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Polymer

Short-time Monte Carlo study on the phase transition of a ferromagnetic polymer chain model

Meng‐Bo Luo, Chang-Ji Qian

Published Jan 19, 2006• 10 citations
Publisher
DOI
10.1016/j.polymer.2005.12.075

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In this work, the phase diagram of the ferromagnetic Ising model with dipole interactions is revisited with the aim of determining the nature of the phase transition between stripe-ordered phases with width nnn (hn)({h}_{n})(hn​) and tetragonal liquid (TL) phases. Extensive Monte Carlo simulations are performed in order to study the short-time dynamic behavior of the observables for selected values of the ratio between the ferromagnetic exchange and dipolar constants $\ensuremath{\delta}$. The obtained results indicate that the h1{h}_{1}h1​-TL phase transition line is continuous up to $\ensuremath{\delta}=1.2585$, while for the h2{h}_{2}h2​-TL line a weak first-order character is found in the interval $1.2585\ensuremath{\le}\ensuremath{\delta}\ensuremath{\le}1.36$ and becomes continuous for $1.37\ensuremath{\le}\ensuremath{\delta}\ensuremath{\le}1.9$. This result suggests the existence of a tricritical point close to $\ensuremath{\delta}=1.37$. When it is appropriate, the complete set of critical exponents is obtained, and in all the studied cases they depend on $\ensuremath{\delta}$ but do not belong to the Ising universality class. Furthermore, short-time dynamic studies reveal that at the point where the mentioned lines meet the ${h}_{1}\ensuremath{-}{h}_{2}$ line, i.e., at $\ensuremath{\delta}=1.2585$, the critical phase corresponding to the ${h}_{1}\ensuremath{-}\mathrm{TL}$ transition coexists with the h2{h}_{2}h2​ phase.