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Chemical Physics Letters

Two-electron-one-photon transitions in polycenter systems

Alexander A. Berezin

Published Feb 1, 1984• 4 citations
Publisher
DOI
10.1016/0009-2614(84)80200-6

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We have studied two-electron one-photon transitions in dielectronic recombination with H-like ions (Z=5−−54Z=5--54Z=5−−54) within ab initio QED theory. It was found that interference between dielectonic recombination with two-electron one-photon transitions and radiative recombination is prominent for light and medium ions being large enough for experimental observation. The interference manifests itself firstly in a sharp Fano-like resonance structure and secondly in a noticeable distortion of the photon angular distribution of the radiative recombination.
We consider one-photon ionization in a system consisting of two different atoms, AAA and BBB, which are well separated in space. In such a case, photoionization of the atom with a lower ionization potential can be very strongly influenced, via two-center electron-electron correlations, by resonant electron dipole transitions induced in the other atom. We present a detailed consideration of this resonant photoionization process and discuss a number of effects that are inherent to it.