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Journal of Experimental and Theoretical Physics

Quantum kinetic Boltzmann equation taking into account the resonant exchange of excitations

T. L. Andreeva, P. L. Rubin

Published Mar 1, 1997• 0 citations
Publisher

Abstract

A derivation of the quantum Boltzmann equation is given for identical particles with internal degrees of freedom. It is shown that the off-diagonal (with respect to the internal degrees of freedom) term of the equation contains an energy pole term, which is not present in the most commonly used kinetic equation, known as the Waldmann-Snider equation. The physical conditions underlying the occurrence of the pole term in the quantum kinetic equation are analyzed.

DOI
10.1134/1.558162

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A derivation of the quantum Boltzmann equation is given for identical particles with internal degrees of freedom. It is shown that the off-diagonal (with respect to the internal degrees of freedom) term of the equation contains an energy pole term, which is not present in the most commonly used kinetic equation, known as the Waldmann-Snider equation. The physical conditions underlying the occurrence of the pole term in the quantum kinetic equation are analyzed.
Quantum coherent phenomena in Boltzmann gases are studied on the basis of the generalized Waldmann-Snider kinetic equation. The equation takes into account the effects of quantum identity of particles. The conditions are formulated for the propagation of different collective modes in gases of particles with arbitrary internal degrees of freedom. Collective coherent effects are macroscopic manifestations of the molecular field for the transverse (off-diagonal) elements of particle distribution in a ``polarized'' system (a system with a nonuniform population of internal energy levels in an unperturbed state). The simplest results are obtained for particles with equidistant internal-energy levels exploiting the analogy with spin-polarized quantum gases. The accurate study of nonlocal interaction terms permits one to compare classical-kinetic and Fermi-liquid approaches to kinetic phenomena in dilute gases, and shows the limitations of both approaches. In the case of collective modes, more accurate schemes of derivation of the kinetic equation must be accompanied by the simultaneous calculations of nonlocal contributions.
The quantum Boltzmann equation governing the evolution of the one-body internal density matrix of an atomic hydrogen (or alkali) gas is established. Indistinguishability of both nuclei and electrons explains the presence in the collision term of a large number (eleven) of « exchange cross sections ». The different collision terms fall into two categories : these which contribute to the damping of perturbations (similar to the usual collision term in the classical regime) and those which are Hamiltonian like and originate from the « identical spin rotation effect ». Due to those numerous exchange terms, all transport properties in atomic hydrogen are very sensitive to the internal state of the gas.
A bstract We study the kinetic theory of a weakly interacting quantum field. Assuming a state that is close to homogeneous and stationary, we derive a closed kinetic equation for the rate of change of the occupation numbers, perturbatively in the coupling. For a dilute gas, this reproduces the quantum Boltzmann equation, which only accounts for two-to-two scattering processes. Our expression goes beyond this, with terms accounting for multi-particle scattering processes, which are higher order in the density.
Starting from the Dyson equation in the Keldysh formulation, we derive a kinetic equation for steady-state quantum transport under the simplifying assumption that the inelastic scattering is caused by uncorrelated point scatterers, such as impurities with internal degrees of freedom. This assumption allows us to write a transport equation that involves only the electron density and not the spatial correlations of the wave function. Assuming local thermodynamic equilibrium we then simplify the transport equation to a form which resembles the B\"uttiker-Landauer formula extended to include a continuous distribution of probes.
In the framework of real-time Green's functions, the general kinetic equations are investigated in a first-order gradient expansion. Within this approximation, the problem of the reconstruction of the two-time correlation functions from the one-time Wigner function was solved. For the Wigner function, a cluster expansion is found in terms of a quasiparticle distribution function. In equilibrium, this expansion leads to the well-known generalized Beth-Uhlenbeck expression of the second virial coefficient. As a special case, the T-matrix approximation for the self-energy is investigated. The quantum kinetic equation derived thus has, besides the (Markovian) Boltzmann collision integral, additional terms due to the retardation expansion which reflect memory effects. Special interest is paid to the case that bound states exist in the system. It is shown that the bound state contribution, which can be introduced via a bilinear expansion of the two-particle T matrix, follows from the first-order retardation term in the general kinetic equation. The full Wigner function is now a sum of one function describing the unbound particles and another one for the bound state contribution. The latter two functions have to be determined from a coupled set of kinetic equations. In contrast to the quantum Boltzmann equation, energy and density of a nonideal system are conserved. \textcopyright{} 1996 The American Physical Society.