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Physical Review A

System of Bosons with Attractive Interactions. II. Low-Temperature Properties

K. K. Singh, Satish Kumar

Published Feb 1, 1970• 11 citations
Publisher

Abstract

The work of an earlier paper on the ground-state properties of a system of bosons interacting via a strong short-ranged repulsive potential and a weak long-ranged attractive potential is extended to nonzero temperatures. The technique of temperature-dependent Green's functions is employed. It is shown that with the same restrictions on the two-body potential as imposed in the case of the ground state, it is possible to calculate in a consistent fashion the leading low-temperature contributions to the various thermodynamic functions. The results provide support for Landau's point of view for treating the system at low temperatures as a collection of noninteracting quasiparticles. The isotherms of the system at the low temperatures considered indicate a first-order transition between a phase with a condensate and one without a condensate, and also the possibility, at higher temperatures, of three phases.

DOI
10.1103/physreva.1.497

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In this paper we suggest a new ground-state wave function and low-temperature density matrix for a strongly interacting system of bosons. Our basic assumption is that the system can support long-wavelength phonons and that these can propagate independently of any other mode of motion. We therefore write the ground-state function as the product of two factors. One factor arises from the zero-point motion of the phonons, and we show that it has the form ${\ensuremath{\Pi}}_{i<j}f({r}_{\mathrm{ij}})$, where $\mathrm{ln}f(r)$ has an infinite range. The other factor is assumed to have this same form but with $\mathrm{ln}f(r)$ of finite range; it takes into account the short-range correlations arising from the strong repulsive part of the interparticle potential. The function we have chosen to represent the short-range correlations is not new; functions of this kind were first introduced by Bijl and later by Jastrow. At finite temperatures we use a density matrix for an ensemble of excited phonon states. We find that for small wave vectors $k$, the structure factor $S(k)$ is equal to $\frac{\ensuremath{\hbar}k}{2mc}$, a result that was first derived by Feynman. At a finite temperature $T$, $S(k)$ tends to the constant value $\frac{{k}_{B}T}{m{c}^{2}}$, where $m$ is the mass of the particles and $c$ the velocity of propagation of the phonons. The momentum distribution ${n}_{k}$ has a ${k}^{\ensuremath{-}1}$ singularity at absolute zero and a stronger, ${k}^{\ensuremath{-}2}$ singularity at finite temperatures. The small-$k$ behavior of both $S(k)$ and ${n}_{k}$ is completely controlled by the correlations introduced by the phonons. Both the ground-state function and the density matrix imply that there is a finite fraction of particles in the zero-momentum state in three dimensions; this fraction does not seem to be appreciably affected by the infinite-range correlations introduced by the phonons. We find, however, that these correlations imply that a one-dimensional Bose system does not exhibit Bose-Einstein condensation at any temperature, while a two-dimensional system exhibits Bose-Einstein condensation only at absolute zero.

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Thermodynamics of a Weakly Interacting Bose-Einstein Gas

Tor Haugset, Hårek Haugerud, F. Ravndal

Abstract: The one-loop effective potential for non-relativistic bosons with a delta function repulsive potential is calculated for a given chemical potential using functional methods. After renormalization and at zero temperature it reproduces the standard ground state energy and pressure as function of the particle density. At finite temperatures it is found necessary to include ring corrections to the one-loop result in order to satisfy the Goldstone theorem. It is natural to introduce an effective chemical potential directly related to the order parameter and which uniformly decreases with increasing temperatures. This is in contrast to the the ordinary chemical potential which peaks at the critical temperature. The resulting thermodynamics in the condensed phase at very low temperatures is found to be the same as in the Bogoliubov approximation where the degrees of freedom are given by the Goldstone bosons. At higher temperatures the ring corrections dominate and result in a critical temperature unaffected by the interaction. 1

