Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Molecular Physics

Discrete Hamiltonian symmetries and semiclassical quantization

Sudeshna Sinha, V B Sheorey

Published Dec 20, 1993• 5 citations
Publisher

Abstract

Most quantum Hamiltonian systems exhibit discrete symmetries. Allowing for these is crucial when properly calculating the fluctuation properties of the quantal spectrum. These properties are then employed to distinguish between classically chaotic or non-chaotic quantum systems. In general, semiclassical quantization procedures do not take into account irreducible representations of the Hamiltonian. A procedure is presented to take these into account in semiclassical quantization schemes and calculate some of the energy eigenvalues belonging to a specific irreducible representation.

DOI
10.1080/00268979300103191

Related papers

Semiclassical quantization of the Liouville formulation of classical mechanics

Charles Jaffé

A new method for the quantization of classical Hamiltonian systems is presented. This method is based upon the correspondence between the Liouville formulation of classical mechanics and the Liouville–von Neumann formulation of quantum mechanics. It does not distinguish between integrable and nonintegrable systems, and consequently, is equally applicable to both types of systems. Further, it treats the indistinguishability of identical particles correctly, and thus, the semiclassical eigenstates have the correct symmetry properties. Application of the method is illustrated by a series of examples. The results are in excellent agreement with quantum mechanics and represent an improvement over results obtained using the uniform semiclassical approximation.

The Journal of Chemical Physics•Jun 15, 1988•9 citations

Nature of semiclassical spectrum in terms of classical trajectories(4) Quantum chaos and semiclassical theory in molecular science and nuclear theory, Chaos and Nonlinear Dynamics in Quantum-Mechanical and Macroscopic Systems)

Hiroshi Ushiyama, Kazuo Takatsuka

The mechanism of semiclassical quantization is examined in detail. We found an important role of destructive interference in building quantum spectrum. Based on this analysis, we propose an efficient method to calculate the semiclassical spectrum. This method is particularly promising in multidimensional chaotic systems and also very useful to identify which trajectories dominate a quantum spectrum. We numerically examine this method by applying to a two-dimensional chaotic system and show an illustrative example of identifying such a dominant trajectory that corresponds to an eigenstate.

物性研究•Jun 20, 2005•0 citations

Semiclassical mechanics of periodic motion: I. General scheme

Peter Kasperkovitz, Momtchil Peev

A unified treatment of quantum mechanical oscillatory motion in one dimension is presented in a phase space formalism which is especially adapted to the semiclassical energy domain and closely related to a `naive' quantization of action and angle variables. Characteristics of this scheme are non-classical symmetry properties of the phase space functions representing density operators and observables and the inclusion of half-Bohr orbits besides the familiar Bohr orbits. Over long time intervals the quantum evolution can be well approximated by a Hamiltonian flow along these distinguished classical orbits. The interplay of this reduced classical evolution and the symmetry properties of the phase space functions results in a consistent quantitative description of quantum interference effects which are most clearly seen in the revivals of wavepackets.

Journal of Physics A Mathematical and General•Mar 6, 1998•2 citations

Semiclassical mechanics of symmetry reduction

Stephen C. Creagh

The author discusses semiclassical approximations that are adapted to given symmetry classes in quantum mechanics. Arbitrary abelian symmetries and also rotational symmetry are treated. Semiclassical approximations are derived for the projected propagator and energy dependent Green's function associated with a given irreducible representation of the symmetry group. From these they derive trace formulae, analogous to the usual trace formula, that determine the energy levels in a given symmetry class in terms of classical orbits.

Journal of Physics A Mathematical and General•Jan 7, 1993•22 citations

Discrete symmetries in classical and quantum oscillators

Alexander D. Popov

We consider the nature of the wave function using the example of a harmonic oscillator. We show that the eigenfunctions $ψ_n{=}z^n$ of the quantum Hamiltonian in the complex Bargmann-Fock-Segal representation with $z\in\mathbb C$ are the coordinates of a classical oscillator with energy $E_n=\hbarωn$, $n=0,1,2,...\,$. They are defined on conical spaces ${\mathbb C}/{\mathbb Z}_n$ with cone angles $2π/n$, which are embedded as subspaces in the phase space $\mathbb C$ of the classical oscillator. Here ${\mathbb Z}_n$ is the finite cyclic group of rotations of the space $\mathbb C$ by an angle $2π/n$. The superposition $ψ=\sum_n c_nψ_n$ of the eigenfunctions $ψ_n$ arises only with incomplete knowledge of the initial data for solving the Schrödinger equation, when the conditions of invariance with respect to the discrete groups ${\mathbb Z}_n$ are not imposed and the general solution takes into account all possible initial data parametrized by the numbers $n\in\mathbb N$.

quant-pharXiv:2601.01960•Jan 6, 2026•0 citations

Renormalized semiclassical quantization for rescalable Hamiltonians

Satoshi Takahashi, Kazuo Takatsuka

A renormalized semiclassical quantization method for rescalable Hamiltonians is proposed. A classical Hamilton system having a potential function that consists of homogeneous polynomials like the Coulombic potential can have a scale invariance in its extended phase space (phase space plus time). Consequently, infinitely many copies of a single trajectory constitute a one-parameter family that is characterized in terms of a scaling factor. This scaling invariance in classical dynamics is lost in quantum mechanics due to the presence of the Planck constant. It is shown that in a system whose classical motions have a self-similarity in the above sense, classical trajectories adopted in the semiclassical scheme interact with infinitely many copies of their own that are reproduced by the relevant scaling procedure, thereby undergoing quantum interference among themselves to produce a quantized spectrum.

