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Journal of Mathematical Physics

Local properties of quantum systems

Boris Leaf

Published Jun 1, 1986• 2 citations
Publisher

Abstract

Local properties of a quantum system are defined as the expectation values of its observables in a microstate of some complete set of commuting observables. An equation for the time evolution of local properties is obtained for any system whose statistical operator (density matrix) evolves by unitary transformation in accordance with the von Neumann equation. The formalism is applied to the example of a system of one particle. In this case the local properties are fields, the time-evolution equation is an equation of continuity with source terms. For constants of motion the source terms vanish, giving equations of continuity for the fields. For each scalar field a flux vector for its transport current is defined. For momentum, a stress tensor is obtained. The effects on local properties of realization of a latent ensemble of the statistical operator (an entropy-increasing mechanism recently proposed to explain approach to equilibrium) are also considered; a non-negative local entropy production is identified, as well as a discontinuous redistribution of local properties among microstates.

DOI
10.1063/1.527386

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•Jan 25, 2019•0 citations
Local properties of a quantum system are defined as the expectation values of its observables in a microstate of some complete set of commuting observables. An equation for the time evolution of local properties is obtained for any system whose statistical operator (density matrix) evolves by unitary transformation in accordance with the von Neumann equation. The formalism is applied to the example of a system of one particle. In this case the local properties are fields, the time-evolution equation is an equation of continuity with source terms. For constants of motion the source terms vanish, giving equations of continuity for the fields. For each scalar field a flux vector for its transport current is defined. For momentum, a stress tensor is obtained. The effects on local properties of realization of a latent ensemble of the statistical operator (an entropy-increasing mechanism recently proposed to explain approach to equilibrium) are also considered; a non-negative local entropy production is identified, as well as a discontinuous redistribution of local properties among microstates.
Classical transport equations with probabilistic initial conditions can be viewed as quantum systems. In a discrete version they are probabilistic automata. The time-local probabilistic information is encoded in a classical wave function. Its unitary evolution obeys a Schrödinger equation. Statistical observables measure properties of the classical probability distribution. In the quantum formalism they are represented by operators which do not commute with the ones associated to classical observables. Momentum, quantum energy and angular momentum or charges yield conserved quantities which constrain the evolution of the classical probability distribution. The characteristic features of quantum mechanics, as the superposition of wave functions, interference, the importance of phases, non-commuting operators or a unitary time evolution, are realized by probabilistic classical transport equations. Stochastic transport equations are described by a quantum system with a stochastic Hamiltonian.
We present a partition of quantum observables in an open quantum system that is inherited from the division of the underlying Hilbert space or configuration space. It is shown that this partition leads to the definition of an inhomogeneous continuity equation for generic, non-local observables. This formalism is employed to describe the local evolution of the von Neumann entropy of a system of independent quantum particles out of equilibrium. Crucially, we find that all local fluctuations in the entropy are governed by an entropy current operator, implying that the production of entanglement entropy is not measured by this partitioned entropy. For systems linearly perturbed from equilibrium, it is shown that this entropy current is equivalent to a heat current, provided that the system-reservoir coupling is partitioned symmetrically. Finally, we show that any other partition of the coupling leads directly to a divergence of the von Neumann entropy. Thus, we conclude that Hilbert-space partitioning is the only partition of the von Neumann entropy that is consistent with the laws of thermodynamics.
The macroscopic hydrodynamic equations are derived for many-body systems in the local-equilibrium approach, using the Schrödinger picture of quantum mechanics. In this approach, statistical operators are defined in terms of microscopic densities associated with the fundamentally conserved quantities and other slow modes possibly emerging from continuous symmetry breaking, as well as macrofields conjugated to these densities. Functional identities can be deduced, allowing us to identify the reversible and dissipative parts of the mean current densities, to obtain general equations for the time evolution of the conjugate macrofields, and to establish the relationship to projection-operator methods. The entropy production is shown to be nonnegative by applying the Peierls-Bogoliubov inequality to a quantum integral fluctuation theorem. Using the expansion in the gradients of the conjugate macrofields, the transport coefficients are given by Green-Kubo formulas and the entropy production rate can be expressed in terms of quantum Einstein-Helfand formulas, implying its nonnegativity in agreement with the second law of thermodynamics. The results apply to multicomponent fluids and can be extended to condensed matter phases with broken continuous symmetries.
Localization properties of a QFT model, consisting of a quantum scalar field interacting linearly with a classical localized source, are investigated using various approaches present in the literature. We evaluate, to any order of the field–matter coupling constant, the time evolution of average values of one-point localization observables and scalar product between the quantum field state of the evolving system and localized states. We show that the appearance of nonlocality can be connected to nonlocal properties of localized states used or to the fact that localization operators do not satisfy the microcausality principle and therefore does not imply the violation of causality.
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
For a quantum state undergoing unitary Schrodinger time evolution, the von Neumann entropy is constant. Yet the second law of thermodynamics, and our experience, show that entropy increases with time. Ingarden introduced the quantum operator entropy, which is the Shannon entropy of the probability distribution for the eigenvalues of a Hermitian operator. These entropies characterize the missing information about a particular observable inherent in the quantum state itself. The von Neumann entropy is the quantum operator entropy for the case when the operator is the density matrix. We examine pure state unitary evolution in a simple model system comprised of a set of highly-interconnected topologically disordered states and a time-independent Hamiltonian. An initially confined state is subject to free expansion into available states. The time development is completely reversible with no loss of quantum information and no course graining is applied. The positional entropy increases in time in a way that is consistent with both the classical statistical mechanical entropy and the second law.