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European Journal of Physics

Harmonic oscillator quantization: kinetic theory approach

Mark Denny

Published Jan 30, 2002• 2 citations
Publisher

Abstract

The exact harmonic oscillator energy distribution, including zero-point energy, is derived from a random walk calculation. The Planck distribution for blackbody radiation is found as a special case, in which the number of oscillators is not constrained. Connection with the correspondence principle sheds light upon the special historical role of harmonic oscillators in the development of quantum mechanics.

DOI
10.1088/0143-0807/23/2/312

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The exact harmonic oscillator energy distribution, including zero-point energy, is derived from a random walk calculation. The Planck distribution for blackbody radiation is found as a special case, in which the number of oscillators is not constrained. Connection with the correspondence principle sheds light upon the special historical role of harmonic oscillators in the development of quantum mechanics.
We apply the theory of stochastic electrodynamics to the study of the (nonrelativistic) harmonic oscillator by using the Fokker–Planck method. It is demonstrated that the equilibrium distribution in phase space is exactly equal to that given by quantum statistical mechanics, i.e., the corresponding Wigner distribution, and that analysis of this distribution by means of a decomposition in terms of canonical densities leads automatically to the usual description of quantum mechanics in terms of excited states. All fundamental equations of quantum mechanics are recovered as aprproximations to zero order in the radiation terms; the first-order terms lead to the radiative corrections predicted by quantum electrodynamics, namely, the decay of states and the Lamb shift of the energy levels. The necessary differences between both treatments of the oscillator and their implications are briefly discussed.
According to Planck's first theory (1900) the best expression for the average energy of an harmonic oscillator at high temperature is not kT but kT- 1 / 2 h nu . A second theory of Planck (1911) restores the expression kT, and also predicts zero-point energy. A discussion is given in terms of the correspondence principle, which, it is stressed, is active, rather than passive, in nature. Planck's second theory is then discussed in more detail, including the use made of it by Bohr (1918), both in the construction of his atomic theory, and in his development of the correspondence principle itself.
An earlier study of quantum-mechanical time has suggested that, from the quantum-theoretic point of view, time is a random variable. The present work explores how such a description of time can be used to bring greater detail into the analysis of the one-dimensional harmonic oscillator. Specifically, the classical equations for harmonic motion are used as a point transformation between phase space and time-energy space, permitting probability distributions in the two spaces to be different representations of the same thing. The familiar energy-quantization hypothesis is supplemented with the hypothesis that quantized energy values are means (averages) of energy distributions characteristic of each energy state. With the probability distribution of time determined from the previously cited study, the desired quantized energy distributions follow from the requirements: (1) that they should be normalized, non-negative, and with means equal to the quantized energy values; (2) that the equivalent representation of distribution in position-momentum space should have marginal densities that are proportional (except near the origin) to the densities in position and momentum, ${|\ensuremath{\phi}(q)|}^{2}$ and ${|\ensuremath{\psi}(p)|}^{2}$, which are postulated in quantum theory. Requirement (2) is a weakening of the Born postulate. In the time-energy space, the probability distributions exclude energies smaller than the mode (energy value with maximum probability). In position-momentum space this exclusion requirement becomes the dynamical restriction: $\frac{{q}^{2}m{\ensuremath{\omega}}^{2}}{2}+\frac{{p}^{2}}{2m}\ensuremath{\ge}\frac{{\ensuremath{\Lambda}}_{n}\ensuremath{\hbar}\ensuremath{\omega}}{2}$, where, for the first three energy states, ${\ensuremath{\Lambda}}_{0}=0$, ${\ensuremath{\Lambda}}_{1}=\frac{3}{2}$, ${\ensuremath{\Lambda}}_{2}=2+\ensuremath{\surd}\frac{3}{2}$. In general terms it is thus shown that the quantized harmonic oscillator can be described as a statistical ensemble of classical oscillators. Some comparisons with work on phase-space formulations of quantum mechanics (especially with the work of Wigner) are made and some aspects of the theory that should submit to experimental verification are pointed out.
The physics of quantum electromagnetism in an absorbing medium is that of a field of damped harmonic oscillators. Yet until recently the damped harmonic oscillator was not treated with the same kind of formalism used to describe quantum electrodynamics in a arbitrary medium. Here we use the techniques of macroscopic QED, based on the Huttner--Barnett reservoir, to describe the quantum mechanics of a damped oscillator. We calculate the thermal and zero-point energy of the oscillator for a range of damping values from zero to infinity. While both the thermal and zero-point energies decrease with damping, the energy stored in the oscillator at fixed temperature increases with damping, an effect that may be experimentally observable. As the results follow from canonical quantization, the uncertainty principle is valid for all damping levels.
Dirac's Poisson-bracket-to-commutator analogy for the transition from classical to quantum mechanics assures that for many systems, the classical and quantum systems share the same algebraic structure. The quantum side of the analogy (involving operators on Hilbert space with commutators scaled by Planck's constant ℏ) not only gives the algebraic structure but also dictates the average values of physical quantities in the quantum ground state. On the other hand, the Poisson brackets of nonrelativistic mechanics, which give only the classical canonical transformations, do not give any values for physical quantities. Rather, one must go outside nonrelativistic classical mechanics in order to obtain a fundamental phase space distribution for classical physics. We assume that the values of physical quantities in classical theory at any temperature depend on the phase space probability distribution that arises from thermal radiation equilibrium including classical zero-point radiation with the scale set by Planck's constant ℏ. All mechanical systems in thermal radiation will inherit the constant ℏ from thermal radiation. Here, we note the connections between classical and quantum theories (agreement and contrasts) at all temperatures for the harmonic oscillator in one and three spatial dimensions.
The development of a quantum-mechanical formalism for systems with dissipation that was presented in an earlier article, and intended mainly for application to the electromagnetic field in a cavity, is extended. The problem of the harmonic oscillator with dissipation is shown to be the same as that of a harmonic oscillator coupled to a thermal reservoir, and the need of the formalism to contain the appropriate statistical mechanics is discussed. The derivation of relationships which permit the calculation of all moments of the oscillator coordinate and momentum provides the necessary extension of the theory. The formal resemblance of the completed theory to that of classical Brownian motion, some differences due to quantum mechanics, and the fact that certain fundamental relationships which are assumed in the latter are derived in the present analysis, are pointed out. The application of the theory is illustrated by the consideration of three problems: the proof of Ott's formula, and the derivation of both the probability density and energy distribution of the oscillator in equilibrium with a thermal reservoir.