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Physica A Statistical Mechanics and its Applications

Quantum dissipation: Dynamics of a particle in a symmetric double well in the presence of non-ohmic friction

Claude Aslangul, No¨elle Pottier, Daniel Saint-James

Published Apr 1, 1988• 14 citations
Publisher
DOI
10.1016/0378-4371(88)90118-5

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The real-time dynamics of a particle in a slightly asymmetric double-well potential in the presence of ohmic dissipation is analysed by using standard quantum-statistical methods. At zero temperature, the particle eventually goes towards the lower potential well; the relaxation has an overall exponential character with possibly small oscillations; at finite temperature, the particle thermalizes over the two wells; two successive exponential regimes are observed in this case. The results about the final average position of the particle agree with the detailed balance principle and are in fact independent of the ohmic assumption. For an ohmic dissipation law, the localization phenomenon which occurs in the perfectly symmetric double-well potential at zero temperature disappears when an asymmetry is present, although a precursor behaviour is displayed for very low values of the asymmetry.
A continuum limit frozen Gaussian approximation is formulated for the reduced thermal density matrix for dissipative systems. The imaginary time dynamics is obtained from a novel generalized Langevin equation for the system coordinates. The method is applied to study the thermal density in a double well potential in the presence of Ohmic-like friction. We find that the approximation describes correctly the delocalization of the density due to quantization of the vibrations in the well. It also accounts for the friction induced reduction of the tunneling density in the barrier region.
We study quantum tunneling in a biased double-well potential in the presence of Ohmic dissipation with a friction coefficient $\ensuremath{\alpha}>1$. The tunneling rate out of the metastable well is calculated in real time as a function of the temperature TTT and bias energy $\ensuremath{\epsilon}$. The T=0T=0T=0 result agrees with a droplet-model calculation in imaginary time. At low temperatures we find an enhancement to the T=0T=0T=0 rate varying as ${(\frac{T}{\ensuremath{\epsilon}})}^{2}$.