Quantum control aims at the manipulation of atomic- and molecular-scale dynamics phenomena. An important objective in this regard is the understanding of dynamical control within a family of related quantum systems. To explore this issue, diffeomorphic changes in the system Hamiltonian
H(s,t) are introduced by scanning over a homotopy parameter
s and then monitoring the control field response needed to maintain the value of a specified target observable. This operation is implemented through a procedure referred to as diffeomorphic modulation under observable-response-preserving homotopy (D-MORPH). The governing D-MORPH differential equation determining the control laser field
E(s,t) is shown to explicitly allow for innumerable solutions, with each characterized by the choice of an arbitrary function
f(s,t) of
s and time
t. The presence of
f(s,t) in the D-MORPH differential equation makes clear the origin of multiple control fields that produce the same observable objective. A stable algorithm is presented for practical execution of D-MORPH with the only criterion that the Hamiltonian
H(s,t) permit reaching the objective over the full domain of
s being sampled. Both analytic and numerical examples are presented to illustrate the D-MORPH concept.
The goal of quantum tracking control is to identify shaped fields to steer observable expectation values along designated time-dependent tracks. The fields are determined via an iteration-free procedure, which is based on inverting the underlying dynamical equations governing the controlled observables. In this paper, we generalize the ideas in [Phys. Rev. A 98, 043429 (2018)] to the task of orienting symmetric top molecules in three dimensions. To this end, we derive equations for the control fields capable of directly tracking the expected value of the three-dimensional dipole orientation vector along a desired path in time. We show this framework can be utilized for tracking the orientation of linear molecules as well, and present numerical illustrations of these principles for symmetric-top tracking control problems.
Quantum tracking control aims to identify applied fields to steer the expectation values of particular observables along desired paths in time. The associated temporal fields can be identified by inverting the underlying dynamical equations for the observables. However, fields found in this manner are often plagued by undesirable singularities. In this paper we consider a planar molecular rotor and derive singularity-free tracking expressions for the fields that steer the expectation of the orientation of the rotor along the desired trajectories in time. Simulations are presented that utilize two orthogonal control electric fields to drive the orientation of the rotor along a series of designated tracks.
For quantum state trajectory tracking of density matrix in Liouville equation of quantum systems, with the help of concept in quantum system control, one can apply unitary transformation both to controlled system and free-evolutionary target system such as to change the time-variant and non-stationary target system into a stationary state. Therefore, the quantum state trajectory tracking problem becomes a steering one. State steering control law of the system transformed is designed by means of the Lyapunov stability theorem. Finally, numerical simulation experiments are given for a five-level energy quantum system. The comparison analysis of original system’s trajectory tracking with other method illustrates the advantage in control time of the method proposed.
A quantum control landscape is defined by the value of a physical observable as a functional of the time-dependent control field
E(t) for a given quantum-mechanical system. Level sets through this landscape are prescribed by a particular value of the target observable at the final dynamical time
T, regardless of the intervening dynamics. We present a technique for exploring a landscape level set, where a scalar variable
s is introduced to characterize trajectories along these level sets. The control fields
E(s,t) accomplishing this exploration (i.e., that produce the same value of the target observable for a given system) are determined by solving a differential equation over
s in conjunction with the time-dependent Schr\"odinger equation. There is full freedom to traverse a level set, and a particular trajectory is realized by making an a priori choice for a continuous function
f(s,t) that appears in the differential equation for the control field. The continuous function
f(s,t) can assume an arbitrary form, and thus a level set generally contains a family of controls, where each control takes the quantum system to the same final target value, but produces a distinct control mechanism. In addition, although the observable value remains invariant over the level set, other dynamical properties (e.g., the degree of robustness to control noise) are not specifically preserved and can vary greatly. Examples are presented to illustrate the continuous nature of level-set controls and their associated induced dynamical features, including continuously morphing mechanisms for population control in model quantum systems.
The orbit tracking of free-evolutionary target system in closed quantum systems is studied in this paper. Based on the concept of system control theory, the unitary transformation is applied to change the time-dependent target function into a stationary target state so that the orbit tracking problem is changed into the state transfer one. A Lyapunov function with virtual mechanical quantity P is employed to design a control law for such a state transferring. The target states in density matrix are grouped into two classes: diagonal and non-diagonal. The specific convergent conditions for target state of diagonal mixed-states are derived. In the case that the target state is a non-diagonal superposition state, we propose a non-diagonal P construction method; if the target state is a non-diagonal mixed-state we use a unitary transformation to change it into a diagonal state and design a diagonal P. In such a way, the orbit tracking problem with arbitrary initial state is properly solved. The explicit expressions of P are derived to obtain a convergent control law. At last, the system simulation experiments are performed on a two-level quantum system and the tracking process is illustrated on the Bloch sphere.