Thermodynamic Continuity and Quantum Principles

Alfred Landé

A condensed survey is given of the results of a previous investigation on quantum concepts and principles developed from the anti-Gibbs postulate of thermodynamic continuity. The same postulate now also yields major parts of quantum statistics, such as the equality of various occupation number sets without permutation of individual particles, not however the alternative "either Bose or Fermi statistics." A distinction must be made between a coherent redistribution of particles without entropy change, and an incoherent redistribution leading to a new thermodynamic equilibrium. The latter is obtained from the former by a process of diffusion from separate level groups to a totality of levels.

Alfred Landé

Alfred Landé

Alfred Landé

The basic concepts and rules of quantum mechanics are shown to be immediate consequences, on the basis of simple reasoning, of a postulate of continuity in the domain of macroscopic thermodynamics. The continuity principle leads first to the concept of a fractional likeness between two states in general, as opposed to the classical alternative of either like or unlike. Then all possible states of a system can be arranged in sets of mutually unlike or “orthogonal” states, with members A and B of different sets interconnected by fractional likeness factors q(A, B) between zero and unity. These factors q are identical with the relative intensities in a splitting effect of a state into components, ruled by probability relations and by the basic principle of quantum statistics of not counting permutations of individual particles. The problem of relation between the various fractional likenesses, or probabilities of transition under analysis, is a purely mathematical problem and is solved by the introduction of probability amplitudes necessarily subject to a matrix law of multiplication, i.e., to the principle of superposition. Thus, starting from the continuity postulate of thermodynamics, quantum theory in its general outline is obtained by simple reasoning. All further details, such as the duality of waves and particles, the uncertainty relation, and the mechanics of special systems, need only one more bit of empirical information, namely, the symmetric and periodic form of the amplitude ψ of fractional likeness between a state of given coordinate and a state of given momentum.

Felix C. Binder, Luis Alfonso Correa, Christian Gogolin +2 more

Adalberto D. Varizi, Daniel Jonathan, Thiago R. de Oliveira

Understanding how macroscopic thermodynamic behavior emerges from microscopic quantum dynamics remains an open problem. While equilibration of quantum observables is well established, thermodynamics also relies on variables not directly associated with linear operators, but which are defined instead as functions of expectation values. Whether and how such derived quantities inherit equilibration properties is an open question. Here, we establish that any continuously differentiable function of equilibrating expectation values also equilibrates. We apply this result to a bipartite isolated system, showing that the entropy and conjugate variables of each subsystem -- defined through Jaynes' maximum entropy principle -- equilibrate. Moreover, with the assumption that their equilibrium properties depend solely on local conserved quantities, we show the dynamical maximization of the total entropy, enforcing equality of conjugate variables across subsystems. These results provide a direct dynamical justification for entropy maximization and the emergence of thermodynamic equilibrium conditions, showing that fundamental principles of thermodynamics follow from the unitary evolution of quantum systems.