of mass and two tilt modes) are addressed, and the temperature is determined by examining the ratio of sidebands.

DOI
10.15278/isms.2014.rh09

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We demonstrate sympathetic Doppler cooling and our progress towards sideband cooling of a CaH+^{+}+ ion co-trapped with a Ca+^{+}+ atomic ion in a linear Paul trap. Molecular ions are generally difficult to laser cool due to a lack of closed electronic transitions as a result of vibrational and rotational states. Despite this challenge, they can be cooled indirectly through their Coulombic interaction with a fluorescent atomic ion that is being directly laser cooled. Ions are firstly Doppler cooled to get to the Lamb-Dicke regime, where the ion motion is small relative to the excitation wavelength and then sideband cooled reaching temperatures below 1 μ\muμK. All the ions' axial modes (center of mass and breathing mode) and radial modes ( two center of mass and two tilt modes) are addressed, and the temperature is determined by examining the ratio of sidebands.
This thesis reports on the setup of a new ion trap apparatus designed for experiments with single ⁴⁰Ca⁺ ions to perform molecular spectroscopy. The calcium ion is laser cooled, allowing for sympathetic cooling of the nonfluorescing molecular ion. The aim of these experiments is to explore loading and identifying molecular ions in RF-Paul traps, as well as developing new spectroscopic tools to measure transitions of molecular ions via the fluorescence of co-trapped ⁴⁰Ca⁺ ions. Ground state cooling of a mixed ion pair is implemented as a first step towards increasing the sensitivity of our technique to the level necessary to measure transitions with low scattering rates (like those present in molecular ions). Doppler cooling on the S(1/2)->P(1/2) transition of the calcium ion results in the formation of a Coulomb crystal, the behavior of which may be used to infer properties of the molecular ion. Following cooling, sideband spectroscopy on the narrow S(1/2)->D(5/2) quadrupole transition of calcium may be used to identify the mass of single molecular ions. This method is verified via a non-destructive measurement on ⁴⁰CaH⁺ and ⁴⁰Ca¹⁶O⁺. The normal modes of the Coulomb crystal can also be used to extract information from the target ion to the control ion. By driving the blue side of a transition, laser induced heating can be put into the two ion system, which leads to changes in fluorescence of the ⁴⁰Ca⁺ ion, first demonstrated with two Ca⁺ isotopes. Increasing the sensitivity of this technique requires ground state cooling of both the ⁴⁰Ca⁺ ion and the ion of interest, enabling the transfer of the ion's motional state into the ground state with high probability. This thesis demonstrates ground state cooling of the atomic ion and sympathetic cooling of a second ion (⁴⁴Ca⁺). Once in the ground state, heating of the Coulomb crystal by scattering photons off of the spectroscopy ion can be measured by monitoring the resolved motional sidebands of the S(1/2)->D(5/2) transition of ⁴⁰Ca⁺, allowing for spectral lines to be inferred. Future experiments will investigate this technique with molecular ions.
We present the results of simulations of optical sideband cooling of atomic ions in a trap with a shallow potential well. In such traps, an ion cannot be Doppler cooled near to the Lamb-Dicke regime $\mathrm{[}{\ensuremath{\eta}}^{2}(2\ensuremath{\langle}n\ensuremath{\rangle}+1)\ensuremath{\ll}1]$. Outside the Lamb-Dicke regime, the sideband cooling dynamics are altered by the existence of various Fock states with weak coupling where the cooling becomes very slow. A 40Ca+^{40}\mathrm{Ca}^{+}40Ca+ ion trapped in our Penning trap realizes such a situation; hence single stage cooling is inefficient to prepare the ion in the motional ground state. For these systems, it is necessary to study the cooling dynamics in detail and we show that it is possible to implement an optimized cooling sequence to achieve efficient ground-state cooling. We also present the simulated cooling dynamics of two ions trapped in a Penning trap, where the presence of an additional motional mode requires a complicated cooling sequence in order to cool both axial modes to the ground state simultaneously. Additionally, we demonstrate the dissipative preparation of Fock states outside the Lamb-Dicke regime by sideband heating a single ion in a Penning trap.