•Jan 1, 1997•8 citations
The work of an earlier paper on the ground-state properties of a system of bosons interacting via a strong short-ranged repulsive potential and a weak long-ranged attractive potential is extended to nonzero temperatures. The technique of temperature-dependent Green's functions is employed. It is shown that with the same restrictions on the two-body potential as imposed in the case of the ground state, it is possible to calculate in a consistent fashion the leading low-temperature contributions to the various thermodynamic functions. The results provide support for Landau's point of view for treating the system at low temperatures as a collection of noninteracting quasiparticles. The isotherms of the system at the low temperatures considered indicate a first-order transition between a phase with a condensate and one without a condensate, and also the possibility, at higher temperatures, of three phases.
The problem of a system of bosons at zero temperature, interacting via a strong short-ranged repulsive interaction and a weak long-ranged attraction, is treated by the methods of quantum-field theory. It is shown that if the parameters of the attractive part of the interaction are suitably restricted, an approximation to the self-energy parts of the Green's functions, similar to that used by Beliaev for the case of purely repulsive interactions, leads to an excitation spectrum which in the limit of small momenta represents phonons. The approximation also yields an NNN-body bound state corresponding to zero pressure. Apart from minor differences, these results are in agreement with an earlier calculation of Huang.
Thermodynamical properties of an interacting boson system at finite temperatures and zero chemical potential are studied within the framework of the Skyrme-like mean-field toy model. It is assumed that the mean field contains both attractive and repulsive terms. Self-consistency relations between the mean field and thermodynamic functions are derived. It is shown that, for sufficiently strong attractive interactions, this system develops a first-order phase transition via the formation of a Bose condensate. An interesting prediction of the model is that the condensed phase is characterized by a constant total density of particles. It is shown that the energy density exhibits a jump at the critical temperature.
In this paper we suggest a new ground-state wave function and low-temperature density matrix for a strongly interacting system of bosons. Our basic assumption is that the system can support long-wavelength phonons and that these can propagate independently of any other mode of motion. We therefore write the ground-state function as the product of two factors. One factor arises from the zero-point motion of the phonons, and we show that it has the form ${\ensuremath{\Pi}}_{i<j}f({r}_{\mathrm{ij}})$, where lnf(r)\mathrm{ln}f(r)lnf(r) has an infinite range. The other factor is assumed to have this same form but with lnf(r)\mathrm{ln}f(r)lnf(r) of finite range; it takes into account the short-range correlations arising from the strong repulsive part of the interparticle potential. The function we have chosen to represent the short-range correlations is not new; functions of this kind were first introduced by Bijl and later by Jastrow. At finite temperatures we use a density matrix for an ensemble of excited phonon states. We find that for small wave vectors kkk, the structure factor S(k)S(k)S(k) is equal to $\frac{\ensuremath{\hbar}k}{2mc}$, a result that was first derived by Feynman. At a finite temperature TTT, S(k)S(k)S(k) tends to the constant value kBTmc2\frac{{k}_{B}T}{m{c}^{2}}mc2kB​T​, where mmm is the mass of the particles and ccc the velocity of propagation of the phonons. The momentum distribution nk{n}_{k}nk​ has a ${k}^{\ensuremath{-}1}$ singularity at absolute zero and a stronger, ${k}^{\ensuremath{-}2}$ singularity at finite temperatures. The small-kkk behavior of both S(k)S(k)S(k) and nk{n}_{k}nk​ is completely controlled by the correlations introduced by the phonons. Both the ground-state function and the density matrix imply that there is a finite fraction of particles in the zero-momentum state in three dimensions; this fraction does not seem to be appreciably affected by the infinite-range correlations introduced by the phonons. We find, however, that these correlations imply that a one-dimensional Bose system does not exhibit Bose-Einstein condensation at any temperature, while a two-dimensional system exhibits Bose-Einstein condensation only at absolute zero.
In this paper properties of a boson gas at zero temperature are investigated by means of field-theoretic methods. Difficulties arising from the depletion of the ground state are resolved in a simple way by the elimination of the zero-momentum state. The result of this procedure when applied to the calculation of the Green's functions of the system is identical to that of Beliaev. It is then shown generally that for a repulsive interaction the energy E(k)E(\mathrm{k})E(k) of a phonon of momentum k, which is found as the pole of a one-particle Green's function, approaches zero for zero momentum, which means that the phonon spectrum does not exhibit an energy gap.The Green's function method is applied to the calculation of the properties of a low-density boson gas. The next order term beyond that calculated by Lee and Yang, and Beliaev for the ground-state energy is obtained and the general form of the series expansion is found to be $(\frac{{E}_{0}}{\ensuremath{\Omega}})=\frac{1}{2}{n}^{2}{f}_{0}[1+a{(n{{f}_{0}}^{3})}^{\frac{1}{2}}+b(n{{f}_{0}}^{3})\mathrm{ln}n{{f}_{0}}^{3}+c(n{{f}_{0}}^{3})+d{(n{{f}_{0}}^{3})}^{\frac{3}{2}}\mathrm{ln}(n{{f}_{0}}^{3})+\ensuremath{\cdots}],$ where nnn is the density and f0{f}_{0}f0​ is the scattering length for the assumed two-body interaction between the bosons. The coefficients aaa and bbb are independent of the shape of the interaction, and are the only terms thus far calculated. The coefficient bbb is in agreement with the hard-sphere gas calculations of Wu and of Sawada.A discussion is given of the intermediate-density calculation of Brueckner and Sawada, and certain possible improvements in the method of summing a selected set of higher-order terms are proposed.
Abstract: The one-loop effective potential for non-relativistic bosons with a delta function repulsive potential is calculated for a given chemical potential using functional methods. After renormalization and at zero temperature it reproduces the standard ground state energy and pressure as function of the particle density. At finite temperatures it is found necessary to include ring corrections to the one-loop result in order to satisfy the Goldstone theorem. It is natural to introduce an effective chemical potential directly related to the order parameter and which uniformly decreases with increasing temperatures. This is in contrast to the the ordinary chemical potential which peaks at the critical temperature. The resulting thermodynamics in the condensed phase at very low temperatures is found to be the same as in the Bogoliubov approximation where the degrees of freedom are given by the Goldstone bosons. At higher temperatures the ring corrections dominate and result in a critical temperature unaffected by the interaction. 1