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The Journal of Chemical Physics

Green's Function for Noninteracting Particles

Bernard J. Laurenzi

Published Apr 15, 1969• 10 citations
Publisher

Abstract

The Green's function for N identical noninteracting particles has been obtained. Some calculations in perturbation theory are explored.
DOI
10.1063/1.1671588

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Despite its centrality in the mathematical structure of perturbative many-body theory, the total Green's function for the many-body time-dependent Schrodinger equation has been ignored for decades, superseded by single-particle Green's functions, for which a vast portion of the literature has been devoted. In this paper, we give the first computation the total Green's function for the time-dependent Schrodinger equation for a non-interacting system of identical particles, setting the stage for a fresh interpretation of perturbative many-body physics.
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I review the way the many-body Green functions are used to renormalize the perturbation theory of correlated fermions. The Green functions are introduced to implement systematically dynamical corrections to the static mean-field theory. The renormalizations enter the perturbation theory via self-consistent evaluations of one-particle and two-particle Green functions. The one-particle self-consistency is discussed within the Baym-Kadanoff construction. We point to an inherent dichotomy of the Baym-Kadanoff approach in the relation between one and two-particle Green functions. They are the Schwinger-Dyson equation, directly derived from the generating Luttinger-Ward functional, and the Ward identity. The latter imposes a severe restriction on the two-particle irreducible vertex and is not guaranteed in the Baym-Kadanoff approach. No approximate theory is capable to obey both relations. I further discuss the two-particle approach with two-particle renormalizations that offers a way to reconcile the Schwinger-Dyson equation and the Ward identity. The two-particle irreducible vertex from the critical Bethe-Salpeter equation becomes a generating functional in the two-particle renormalization of the perturbation theory. The irreducible vertex is used in the Ward identity to determine the order parameter beyond the critical point and in the Bethe-Salpeter equation representing the vertex of the Schwinger-Dyson equation to determine the spectral self-energy in such a way that the thermodynamic critical behavior from both equations is qualitatively the same. Finally, I discuss a static mean-field-like approximation with a renormalized effective interaction determined self-consistently that leads to a qualitatively correct description of strong electron correlations in impurity and lattice models.