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The European Physical Journal D

Calculation of the 1s–2s two-photon excitation cross-section in atomic hydrogen

Gültekin Çelik, Zeliha Esin Çelik, Hamdi Şükür Kılıç

Published Dec 1, 2008• 1 citation
Publisher
DOI
10.1140/epjd/e2008-00233-9

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Optics Letters•Jan 1, 1989•21 citations
Excitation of a model hydrogen atom by a coherent electron beam is calculated by direct solution of the time-dependent Schrödinger equation on a three-dimensional lattice. The Coulomb interaction between the electrons is described by v ( r 1 , r 2 ) = 1/r > and all angular momenta are set to zero. The coherent beam consists of moving wavepackets for each of two free electrons which arrive at the third bound electron at different times. As recently predicted by Robicheaux and Noordam (2000 Phys. Rev. Lett. 84 3735), the probability for a weak excitation should vary as a function of arrival time. The time-dependent calculations for the model hydrogen atom show that the 1s → 2s excitation probability oscillates about an axis which is between one and two times the excitation probability from only one wavepacket. The frequency of the probability oscillation is found to be equal to the 1s → 2s transition frequency. Large destructive interference of the 1s → 2s cross section is illustrated by contour maps of the 2s projected probability as a function of wavepacket arrival time.
Two-photon-resonant, three-photon ionization of atomic hydrogen and deuterium is performed at 243 nm, and the ions are detected by time-of-flight mass spectrometry. The power dependence of the 1S-2S two-photon excitation and one-photon ionization of 2S hydrogen and deuterium are determined. The ionization step saturates at 4 x 10(6) W/cm(2). The two-photon step-power dependence varies with laser linewidth, with saturation occurring between 1 x 10(7) and 3 x 10(7) W/cm(2). The extraction electric field in the mass spectrometer does not affect the 2S excitation. Strong signals are recorded at atomic concentrations of 10(5) atoms/cm(3). Nonresonant ionization of background gases producing H(+) and D(+) is minimized.