We first review the microscopic characterization of Bose-Einstein condensation. We then discusses possibilities of fragmented condensates, where the single-particle density matrix has more than one macroscopic eigenvalue. Afterwards, we turn to several problems in which it is necessary to go beyond the Gross-Pitaevksii approximation to determine the physics of condensates, in particular, the dependence of the transition temperature on interaction strength, and the physics of the regime where the scattering length becomes comparable to or greater than the interparticle spacing.
We first review the microscopic characterization of Bose-Einstein condensation. We then discusses possibilities of fragmented condensates, where the single-particle density matrix has more than one macroscopic eigenvalue. Afterwards, we turn to several problems in which it is necessary to go beyond the Gross-Pitaevksii approximation to determine the physics of condensates, in particular, the dependence of the transition temperature on interaction strength, and the physics of the regime where the scattering length becomes comparable to or greater than the interparticle spacing.
Bose–Einstein condensation can be understood as a macroscopic occupation of a single-particle state. But an alternative definition, which requires only a macroscopic occupation of an arbitrarily small energy band of single-particle states, is also known, referred to as generalized Bose–Einstein condensation, and considered to be thermodynamically more stable. Depending on the number of macroscopically occupied single-particle states in the condensate, three types are then distin-guished. If the number of macroscopically occupied single-particle states is finite but at least one, then the condensation is said to be of type-I. A type-II condensate occurs if infinitely many single-particle states are macroscopically occupied. If a generalized Bose–Einstein condensation without any macroscopically occupied single-particle states is present, then one speaks of a type-III con-densation. In noninteracting Bose gases, it is generally easier to prove the occurrence of generalized Bose–Einstein condensation than to determine its type. While a main step for the former task is to show that the critical density is finite, quite detailed knowledge of the energy gaps of the cor-responding single-particle Hamiltonian at the lower edge of the spectrum is needed for the latter one. In this dissertation, we study the occurrence of a Bose–Einstein condensate in Bose gases that are placed in metrically transitive random potentials. We mainly consider the Poisson random potential. The thermodynamic limit and Dirichlet boundary conditions are used throughout this work. We explore noninteracting Bose gases in arbitrary dimension at positive temperatures and a one-dimensional interacting Bose gas at zero temperature. We provide fairly general sufficient conditions for the random potential that imply the almost sure occurrence of generalized Bose–Einstein condensation in noninteracting Bose gases. These conditions are fulfilled by a Poisson random potential, depending on its single-impurity potential. They are also met by the one-dimensional Luttinger–Sy model, which is a central system in the research area of Bose gases in random potentials, and a generalization thereof. Moreover, we state sufficient energy gap conditions such that one can conclude a type-I condensation in Poisson random potentials. We consider different probabilistic notions here, such as convergence in the rth mean, r P N, in probability, and with probability almost one. In particular, we prove that in the Luttinger–Sy model with infinitely strong random potential a type-I condensation occurs in the rth mean, r P N, if the particle density is greater than the critical one. For the Luttinger–Sy model with a finitely strong random potential, we show the same statement, but with probability almost one. Finally, we discuss the Luttinger–Sy model with a repulsive contact interaction between the particles at zero temperature. We provide sufficient requirements such that a generalized Bose–Einstein condensate almost surely occurs. We also show that the type of the condensate is altered by the interparticle interaction. In particular, we demonstrate a transition from a type-I to a type-III condensate when the strength of the contact interaction is increased. Furthermore, we prove that the interparticle interaction reduces the local particle density.
In the present chapter we consider the structure of the Bose–Einstein condensed state in the presence of interactions. Our discussion is based on the Gross–Pitaevskii equation, which describes the zero-temperature properties of the non-uniform Bose gas when the scattering length a is much less than the mean interparticle spacing. We shall first derive the Gross–Pitaevskii equation at zero temperature by treating the interaction between particles in a mean-field approximation (Sec. 6.1). Following that, in Sec. 6.2 we discuss the ground state of atomic clouds in a harmonic-oscillator potential. We compare results obtained by variational methods with those derived in the Thomas–Fermi approximation, in which the kinetic energy operator is neglected in the Gross–Pitaevskii equation. The Thomas–Fermi approximation fails near the surface of a cloud, and in Sec. 6.3 we calculate the surface structure using the Gross–Pitaevskii equation. In Sec. 6.4 we determine how the condensate wave function ‘heals’ when subjected to a localized disturbance. Finally, in Sec. 6.5 we show how the magnetic dipole–dipole interaction, which is long-ranged and anisotropic, may be included in the Gross–Pitaevskii equation and determine within the Thomas–Fermi approximation its effect on the density distribution. The Gross–Pitaevskii equation In the previous chapter we have shown that the effective interaction between two particles at low energies is a constant in the momentum representation, U 0 = 4π ħ 2 a/m .
In the present chapter we consider the structure of the Bose–Einstein condensed state in the presence of interactions. Our discussion is based on the Gross–Pitaevskii equation, which describes the zero-temperature properties of the non-uniform Bose gas when the scattering length a is much less than the mean interparticle spacing. We shall first derive the Gross–Pitaevskii equation at zero temperature by treating the interaction between particles in a mean-field approximation (Sec. 6.1). Following that, in Sec. 6.2 we discuss the ground state of atomic clouds in a harmonic-oscillator potential. We compare results obtained by variational methods with those derived in the Thomas-Fermi approximation, in which the kinetic energy operator is neglected in the Gross–Pitaevskii equation. The Thomas–Fermi approximation fails near the surface of a cloud, and in Sec. 6.3 we calculate the surface structure using the Gross–Pitaevskii equation. Finally, in Sec. 6.4 we determine how the condensate wave function ‘heals’ when subjected to a localized disturbance. The Gross–Pitaevskii equation In the previous chapter we have shown that the effective interaction between two particles at low energies is a constant in the momentum representation, U 0 = 4πħ 2 a / m . In coordinate space this corresponds to a contact interaction U 0 δ( r – r ′), where r and r ′ are the positions of the two particles. To investigate the energy of man y-body states we adopt a Hartree or mean-field approach, and assume that the wave function is a symmetrized product of single-particle wave functions.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.