Laser-cooled atomic ions have led to an unprecedented amount of control over the quantum states of matter. The Coulombic interaction allows for information to be transferred between neighboring ions, and this interaction can be used to entangle qubits for logic operations in quantum information processors. The same procedure for logic operations can be used for high resolution atomic spectroscopy, and is the basis for the most accurate atomic optical clocks to date. This thesis describes how laser-cooled atomic ions can impact physical chemistry through the development of molecular ion spectroscopy techniques and the simulation of magnetic systems by ion trap quantum computers. \n\t \n\tA new technique developed for spectroscopy, Sympathetic Heating Spectroscopy (SHS), takes advantage of the Coulombic interaction between two trapped ions: the control ion and a spectroscopy ion. SHS uses the back action of the interrogating laser to map spectroscopy ion information onto the Doppler shift of the control ion for measurement. SHS only requires Doppler cooling of the ions and fluorescence measurement and represents a simplification of quantum logic spectroscopy. This technique is demonstrated on two individual isotopes of calcium: Ca-40(+) for cooling and Ca-44(+) as the spectroscopy ion. \n \n\tHaving demonstrated SHS with atomic ions, the next step was to extend the technique by loading and characterizing molecular ions. The identification of an unknown molecular ion is necessary and can be achieved by monitoring the change in motion of the two ion crystal, which is dependent on the molecular ion mass. The motion of two trapped ions is described by their normal modes, which can be accurately measured by performing resolved sideband spectroscopy of the S(1/2)-D(5/2) transition of calcium. The resolved sidebands can be used to identify unknown ions (atomic and molecular) by calculating the mass based on the observed value in axial normal mode frequencies. Again, the trapped molecular ion is sympathetically cooled via the Coulombic interaction between the Ca-40(+) and the unknown molecular ion. The sensitivity of SHS could be improved by implementing sympathetic sideband cooling and determining the heating by measuring single quanta of motion. \n\t \n\tThe ultimate limit of control would be the development of an ion trap quantum computer. Many theoretical quantum computing researchers have made bold claims of the exponential improvement a quantum computer would have over a classical computer for the simulation of physical systems such as molecules. These claims are true in principle for ideal systems, but given non-ideal components it is necessary to consider the scaling due to error correction. An estimate of the resource requirements, the total number of physical qubits and computational time, required to compute the ground state energy of a 1-D quantum Transverse Ising Model (TIM) of N spin-1/2 particles, as a function of the system size and the numerical precision, is presented. This estimate is based on analyzing the impact of fault-tolerant quantum error correction in the context of the quantum logic array architecture. The results show that a significant amount of error correction is required to implement the TIM problem due to the exponential scaling of the computational time with the desired precision of the energy. Comparison of this result to the resource requirements for a fault-tolerant implementation of Shor's quantum factoring algorithm reveals that the required logical qubit reliability is similar for both the TIM problem and the factoring problem.
We have recently demonstrated the laser cooling of a single 40Ca+ ion to the motional ground state in a Penning trap using the resolved-sideband cooling technique on the electric quadrupole transition S12↔ D52. Here we report on the extension of this technique to small ion Coulomb crystals made of two or three 40Ca+ ions. Efficient cooling of the axial motion is achieved outside the Lamb-Dicke regime on a two-ion string along the magnetic field axis as well as on two- and three-ion planar crystals. Complex sideband cooling sequences are required in order to cool both axial degrees of freedom simultaneously. We measure a mean excitation after cooling of n¯COM=0.30(4) for the centre of mass (COM) mode and n¯B=0.07(3) for the breathing mode of the two-ion string with corresponding heating rates of 11(2) s-1 and 1(1)s-1 at a trap frequency of 162 kHz. The occupation of the ground state of the axial modes (ntilt=nCOM=0) is above 75% for the two-ion planar crystal and the associated heating rates 0.8(5) s-1 at a trap frequency of 355 kHz.
We propose a sub-Doppler cooling scheme for trapped-ion crystals in Paul traps. The combination of a hollow tweezer and microwave drive creates an effective two-level system which is cooled through attractive Sisyphus cooling. For 171Yb+{}^{171}\rm{Yb}^+171Yb+ ions, we numerically identify optimal parameters for one- and two-ion crystals, and investigate the cooling rate in ion crystals with up to three ions. Our cooling scheme utilizes a single ion addressed with a tweezer to achieve sub-Doppler cooling of the NNN axial motional modes perpendicular to the tweezer propagation direction, does not rely on the Lamb-Dicke regime and uses off-resonant light. We reach 1/e1/e1/e cooling times for the center of mass mode of τcom<2τ_{\rm com}<2τcom​<2 ms, and a steady-state excitation number of nˉcom≈0.7\bar{n}_{\rm{com}}\approx 0.7nˉcom​≈0.7. Our scheme is well-suited as an intermediate stage between Doppler cooling and ground-state sideband cooling, and can be readily realized in trapped-ion platforms.