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Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

First-order phase transitions, the Maxwell construction, and the momentum-space renormalization group

Alberto Parola, Davide Pini, L. Reatto

Published Nov 1, 1993• 38 citations
Publisher

Abstract

The behavior of a nonperturbative momentum-space renormalization group (RG) is analyzed both above and below the critical temperature. The case of a scalar order parameter and of the Ising model is studied in detail by analytical and numerical means. It is shown that this RG transformation is always well defined even inside the coexistence curve. van der Waals loops are suppressed by long-wavelength fluctuations which enforce the convexity of the free energy. The RG description emerging from this study is then compared with exact results and other approximate theories.

DOI
10.1103/physreve.48.3321

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The behavior of a nonperturbative momentum-space renormalization group (RG) is analyzed both above and below the critical temperature. The case of a scalar order parameter and of the Ising model is studied in detail by analytical and numerical means. It is shown that this RG transformation is always well defined even inside the coexistence curve. van der Waals loops are suppressed by long-wavelength fluctuations which enforce the convexity of the free energy. The RG description emerging from this study is then compared with exact results and other approximate theories.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.
The perturbative approach to the description of long-wavelength excitations at high temperature breaks down near the critical point of a second order phase transition. We study the dynamics of these excitations in a relativistic scalar field theory at and near the critical point via a renormalization group approach at high temperature and an $\ensuremath{\epsilon}$ expansion in $d=5\ensuremath{-}\ensuremath{\epsilon}$ space-time dimensions. The long-wavelength physics is determined by a nontrivial fixed point of the renormalization group. At the critical point we find that the dispersion relation and width of quasiparticles of momentum p are ${\ensuremath{\omega}}_{p}\ensuremath{\sim}{p}^{z}$ and ${\ensuremath{\Gamma}}_{p}\ensuremath{\sim}(z\ensuremath{-}1){\ensuremath{\omega}}_{p},$ respectively, and the group velocity of quasiparticles ${v}_{g}\ensuremath{\sim}{p}^{z\ensuremath{-}1}$ vanishes in the long-wavelength limit at the critical point. Away from the critical point for $T\ensuremath{\gtrsim}{T}_{c}$ we find ${\ensuremath{\omega}}_{p}\ensuremath{\sim}{\ensuremath{\xi}}^{\ensuremath{-}z}[1+(p\ensuremath{\xi}{)}^{2z}{]}^{1/2}$ and ${\ensuremath{\Gamma}}_{p}\ensuremath{\sim}(z\ensuremath{-}1){\ensuremath{\omega}}_{p}(p\ensuremath{\xi}{)}^{2z}/[1+(p\ensuremath{\xi}{)}^{2z}]$ with $\ensuremath{\xi}$ the finite temperature correlation length $\ensuremath{\xi}\ensuremath{\propto}|T\ensuremath{-}{T}_{c}{|}^{\ensuremath{-}\ensuremath{\nu}}.$ The new dynamical exponent z results from anisotropic renormalization in the spatial and time directions. For a theory with O(N)O(N)O(N) symmetry we find $z=1+\ensuremath{\epsilon}{(N+2)/(N+8)}^{2}+\mathcal{O}({\ensuremath{\epsilon}}^{2}).$ This dynamical critical exponent describes a new universality class for dynamical critical phenomena in quantum field theory. Critical slowing down, i.e., a vanishing width in the long-wavelength limit, and the validity of the quasiparticle picture emerge naturally from this analysis.
The description of first-order phase transitions using the linear renormalization group is illustrated with the two-dimensional Ising model. Different linear renormalization groups should be used to describe the system in the neighborhood of criticality and away from it. In the latter case, the renormalization-group trajectories are lines of constant spin expectation value, which map a system below critical temperature in a small magnetic field to a system of free spins at a finite magnetic field. A finite-lattice approximation is also presented. The equation of state and several thermodynamic quantities are obtained; a smooth matching of the behavior near and away from criticality occurs naturally.
We show by a detailed study of the mean-field approximation, the Gaussian approximation, the perturbation expansion, and the field-theoretic renormalization-group analysis of a φ3φ^{3}φ3 theory that its instability fixed points with their associated instability exponents are quite probably relevant to the scaling and universality behavior exhibited by the first-order phase transitions in a field-driven scalar ϕ4ϕ^4ϕ4 model below its critical temperature near their instability points. Finite-time scaling and leading corrections to scaling are considered. We also show that the instability exponents of the first-order phase transitions equal those of the Yang--Lee edge singularity and employ the latter to improve our estimates of the former. The outcomes agree well with existent numerical results.
Through a detailed study of the mean-field approximation, the Gaussian approximation, the perturbation expansion, and the field-theoretic renormalization-group analysis of a φ 3 theory, we show that the instability fixed points of the theory, together with their associated instability exponents, are quite probably relevant to the scaling and universality behavior exhibited by the first-order phase transitions in a field-driven scalar ϕ 4 model, below its critical temperature and near the instability points. Finitetime scaling and leading corrections to the scaling are considered. We also show that the instability exponents of the first-order phase transitions are equivalent to those of the Yang–Lee edge singularity, and employ the latter to improve our estimates of the former. The outcomes agree well with existing numerical results.
We propose an implementation of the nonperturbative renormalization group (NPRG) which applies to lattice models. Contrary to the usual NPRG approach where the initial condition of the RG flow is the mean-field solution, the lattice NPRG uses the (local) limit of decoupled sites as the (initial) reference system. In the long-distance limit, it is equivalent to the usual NPRG formulation and therefore yields identical results for the critical properties. We discuss both a lattice field theory defined on a d-dimensional hypercubic lattice and classical spin models. The simplest approximation, the local potential approximation, is sufficient to obtain the critical temperature and the magnetization of the three-dimensional Ising, XY, and Heisenberg models to an accuracy on the order of 1%. We show how the local potential approximation can be improved to include a nonzero anomalous dimension η and discuss the Berezinskii-Kosterlitz-Thouless transition of the two-dimensional XY model on a square lattice.