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Physical review. B, Condensed matter

Universality, irrelevant surface operators, and corrections to scaling in systems with free surfaces and defect planes

Hans Werner Diehl, S. Dietrich, Erich Eisenriegler

Published Mar 1, 1983• 107 citations
Publisher

Abstract

The effects of irrelevant surface perturbations on the local critical behavior of ($4\ensuremath{-}\ensuremath{\epsilon}$)-dimensional $n$-vector models with a free surface or an internal defect plane are investigated with particular attention paid to the corrections to scaling induced by the surface term $\frac{1}{2}c\ensuremath{\int}{\mathrm{surface}}^{}{\ensuremath{\varphi}}^{2}$ near the ordinary transition. A systematic expansion in ${c}^{\ensuremath{-}1}$ is developed. In the case of a semi-infinite system, ${c}^{\ensuremath{-}1}$ couples to the square of the normal derivative of $\ensuremath{\varphi}$. The associated crossover exponent is ${\ensuremath{\Phi}}^{o}=\ensuremath{-}\ensuremath{\nu}$ to all orders in $\ensuremath{\epsilon}$. In the case of an infinite-space model with a defect plane, ${c}^{\ensuremath{-}1}$ couples to the squares of the normal derivatives on either side of the plane and to the product of the normal derivative on one side with the normal derivative on the other side. The latter operator represents perpendicular interactions across the defect plane, while the other two describe parallel interactions between spins on the same side of the plane. The associated crossover exponents are ${\ensuremath{\Phi}}_{\ensuremath{\parallel}}^{o}=\ensuremath{-}\ensuremath{\nu}$ and ${\ensuremath{\Phi}}_{\ensuremath{\perp}}^{o}={\ensuremath{\gamma}}_{11}^{o}$. A reanalysis of Bray and Moore's derivation of the (incorrect) relation ${\ensuremath{\Phi}}^{o}={\ensuremath{\gamma}}_{11}^{o}=\ensuremath{\nu}\ensuremath{-}1$ is presented which reveals where their arguments go wrong.

