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Journal of the Chilean Chemical Society

TOWARDS A QUANTUM MOLECULAR MEASUREMENT THEORY: STERN-GERLACH THOUGHT EXPERIMENTS AT THE INTERFACE OF HILBERT AND REAL SPACES

O. Tapia, Henk Fidder

Published Jun 1, 2004• 0 citations
Publisher

Abstract

Towards a quantum molecular measurement theory: Stern-Gerlach thought experiments at the interface of Hilbert and real spaces
DOI
10.4067/s0717-97072004000200002

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The Stern–Gerlach experiment can play an important role in teaching the formalism of quantum mechanics. In the context of a finite-dimensional Hilbert space students can learn how to prepare a specific quantum state starting from an arbitrary state, issues related to the time evolution of the wave function and quantum measurement. The Stern–Gerlach experiment can also be used to teach the distinction between the physical space where the experiment is performed and the Hilbert space where the state of the system lies, and how information about the state of the system in the Hilbert space can be exploited to interpret the possible outcomes of the experiment in physical space. Students can learn the advantages of choosing an appropriate basis to make predictions about the outcomes of experiments with different arrangements of Stern–Gerlach devices. The latter can also help students understand that an ensemble of identically prepared systems is not the same as a mixture. We discuss student difficulties with the Stern–Gerlach experiment based on written tests and interviews with advanced undergraduate and graduate students in quantum mechanics courses. We also discuss preliminary data which suggest that the Quantum Interactive Learning Tutorial on the Stern–Gerlach experiment is helpful in improving student understanding of these concepts.
ABSTRACT The bulk of experiments and observations that lined the path to quantum mechanics amounted to a backlog of data in need of explanation. A notable exception was the Stern–Gerlach experiment (SGE) designed to test the predictions of the old quantum theory as embodied by the 1913–1916 Bohr–Sommerfeld–Debye atom model. After its initial triumphs, such as the explanation of the astrophysically observed spectrum of , this model was frowned upon in some quarters, mainly because of its ad hoc nature. Otto Stern (1888–1969)—and his close colleague and friend, Max von Laue (1879–1960)—even took a vow: “If this nonsense of Bohr should, in the end, prove to be right, we will quit physics.” Stern would go further yet and, in 1920, devise an experiment—the SGE—to disprove Bohr's model. However, contrary to Stern's expectations, the SGE ruled unequivocally in favor of the model and its amendments. Wolfgang Pauli (1900–1958) quipped: “That should convert even the non‐believer Stern.” And it did: Confronted with the outcome of the SGE, Stern noted in 1961: “I still have objections to the idea of beauty of quantum mechanics. But she is correct.” Ironically, the SGE would epitomize quantum mechanics as we know it: whether quantum measurement, state preparation, coherence, or entanglement—in addition to the quantization of angular momentum and its spatial projections—the SGE has it all. It now seems that the SGE may even impact future studies of the relationship of quantum theory to other pillars of physics, most notably, general relativity. The descendants of the SGE include transformative techniques for the study of the quantum properties of nuclear, atomic, molecular, and condensed‐matter systems, with magnetic resonance imaging being among the most widely used. Key Points Edward Pickering; Williamina Fleming; Pickering series; Bohr‐Sommerfeld‐Debye model of the atom; Otto Stern; Stern‐Gerlach experiment; Bohr magneton; Old Quantum Theory; Spin; nuclear magneton; magnetic dipole moment of the proton; matter‐wave duality; Quantum Mechanics.
The central problem in the quantum theory of measurement, how to describe the process of state reduction in terms of the quantum mechanical formalism, is solved on the basis of the relativity of quantal states, which implies that once the apparatus is detected in a well-defined state, the object state must reduce to a corresponding one. This is a process termed by Schrodinger disentanglement. Here, it is essential to observe that Renninger's negative result does constitute an actual measurement process. From this point of view, Heisenberg's interpretation of his microscope experiment and the Einstein-Podolsky-Rosen arguments are reinvestigated. Satisfactory discussions are given to various experimental situations, such as the Stern-Gerlach-type experiment, successive measurements, macroscopic measurements, and Schrodinger's cat. Finally it is proposed to regard a state vector in quantum mechanics as an irreducible physical construct, in Margenau's sense, that is not further analyzable both mathematically and conceptually.