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Applied Physics Letters

Scattering-based hole burning through volume speckles in a random medium with tunable diffusion constant

Shunsuke Murai, Koji Fujita, Takayuki Hirao, Kazuki Nakanishi, Kazuyuki Hirao, Katsuhisa Tanaka

Published Oct 13, 2008• 5 citations
Publisher

Abstract

A photoreactive random medium with tunable diffusion constant D is fabricated by infiltrating Sm2+-doped macroporous aluminosilicate glass with liquid crystal (LC). Time-resolved transmission experiment reveals that D in the LC-infiltrated sample changes abruptly at around 35°C due to the phase transition of LC between nematic and isotropic. The hole burning effect based on the interference of multiply scattered light is investigated with a particular motivation of controlling hole burning properties externally via temperature. We demonstrate that the holes are separately registered in each LC phase and can be detected selectively depending on the temperature.

DOI
10.1063/1.2955830

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A photoreactive random medium with tunable diffusion constant D is fabricated by infiltrating Sm2+-doped macroporous aluminosilicate glass with liquid crystal (LC). Time-resolved transmission experiment reveals that D in the LC-infiltrated sample changes abruptly at around 35°C due to the phase transition of LC between nematic and isotropic. The hole burning effect based on the interference of multiply scattered light is investigated with a particular motivation of controlling hole burning properties externally via temperature. We demonstrate that the holes are separately registered in each LC phase and can be detected selectively depending on the temperature.
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We analyzed the shape and width of room-temperature persistent holes in photoreactive and multiple-scattering media in frequency and wave-vector domains. The shape and width of holes depend on sample thickness, transport mean free path, geometrical configuration, and absorption lengths. The measurements of the angular dependence of hole burning in a disordered CdS0.85Se0.15{\mathrm{CdS}}_{0.85}{\mathrm{Se}}_{0.15}CdS0.85​Se0.15​- doped glass sample were in quantitative agreement with theory.
We reported the first observation of room-temperature persistent spectral hole burning in Sm2+-doped fluoride glass in the last conference [1]. Room-temperature hole burning had been also observed in Sm2+-doped crystals [2]. We found considerable differences in the hole-burning characteristics between Sm2+-doped glasses and Sm2+-doped crystals: The burning-laser-intensity dependence is approximately linear, and no antihole is observed around the hole burned in Sm2+-doped glasses [3]. More detailed experimental studies are needed to clarify the mechanism of the hole burning in this glass and to explore more efficient hole-burning systems. In this paper, we report several experimental results related to wavelength dependence of the hole burning process.
Persistent spectral hole burning (PSHB) and light-induced absorption spectra with the pump of burning light were measured and studied in the Sm2+-doped xAl2O3⋅(100−x)SiO2 glasses to reveal the electron transfer and the formation of PSHB at room temperature. It was observed that the density of Sm2+ at the burnt sites decreased, while that of Sm3+ increased after the burning. The hole depth increased with the increase of Al2O3 concentration. The formation of PSHB is attributed to a one-step electron transfer by tunneling through the excited state, D05. The traps that capture the electrons produced by the ionization of Sm2+ may be related to the oxygen vacancies. In addition, the thermal activated barrier height between the burnt and unburnt configuration was estimated as ∼1.0 eV by thermal hole filling.
Permanent and transient hole-burning experiments carried out on various types of amorphous systems at temperatures between 0.3 and 20 K are presented. Optical dephasing on organic molecules in glasses and polymers measured on different time scales are discussed in relation to spectral diffusion processes and compared to the literature. The pure dephasing time appears to be proportional to the excited state lifetime of the guest. Organic molecules adsorbed on the surface of porous silica glass show that their homogeneous linewidth is an order of magnitude larger than in polymers and glasses in the bulk, but follows the same temperature dependence. Hole-burning results on bacteriochlorophyll in various disordered hosts are compared to those on a isolated light-harvesting photosynthetic pigment-protein complex (B800–850). From the holewidth in the latter the energy transfer rate between aggregated bacteriochlorophyll pigments is determined and compared to time-resolved spectroscopy results in the literature.