DOI
10.1103/physrevb.27.2937

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The effects of irrelevant surface perturbations on the local critical behavior of (4\ensuremath−\ensuremathϵ4\ensuremath{-}\ensuremath{\epsilon}4\ensuremath−\ensuremathϵ)-dimensional nnn-vector models with a free surface or an internal defect plane are investigated with particular attention paid to the corrections to scaling induced by the surface term 12c\ensuremath∫surface\ensuremathφ2\frac{1}{2}c\ensuremath{\int}{\mathrm{surface}}^{}{\ensuremath{\varphi}}^{2}21​c\ensuremath∫surface\ensuremathφ2 near the ordinary transition. A systematic expansion in c\ensuremath−1{c}^{\ensuremath{-}1}c\ensuremath−1 is developed. In the case of a semi-infinite system, c\ensuremath−1{c}^{\ensuremath{-}1}c\ensuremath−1 couples to the square of the normal derivative of \ensuremathφ\ensuremath{\varphi}\ensuremathφ. The associated crossover exponent is \ensuremathΦo=\ensuremath−\ensuremathν{\ensuremath{\Phi}}^{o}=\ensuremath{-}\ensuremath{\nu}\ensuremathΦo=\ensuremath−\ensuremathν to all orders in \ensuremathϵ\ensuremath{\epsilon}\ensuremathϵ. In the case of an infinite-space model with a defect plane, c\ensuremath−1{c}^{\ensuremath{-}1}c\ensuremath−1 couples to the squares of the normal derivatives on either side of the plane and to the product of the normal derivative on one side with the normal derivative on the other side. The latter operator represents perpendicular interactions across the defect plane, while the other two describe parallel interactions between spins on the same side of the plane. The associated crossover exponents are \ensuremathΦ\ensuremath∥o=\ensuremath−\ensuremathν{\ensuremath{\Phi}}_{\ensuremath{\parallel}}^{o}=\ensuremath{-}\ensuremath{\nu}\ensuremathΦ\ensuremath∥o​=\ensuremath−\ensuremathν and \ensuremathΦ\ensuremath⊥o=\ensuremathγ11o{\ensuremath{\Phi}}_{\ensuremath{\perp}}^{o}={\ensuremath{\gamma}}_{11}^{o}\ensuremathΦ\ensuremath⊥o​=\ensuremathγ11o​. A reanalysis of Bray and Moore's derivation of the (incorrect) relation \ensuremathΦo=\ensuremathγ11o=\ensuremathν\ensuremath−1{\ensuremath{\Phi}}^{o}={\ensuremath{\gamma}}_{11}^{o}=\ensuremath{\nu}\ensuremath{-}1\ensuremathΦo=\ensuremathγ11o​=\ensuremathν\ensuremath−1 is presented which reveals where their arguments go wrong.
The local critical behavior of the ddd-dimensional nnn-vector model near an internal $d\ensuremath{-}1$ dimensional plane of weakened interactions in the limit $n\ensuremath{\rightarrow}\ensuremath{\infty}$ changes qualitatively at d=3d=3d=3. For d>3d>3d>3 the critical exponent ${\ensuremath{\eta}}_{\ensuremath{\parallel}}$, which characterizes the correlation of spins in the defect plane, is universal, i.e., is independent of the strength of the interactions in the defect plane. We argue that ${\ensuremath{\eta}}_{\ensuremath{\parallel}}$ is nonuniversal for d=3d=3d=3 and calculate its dependence on the difference between the defect and bulk couplings to second order in perturbation theory. We show that the excess energy density at a distance zzz from the defect plane decays at the critical point to the bulk value as ${z}^{\ensuremath{-}2}$ for $d\ensuremath{\ge}3$ and faster than ${z}^{\ensuremath{-}2}$ for d<3d<3d<3. Near the free surface of a semi-infinite system one finds a ${z}^{\ensuremath{-}2}$ dependence for d>3d>3d>3 as well as for $d\ensuremath{\ge}3$.
We discuss the universality classes of the local critical behavior of a bulk system near a free surface and near an internal plane of defects. A phase diagram and plausible renormalization-group flow properties for a general model which encompasses both cases are described qualitatively. Several of the crossover exponents are related to bulk critical exponents or semi-infinite surface critical exponents. The picture which is proposed accomodates systems with nonuniversal local critical exponents near a plane of defects, such as the two-dimensional Ising model near a defect line, in a natural way. Necessary conditions for nonuniversal local critical exponents and for logarithmic corrections are derived. The singularities of the energy densities near a free surface and near an internal defect plane on approaching the bulk critical temperature are analyzed.
The critical behavior of a semi-infinite nnn-vector model in $4\ensuremath{-}\ensuremath{\epsilon}$ dimensions near the special transition is studied. The renormalization of the relevant surface operators is discussed and explicitly carried out in two-loop order. It is found that the crossover exponent ${\ensuremath{\varphi}}_{s}$ related to the square of the order parameter in the surface does not satisfy the relation ${\ensuremath{\varphi}}_{s}=1\ensuremath{-}\ensuremath{\nu}$ due to Bray and Moore.
We study the local critical behavior near the free surface of a d-dimensional system with a smooth inhomogeneity induced by a defect of dimension d∗{\mathit{d}}^{\mathrm{*}}d∗\ensuremath{\le}d-1 located on the surface. The couplings deviate from their bulk critical value by \ensuremath{\lambda}${\mathit{r}}_{\mathrm{\ensuremath{\perp}}}^{\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\alpha}}}$ where ${\mathit{r}}_{\mathrm{\ensuremath{\perp}}}$ is the distance to the center of the defect. Using a phenomenological approach, the change in the surface critical exponents is calculated to first order in the perturbation amplitude \ensuremath{\lambda} when the system is marginal, i.e., when the decay exponent of the perturbation \ensuremath{\alpha} is equal to the scaling dimension ${\mathrm{\ensuremath{\Delta}}}_{\mathrm{\ensuremath{\varepsilon}}}^{0}$ of the bulk energy-density operator. Finally, the critical behavior near extended defects in the bulk is compared to the surface case.
The critical behavior of a semi-infinite nnn-vector model with anisotropic ferromagnetic pair interactions on the surface and isotropic interactions everywhere else is studied with the use of renormalization-group methods for dimension $d=4\ensuremath{-}\ensuremath{\epsilon}$. The effects of surface anisotropies are analyzed near the isotropic ordinary transition (where they produce corrections to scaling), near the isotropic special transition (where they are relevant perturbations), and near a new class of "anisotropic special" transitions. The latter occur if the surface exchange constants associated with me{m}_{e}me​ (easy-magnetization) components take a critical value above which me{m}_{e}me​-component surface order is possible while the interaction constants of the remaining ${m}_{h}=n\ensuremath{-}{m}_{e}$ (hard-magnetization) components are weaker. Of particular interest is the anisotropic special transition with an easy axis (me=1{m}_{e}=1me​=1) because it occurs also in three dimensions, in contrast to the isotropic special one. The associated critical, crossover, and correction-to-scaling exponents are given to second order in $\ensuremath{\epsilon}$.
We study the surface critical behavior of semi-infinite systems belonging to the bulk universality class of the Ising model. Special attention is paid to the local behavior of experimentally relevant quantities such as the order parameter and the correlation function in the crossover regimes between different surface universality classes, where the surface field h1 and the temperature enhancement c can induce additional macroscopic length scales. Starting from the field-theoretical φ4 model and employing renormalization-group improved perturbation theory (ϵ-expansion), explicit results for the local behavior of the correlation and structure function (zero-loop) and the order parameter (one-loop) are derived. Supplementing earlier studies that focused on the special transition, we here pay particular attention to the situation where a large c suppresses the tendency to order in the surface (ordinary transition) but a surface field h1 generates a small surface magnetization m1. Our results are in good agreement with recent phenomenological considerations and Monte Carlo studies devoted to similar questions and, combined with the latter, provide a much more detailed understanding of the local properties of systems with weak surface fields.