Physical Review A•Nov 9, 2004•9 citations
Most quantum Hamiltonian systems exhibit discrete symmetries. Allowing for these is crucial when properly calculating the fluctuation properties of the quantal spectrum. These properties are then employed to distinguish between classically chaotic or non-chaotic quantum systems. In general, semiclassical quantization procedures do not take into account irreducible representations of the Hamiltonian. A procedure is presented to take these into account in semiclassical quantization schemes and calculate some of the energy eigenvalues belonging to a specific irreducible representation.
A new method for the quantization of classical Hamiltonian systems is presented. This method is based upon the correspondence between the Liouville formulation of classical mechanics and the Liouville–von Neumann formulation of quantum mechanics. It does not distinguish between integrable and nonintegrable systems, and consequently, is equally applicable to both types of systems. Further, it treats the indistinguishability of identical particles correctly, and thus, the semiclassical eigenstates have the correct symmetry properties. Application of the method is illustrated by a series of examples. The results are in excellent agreement with quantum mechanics and represent an improvement over results obtained using the uniform semiclassical approximation.
The mechanism of semiclassical quantization is examined in detail. We found an important role of destructive interference in building quantum spectrum. Based on this analysis, we propose an efficient method to calculate the semiclassical spectrum. This method is particularly promising in multidimensional chaotic systems and also very useful to identify which trajectories dominate a quantum spectrum. We numerically examine this method by applying to a two-dimensional chaotic system and show an illustrative example of identifying such a dominant trajectory that corresponds to an eigenstate.
A unified treatment of quantum mechanical oscillatory motion in one dimension is presented in a phase space formalism which is especially adapted to the semiclassical energy domain and closely related to a `naive' quantization of action and angle variables. Characteristics of this scheme are non-classical symmetry properties of the phase space functions representing density operators and observables and the inclusion of half-Bohr orbits besides the familiar Bohr orbits. Over long time intervals the quantum evolution can be well approximated by a Hamiltonian flow along these distinguished classical orbits. The interplay of this reduced classical evolution and the symmetry properties of the phase space functions results in a consistent quantitative description of quantum interference effects which are most clearly seen in the revivals of wavepackets.
The author discusses semiclassical approximations that are adapted to given symmetry classes in quantum mechanics. Arbitrary abelian symmetries and also rotational symmetry are treated. Semiclassical approximations are derived for the projected propagator and energy dependent Green's function associated with a given irreducible representation of the symmetry group. From these they derive trace formulae, analogous to the usual trace formula, that determine the energy levels in a given symmetry class in terms of classical orbits.
We consider the nature of the wave function using the example of a harmonic oscillator. We show that the eigenfunctions ψn=znψ_n{=}z^nψn​=zn of the quantum Hamiltonian in the complex Bargmann-Fock-Segal representation with z∈Cz\in\mathbb Cz∈C are the coordinates of a classical oscillator with energy En=ℏωnE_n=\hbarωnEn​=ℏωn, n=0,1,2,... n=0,1,2,...\,n=0,1,2,.... They are defined on conical spaces C/Zn{\mathbb C}/{\mathbb Z}_nC/Zn​ with cone angles 2π/n2π/n2π/n, which are embedded as subspaces in the phase space C\mathbb CC of the classical oscillator. Here Zn{\mathbb Z}_nZn​ is the finite cyclic group of rotations of the space C\mathbb CC by an angle 2π/n2π/n2π/n. The superposition ψ=∑ncnψnψ=\sum_n c_nψ_nψ=∑n​cn​ψn​ of the eigenfunctions ψnψ_nψn​ arises only with incomplete knowledge of the initial data for solving the Schrödinger equation, when the conditions of invariance with respect to the discrete groups Zn{\mathbb Z}_nZn​ are not imposed and the general solution takes into account all possible initial data parametrized by the numbers n∈Nn\in\mathbb Nn∈N.
A renormalized semiclassical quantization method for rescalable Hamiltonians is proposed. A classical Hamilton system having a potential function that consists of homogeneous polynomials like the Coulombic potential can have a scale invariance in its extended phase space (phase space plus time). Consequently, infinitely many copies of a single trajectory constitute a one-parameter family that is characterized in terms of a scaling factor. This scaling invariance in classical dynamics is lost in quantum mechanics due to the presence of the Planck constant. It is shown that in a system whose classical motions have a self-similarity in the above sense, classical trajectories adopted in the semiclassical scheme interact with infinitely many copies of their own that are reproduced by the relevant scaling procedure, thereby undergoing quantum interference among themselves to produce a quantized spectrum.