Description of States in Quantum Mechanics by Density Matrix and Operator Techniques

Bernard d’Espagnat

Along with an elementary description of the well-known density matrix formalism and of its application to the description of quantum-statistical ensembles, this chapter includes the proofs of a few propositions that are especially useful for understanding most of the developments. In the new formulation, ensembles are directly described by density matrices, observables are still described by Hermitean operators, and the rules giving the statistical distribution and the mean values of the predicted measurement results are, respectively, expressions. When stated in this manner, the rules of quantum mechanics apply directly not only to pure states but also to mixtures. This is a distinct advantage. In the case of mixtures defined by their density matrices, the new formulation also has another merit. If two proper mixtures are described by the same density matrix, any state vector representing a subensemble of one of these mixtures can be expressed as a linear combination of the state vectors representing the subensembles of the other mixture.

Mark G. Kuzyk

Students in quantum mechanics class are taught that the wave function contains all knowable information about an isolated system. Later in the course, this view seems to be contradicted by the mysterious density matrix, which introduces a new set of probabilities in addition to those that are built into the wave function. This paper brings attention to the fact that the density matrix can be reconciled with the underlying quantum-mechanical description using a two-particle entangled state with a one-particle subsystem as the simplest illustration of the basic principle. The extra-quantum probabilities are traced to the coefficients of superposition of the quantum state vector and the seemingly irreversible exponential population decay is shown to be compatible with the unitary time evolution of a pure state when the two particles interact. The two-particle universe thus provides the student with a tool for understanding how the density operator, with all its richness, emerges from quantum mechanics.

Steven M. Moore

Narasimhaiengar Mukunda

Jarosław K. Korbicz, F. Hulpke, Andreas Osterloh +1 more

We present a description of finite-dimensional quantum entanglement based on a study of the space of all convex decompositions of a given density matrix. On this space we construct a system of real polynomial equations describing separable states. We further study this system using methods of statistical mechanics. As an example, we finally apply our techniques to Werner states of two qubits and obtain a sufficient criterion for separability.