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Chemical Physics Letters

Conditional probability amplitudes and the variational principle

David M. Bishop, Lap Ming Cheung

Published Aug 1, 1977• 9 citations
Publisher
DOI
10.1016/0009-2614(77)80704-5

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arXiv:1202.4638•Physical Review A•Apr 9, 2012•13 citations
We show that the time-dependent Schr\"odinger equation (TDSE) is the phenomenological dynamical law of evolution unraveled in the classical limit from a timeless formulation in terms of probability amplitudes conditioned by the values of suitably chosen internal clock variables, thereby unifying the conditional probability interpretation (CPI) and the semiclassical approach for the problem of time in quantum theory. Our formalism stems from an exact factorization of the Hamiltonian eigenfunction of the clock plus system composite, where the clock and system factors play the role of marginal and conditional probability amplitudes, respectively. Application of the Variation Principle leads to a pair of exact coupled pseudoeigenvalue equations for these amplitudes, whose solution requires an iterative self-consistent procedure. The equation for the conditional amplitude constitutes an effective ``equation of motion'' for the quantum state of the system with respect to the clock variables. These coupled equations also provide a convenient framework for treating the back-reaction of the system on the clock at various levels of approximation. At the lowest level, when the WKB approximation for the marginal amplitude is appropriate, in the classical limit of the clock variables the TDSE for the system emerges as a matter of course from the conditional equation. In this connection, we provide a discussion of the characteristics required by physical systems to serve as good clocks. This development is seen to be advantageous over the original CPI and semiclassical approach since it maintains the essence of the conventional formalism of quantum mechanics, admits a transparent interpretation, avoids the use of the Born-Oppenheimer approximation, and resolves various objections raised about them.