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Modern Physics Letters B

FINITE-SIZE SCALING ANALYSIS OF THE DECAY OF AN UNSTABLE STATE DURING A FIRST ORDER PHASE TRANSITION

Jorge Viñals, David Jasnow

Published Apr 1, 1988• 4 citations
Publisher

Abstract

We extend standard finite-size scaling methods to study the dynamical evolution of an unstable state far from equilibrium as the system undergoes a first order phase transition. We suggest that the nonequilibrium structure factor S(q, t, L), at late times and for large enough lattice sizes, scales as S(q, t, L)=LdF(qL, t1/x/L). L is the linear dimension of the system and 1/x is the domain growth exponent. We obtain x=2 in the case of the kinetic Ising model with a nonconserved order parameter. For a critical quench in a system with conserved order parameter, scaling of the peak of the structure factor gives 1/x≈0.27. Higher wavenumbers, however, are more consistent with x=3.

DOI
10.1142/s0217984988000126

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We extend standard finite-size scaling methods to study the dynamical evolution of an unstable state far from equilibrium as the system undergoes a first order phase transition. We suggest that the nonequilibrium structure factor S(q, t, L), at late times and for large enough lattice sizes, scales as S(q, t, L)=LdF(qL, t1/x/L). L is the linear dimension of the system and 1/x is the domain growth exponent. We obtain x=2 in the case of the kinetic Ising model with a nonconserved order parameter. For a critical quench in a system with conserved order parameter, scaling of the peak of the structure factor gives 1/x≈0.27. Higher wavenumbers, however, are more consistent with x=3.
The growth of order in Ising models with nonconserved order parameter is considered for quenches to final temperatures T f =0 and T f =T c . The results of numerical simulations in spatial dimension d=2 are presented. In all cases a scaling regime is entered for sufficiently long times, where the characteristic length scale is the 'domain size' L(t) approximately t 1 2/, for T f =0, and the 'nonequilibrium correlation length', xi (t) approximately t 1 z/, for T f =T c . The equal-time correlation function has the expected scaling forms f(r/L(t)) and r -(d-2+ eta ) f c (r/ xi (t)) for T f =0 and T c respectively. The scaling function f c (x) has interesting short-distance behaviour which is elucidated using scaling arguments and by in - and 1/n-expansions. The T=0 scaling function f(x) depends on whether the spin correlations present in the initial conditions are of long or short range, as does the exponent which describes the decay of the autocorrelation function, A(t)=((S i (t))S i (O)) approximately L(t) - . Results for a quench from the equilibrium critical state to T f =0 are consistent with theoretical predictions.
The dynamics of spin fluctuations in nonequilibrium and equilibrium states is studied in the one-phase region above Tc{\mathit{T}}_{\mathit{c}}Tc​. The equal-time structure factor is computed after quenching the system from an infinite temperature to T>Tc{\mathit{T}}_{\mathit{c}}Tc​. The result shows growing spatial patterns which can be scaled with temperature-dependent scaling functions. The different-time (dynamic) structure factor is computed by taking time averages while the system is fluctuating in equilibrium states. The equilibrium autocorrelation decays following a diffusive exponential term and a slower but transient term. The relaxation rate due to the diffusion supports the dynamic scaling.
We have investigated the nonequilibrium critical dynamics of a two-dimensional, spin-exchange (i.e., conserved magnetization), kinetic Ising model following quenches to Tc{\mathit{T}}_{\mathit{c}}Tc​ from random initial states. As in the case of subcritical quenches, we observe dynamical scaling of the equal time order parameter correlation function G(r,t,t), but here the nonequilibrium correlation length grows as L(t)\ensuremath{\sim}t1/z{\mathit{t}}^{1/\mathit{z}}t1/z, where z=4/15 is the usual dynamic critical exponent for this system. Moreover, we find dynamical scaling for correlations with the initial condition G(r,0,t). The temporal decay of autocorrelations at Tc{\mathit{T}}_{\mathit{c}}Tc​ yields a critical exponent ${\ensuremath{\lambda}}_{\mathit{c}}$=1.96\ifmmode\pm\else\textpm\fi{}0.05 for the nonequilibrium dynamics: G(r,0,t)\ensuremath{\approxeq}${\mathit{L}}_{\mathit{c}}^{\mathrm{\ensuremath{-}}\ensuremath{\lambda}}$(t)G\ifmmode \tilde{}\else \~{}\fi{}(r/L(t)).
A one-loop, renormalized, non-Markovian equation of motion for the average order parameter of the time-dependent, scalar, nonconserved Landau-Ginzburg model in the critical region is presented. A new time-dependent length scale, a coherence length of critical-like fluctuations, is defined via a memory-dependent dynamic match condition. Two coupled equations for the new length scale and the average order parameter are numerically solved for instantaneous quenches into the unstable region of the phase diagram. The instantaneous free energy that governs the dynamics is not equal to the adiabatic free energy, and the new length scale increases rapidly in regions of negative instantaneous susceptibility. For quenches at zero external field through the critical temperature the structure factor decomposes into two independent parts at intermediate and late times. The late-time contribution is approximately given by a mean-field, critical structure factor. Both contributions admit scaling forms, albeit with different scaling lengths.
The effect of random impurities (quenched disorder) on the growth of correlations is studied for model A and model B after a sudden quench to Tc{\mathit{T}}_{\mathit{c}}Tc​ from the high-temperature phase (i.e., random initial conditions). Exponents and scaling functions of the nonequilibrium dynamic response function Gk{\mathit{G}}_{\mathit{k}}Gk​(t)=[〈\ensuremath{\partial}${\mathrm{\ensuremath{\varphi}}}_{\mathbf{k}}$(t)/\ensuremath{\partial}${\mathrm{\ensuremath{\varphi}}}_{\mathrm{\ensuremath{-}}\mathbf{k}}$(0)〉] and the structure factor Sk{\mathit{S}}_{\mathit{k}}Sk​(t)=[〈${\mathrm{\ensuremath{\varphi}}}_{\mathbf{k}}$(t)${\mathrm{\ensuremath{\varphi}}}_{\mathrm{\ensuremath{-}}\mathbf{k}}$(t)〉] are calculated to first order in \ensuremath{\epsilon} (\ensuremath{\epsilon}=4-d) for the O(n) model. For a nonconserved order parameter, the scaling form Gk{\mathit{G}}_{\mathit{k}}Gk​(t)=${\mathit{t}}^{\ensuremath{\lambda}/\mathit{z}}$f(kz{\mathit{k}}^{\mathit{z}}kzt) is obtained, with f(0)=const and \ensuremath{\lambda}=\ensuremath{\epsilon}/4+O(${\mathrm{\ensuremath{\epsilon}}}^{2}$), for 1n4. For n>4, random impurities are irrelevant, and \ensuremath{\lambda}=[(n+2)/2(n+8)]\ensuremath{\epsilon}+O(${\mathrm{\ensuremath{\epsilon}}}^{2}$), in agreement with calculations on the pure system. For a conserved order parameter \ensuremath{\lambda}=0, but the scaling function f(x) is nontrivial. For both conserved and nonconserved order parameter, disorder gives rise to algebraically decaying scaling functions.