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International Journal of Quantum Chemistry

Equilibrium and nonequilibrium theory of dilute Bose gases

Yves Pomeau A

Published Jan 1, 2004• 0 citations
Publisher

Abstract

Abstract The explanation of the phenomenon of superfluidity requires an in‐depth analysis of both equilibrium and nonequilibrium statistics. This can be done in dilute gases by a systematic expansion in powers of the density, as done for classical gases in Prigogine's book on kinetic theory. Following the method of expansion of Prigogine and Résibois, the thermodynamics of a dilute gas of N identical Bosons with condensate can be studied in the case of a superflow, that is, of a finite and uniform velocity difference between the normal and superfluid component (assumed at rest). The microscopic interactions between the two components conserve the momentum of the normal component, making it a thermodynamic parameter. No thermal equilibrium exists if the velocity difference is larger than a critical value far below the onset of dissipation given by Landau's criterion. Consequences of this are discussed. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004

DOI
10.1002/qua.10834

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Abstract The explanation of the phenomenon of superfluidity requires an in‐depth analysis of both equilibrium and nonequilibrium statistics. This can be done in dilute gases by a systematic expansion in powers of the density, as done for classical gases in Prigogine's book on kinetic theory. Following the method of expansion of Prigogine and Résibois, the thermodynamics of a dilute gas of N identical Bosons with condensate can be studied in the case of a superflow, that is, of a finite and uniform velocity difference between the normal and superfluid component (assumed at rest). The microscopic interactions between the two components conserve the momentum of the normal component, making it a thermodynamic parameter. No thermal equilibrium exists if the velocity difference is larger than a critical value far below the onset of dissipation given by Landau's criterion. Consequences of this are discussed. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004
In a dilute Bose gas the interaction between the normal gas and the condensate can be studied both at equilibrium and for its relevance to superfluid mechanics. In this article, one reviews first the thermodynamics of the interacting Bose gas in the low density limit and in the low temperature–finite density case. This is extended to thermodynamics with a velocity difference between the two components, normal and superfluid. It is argued that, if the initial value of the momentum related to this velocity difference is larger than the one given by thermodynamic stability, a new condensate should form in a finite time with a velocity close to the that of the normal gas. In the dilute case this occurrence of a new condensate is reminiscent of the condensation in the isotropic case at high enough density.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2L^2L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01\textit{Full-text embargoed until: 2026-01-01}Full-text embargoed until: 2026-01-01
Abstract This chapter presents a general discussion of the phenomenon of superfluidity, starting from the famous Landau criterion for the critical velocity. The Landau expression for the normal (non-superfluid) component of the gas, expressed in terms of the elementary excitations of the system, is derived. The relationship between Bose–Einstein condensation and the phenomenon of superfluidity is outlined, with special focus on the role played by the phase of the order parameter, whose gradient fixes the velocity of the superfluid. The chapter derives the hydrodynamic equations of superfluids at both zero and finite temperatures and discuss the solutions for first and second sound. The formalism of quantum hydrodynamics is presented, with an application to the Beliaev decay of phonons and to the calculation of the fluctuations of the phase. It also discusses the consequences for superfluidity on the rotational properties and the spatial structure of vortex lines.
We investigate an ultracold and dilute Bose gas by taking into account a finite-range two-body interaction. The coupling constants of the resulting Lagrangian density are related to measurable scattering parameters by following the effective-field-theory approach. A perturbative scheme is then developed up to the Gaussian level, where both quantum and thermal fluctuations are crucially affected by finite-range corrections. In particular, the relation between spontaneous symmetry breaking and the onset of superfluidity is emphasized by recovering the renowned Landau’s equation for the superfluid density in terms of the condensate one.
In Chapter 15, we showed that in the limit of short collision times the coupled equations of motion for the condensate and noncondensate atoms lead to Landau's non-dissipative two-fluid hydrodynamics. However the approach used in Chapter 15 was not based on a small expansion parameter, in contrast with the more systematic Chapman–Enskog procedure used to derive hydrodynamic damping in the kinetic theory of classical gases. In the present chapter, we generalize the procedure of Chapter 15 to trapped Bose-condensed gases, in order to derive two-fluid hydrodynamic equations that include dissipation due to transport processes. We solve the kinetic equation by expanding the nonequilibrium single-particle distribution function f ( p, r , t ) around the distribution function f (0) ( p, r , t ) that describes complete local equilibrium between the condensate and the noncondensate components. All hydrodynamic damping effects are included by taking into account deviations from the local equilibrium distribution function f (0) . Our discussion for a trapped Bose gas is a natural extension of the pioneering work of Kirkpatrick and Dorfman (1983, 1985a) for a uniform Bose-condensed gas. This chapter is mainly based on their work as well as on Nikuni and Griffin (2001a,b). We will prove that, with appropriate definitions of various thermodynamic variables, our two-fluid hydrodynamic equations including damping have precisely the structure of those first derived by Landau and Khalatnikov for superfluid He. In particular, the damping associated with the collisional exchange of atoms between the condensate and noncondensate components, which is discussed at length in Chapter 15, is now expressed in terms of frequency-dependent second viscosity coefficients. This special type of damping is a characteristic signature of a dilute Bose superfluid and exists in addition to the hydrodynamic damping associated with the shear viscosity and thermal conductivity of the normal fluid.
The discovery of Bose Einstein condensation (BEC) in trapped ultracold atomic gases in 1995 has led to an explosion of theoretical and experimental research on the properties of Bose-condensed dilute gases. The first treatment of BEC at finite temperatures, this book presents a thorough account of the theory of two-component dynamics and nonequilibrium behaviour in superfluid Bose gases. It uses a simplified microscopic model to give a clear, explicit account of collective modes in both the collisionless and collision-dominated regions. Major topics such as kinetic equations, local equilibrium and two-fluid hydrodynamics are introduced at an elementary level. Explicit predictions are worked out and linked to experiments. Providing a platform for future experimental and theoretical studies on the finite temperature dynamics of trapped Bose gases, this book is ideal for researchers and graduate students in ultracold atom physics, atomic, molecular and optical physics and condensed matter physics.