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Journal of Physics B Atomic and Molecular Physics

Critical discussion of an absolute measurement of multiphoton ionisation cross sections in caesium

M Aymar, Michele Crance

Published Nov 28, 1979• 19 citations
Publisher

Abstract

Four-photon ionisation of caesium requires strong electromagnetic fields and the usual interpretation in terms of generalised cross sections has to be questioned. A theoretical calculation in the experimental conditions of a recent measurement provides a new interpretation of the results of Morellec and Normand (1979): the effect of light shifts masks the effect of saturation and leads one to overestimate the multiphoton ionisation cross section. The expected overestimation is only 25 per cent for the quoted experiment, but could be larger in some other physical cases.

DOI
10.1088/0022-3700/12/22/003

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Journal of Physics B Atomic and Molecular Physics•Oct 14, 1979•6 citations
Four-photon ionisation of caesium requires strong electromagnetic fields and the usual interpretation in terms of generalised cross sections has to be questioned. A theoretical calculation in the experimental conditions of a recent measurement provides a new interpretation of the results of Morellec and Normand (1979): the effect of light shifts masks the effect of saturation and leads one to overestimate the multiphoton ionisation cross section. The expected overestimation is only 25 per cent for the quoted experiment, but could be larger in some other physical cases.
Non-resonant k-photon ionisation cross sections may be calculated by kth order perturbative treatment. This method is generally considered to be good when the detuning from the closest resonance is much larger than the expected shift and width of this resonance. The aim of this paper is to discuss the validity of this criterion for several realistic cases. By diagonalising an effective Hamiltonian built on a few quasi-resonant states, we have calculated multiphoton ionisation cross sections for ground state caesium by linearly polarised light in frequency ranges containing the tuning range of the ruby laser, the Nd glass laser and its first harmonic. The study is carried out up to an intensity of 10 11 W cm -2 .