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Ergodicity of quantum many-body systems

A. Janner

Published Apr 1, 1963• 0 citations
Publisher

Abstract

An important hypothesis in Van Hove's proof of the ergodicity of dissipative quantum systems is the generalized microscopic reversibility condition X/sub ll'/( alpha alpha ') = X/sub l'l/( alpha ' alpha ). I t is shown how such an assumption can be avoided by deducing for a finite system a general symmetry relation which corresponds to the condition used by Stueckelberg for deriving the H-theorem. This general symmetry relation considered in the limit of an infinite system ensures the correct statistical behavior of the system for very large time. The calculation of the trace in the limiting case of an infinite system is discussed. (auth)

DOI
10.5169/seals-113363

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An important hypothesis in Van Hove's proof of the ergodicity of dissipative quantum systems is the generalized microscopic reversibility condition X/sub ll'/( alpha alpha ') = X/sub l'l/( alpha ' alpha ). I t is shown how such an assumption can be avoided by deducing for a finite system a general symmetry relation which corresponds to the condition used by Stueckelberg for deriving the H-theorem. This general symmetry relation considered in the limit of an infinite system ensures the correct statistical behavior of the system for very large time. The calculation of the trace in the limiting case of an infinite system is discussed. (auth)
In a paper by Klein, it is pointed out that for the quantum mechanical ergodic theorem (time average = average over states) to be valid, all integrals of motion R must satisfy the condition ∑ρ"(α′ρ"|R|β′ρ")=const δα′β′ (1) where α′, β′, γ, … refer to the assembly under question and α", β",…, ρ" ,… refer to the surrounding with which our assembly is in equilibrium. In this short note, it is pointed out that the argument of Klein is doubtful at one point and a slightly different approach is given. In this approach, it is shown that (1) is actually sufficient, but only after introducing an additional assumption that the different states of the surroundings have equal probabilities, and that in general, a stronger condition such as (α′ρ″|R|β′θ″)=const δα′β′δρ″θ″ (2) is needed. Cases with integrals of motion is also considered. We consider first an isolated system, write the wave function as (α1α2>, where α1 represents a set of commuting integrals of motion and α2 a set of observables not containing integrals of motion and introduce the assumption that for any integral of motion R, the matrix 1α′2Rα1"α2"> representing it is of the form φ(α′1α1")δ(α′2α2"). (3) Under such conditions, we prove that if the initial state of our system is an eigenstate of α1 corresponding to the eigenvalue α10, then the average of an observable F over time is given by ∑α210α2|F|α10α2>/∑α210α2|1|α10α2>, a result which is clearly to be expected. Extension to systems interacting with external surroundings is easily made.
Relations, which are ergodic in a generalized sense, are deduced from the laws of quantum theory without any hypothesis of a priori probabilities. These relations are satisfied for the overwhelming majority of the initial state-vectors of any isolated system with very many degrees of freedom.By means of these relations, it is proved that a system---when weakly coupled with another system having a comparatively very large number of degrees of freedom---does not deviate significantly from the canonical distribution at the overwhelming majority of the time instants.
We consider the dissipative properties of large quantum systems from the point of view of kinetic theory. The existence of a nontrivial collision operator imposes restrictions on the possible collisional invariants of the system. We consider a model in which a discrete level is coupled to a set of quantum states and which, in the limit of a large "volume," becomes the Friedrichs model. Because of its simplicity this model allows a direct calculation of the collision operator as well as of related operators and the constants of the motion. For a degenerate spectrum the calculations become more involved but the conclusions remain simple. The special role played by the invariants that are functions of the Hamiltonion is shown to be a direct consequence of the existence of a nonvanishing collision operator. For a class of observables we obtain ergodic behavior, and this reformulation of the ergodic problem may be used in statistical mechanics to study the ergodicity of large quantum systems containing a small physical parameter such as the coupling constant or the concentration.
An ergodic theorem is a statement of the equality of the time averages of the physical properties of a system and the averages of these quantities obtained from the consideration of a Gibbsian ensemble of identical systems. It is shown that, in quantum statistical mechanics, a necessary and sufficient condition for the existence of an ergodic theorem can be derived for a system in weak energetic interaction with its surroundings. This necessary and sufficient condition for the equality of time and (microcanonical) ensemble averages is that all operators invariant in time shall reduce to constant multiples of the unit operator when applied to the system itself. It is shown that the conditions for ergodicity are formally analogous to those derived by von Neumann for classical statistical mechanics. No assumption of "molecular chaos" is made.
von Neumann has proved a quantum-mechanical ergodic theorem which deals with a closed macroscopic system and macroscopic observables. Certain unsatisfactory features of this theorem are probably due to the overly-strong idealization of a completely closed system.Since the claims of statistical mechanics go beyond macroscopic systems, there is a need for a more general theorem. The present paper deals with a system of any number of degrees of freedom and with any observable, during interaction with a temperature bath. In order to avoid an assumption of randomness, the bath must be described explicitly and precisely by a time-independent Hamiltonian. The model of the bath is obtained by taking the Gibbs ensemble seriously, i.e., as a set of NNN identical systems interacting through a potential $\ensuremath{\lambda}V$.The following theorem is proved. The time average of the quantum-mechanical expectation value of any observable with respect to any initial state is equal to its statistical average, in the double limit $N\ensuremath{\rightarrow}\ensuremath{\infty}$, $\ensuremath{\lambda}\ensuremath{\rightarrow}0$, for the overwhelming majority of all interaction potentials VVV.
A discrete quantum process is represented by a sequence of quantum operations, which are completely positive maps that are not necessarily trace preserving. We consider quantum processes that are obtained by repeated iterations of a quantum operation with noise. Such ergodic quantum processes generalize independent quantum processes. An ergodic theorem describing convergence to equilibrium for a general class of such processes has been recently obtained by Movassagh and Schenker. Under irreducibility and mixing conditions, we obtain a central limit type theorem describing fluctuations around the ergodic limit.