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On the relation between indistinguishability of identical particles and (anti)symmetry of the wave function in quantum mechanics

Willem M. de Muynck, Gidi P. van Liempd

Published Jun 1, 1986• 4 citations
Publisher
DOI
10.1007/bf00485944

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Abstract One of the outstanding differences between classical theory and quantum mechanics is the importance which the latter attaches to the identity of particles. Although perfectly well realised before the introduction of modern quantum theory, the fact that two electrons are experimentally indistinguish­able did not introduce any novel features into the dynamics of many electron systems on Bohr’s theory. However, Heisenberg showed that these identity relations are of fundamental importance in many body problems, and was able to explain the formerly very puzzling characteristic of the spectrum of neutral helium, its division into two non-combining term systems. Owing to the identity of the particles, the wave function representing such a system must have certain symmetry properties; for the particles known in Nature this symmetry characteristic is that the function be either symmetric or anti-symmetric in the co-ordinates of the particles. For particles with a spin such as the electron and proton, only antisymmetry is allowed (Pauli’s principle), while for α-particles the wave function must be symmetrical. Since Heisenberg’s explanation of the helium spectrum the theory of anti-symmetric electron wave functions has been extended to describe the general features of the spectra of all atoms, while it appears from the work of Heitler and London that the theory is of fundamental importance in the explanation of chemical combination between atoms. Again, in furnishing a new statistics it is an essential feature of the theory of metals. As the effect of the identity relations depends on the fact that exchanging the electrons does not alter the system in any way, these effects are known as exchange phenomena.
Symmetries and wave functions An important difference between the classical and quantum perspectives is their different criteria of distinguishability. Identical particles are classically distinguishable when separated in phase space. On the other hand, identical particles are always quantum mechanically indistinguishable for the purpose of counting distinct microstates. But these concepts and these distinctions do not tell the whole story of how we count the microstates and determine the multiplicity of a quantized system. There are actually two different ways of counting the accessible microstates of a quantized system of identical, and so indistinguishable, particles. While these two ways were discovered in the years 1924–1926 independently of Erwin Schrödinger’s (1887–1961) invention of wave mechanics in 1926, their most convincing explanation is in terms of particle wave functions. The following two paragraphs may be helpful to those familiar with the basic features of wave mechanics. A system of identical particles has, as one might expect, a probability density that is symmetric under particle exchange, that is, the probability density is invariant under the exchange of two identical particles. But here wave mechanics surprises the classical physicist. A system wave function may either keep the same sign or change signs under particle exchange. In particular, a system wave function may be either symmetric or antisymmetric under particle exchange.
We investigate indistinguishability of identical bosons and fermions undergoing arbitrary particle-number-preserving evolutions of their visible degrees of freedom. For the projective indistinguishability measure, defined by the projection of the visible state onto the symmetric/anti-symmetric subspace, we derive an equivalent expression in terms of the dynamically invariant internal state. We further generalize the textbook symmetrization/anti-symmetrization framework for bosons and fermions to arbitrary partial distinguishability by deriving an explicit reconstruction formula for the multiparticle visible state in terms of the indistinguishability function encoding the dynamical invariants. We give complete characterization of the class-functions of indistinguishability by projective measures on generalized symmetries. Finally, we reveal a strikingly counterintuitive effect: introducing additional particle label states can increase the multiparticle indistinguishability of identical particles. The effect originates from the cancellation of collective multiparticle phases.