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Physical Review

Ground-State Energy of a Hard-Sphere Gas

Freeman J. Dyson

Published Apr 1, 1957• 149 citations
Publisher

Abstract

Rigorous lower and upper bounds are established for the energy of the ground state of a Bose gas with hard-sphere interaction between particles.Received 17 December 1956DOI:https://doi.org/10.1103/PhysRev.106.20©1957 American Physical Society

DOI
10.1103/physrev.106.20

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Energy of Interacting Fermi Systems

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Rigorous lower and upper bounds are established for the energy of the ground state of a Bose gas with hard-sphere interaction between particles.Received 17 December 1956DOI:https://doi.org/10.1103/PhysRev.106.20©1957 American Physical Society
Abstract We consider a gas of bosons interacting through a hard-sphere potential with radius a\mathfrak {a}a a in the thermodynamic limit. We derive an upper bound for the ground state energy per particle at low density. Our bound captures the leading term 4πρa4\pi \rho \mathfrak {a}4πρa 4 π ρ a and shows that corrections are smaller than Cρa(ρa3)1/2C \rho \mathfrak {a} (\rho {{\mathfrak {a}}}^3)^{1/2}Cρa(ρa3)1/2 C ρ a ( ρ a 3 ) 1 / 2 , for a sufficiently large constant C>0C > 0C>0 C > 0 . In combination with a known lower bound, our result implies that the first sub-leading term to the ground state energy of a dilute gas of hard spheres is, in fact, of the order ρa(ρa3)1/2\rho \mathfrak {a}(\rho {{\mathfrak {a}}}^3)^{1/2}ρa(ρa3)1/2 ρ a ( ρ a 3 ) 1 / 2 , in agreement with the Lee–Huang–Yang prediction.
We consider a gas of bosons interacting through a hard-sphere potential with radius a\frak{a}a in the thermodynamic limit. We derive a simple upper bound for the ground state energy per particle at low density. Our bound captures the leading term 4πρa4πρ\frak{a}4πρa and shows that corrections are smaller than Cρa(ρa3)1/2C ρ\frak{a} (ρ\frak{a}^3)^{1/2}Cρa(ρa3)1/2, for a sufficiently large constant C>0C > 0C>0. In combination with a known lower bound, our result implies that the first sub-leading term to the ground state energy is, in fact, of the order ρa(ρa3)1/2ρ\frak{a} (ρ\frak{a}^3)^{1/2}ρa(ρa3)1/2, in agreement with the Lee-Huang-Yang prediction.
We review some rigorous estimates for the ground state energy of dilute Bose gases. We start with Dyson’s upper bound, which provides the correct leading order asymptotics for hard spheres. Afterward, we discuss a rigorous version of Bogoliubov theory, which recently led to an estimate for the ground state energy in the Gross–Pitaevskii regime, valid up to second order, for particles interacting through integrable potentials. Finally, we explain how these ideas can be combined to establish a new upper bound, valid to second order, for the energy of hard spheres in the Gross–Pitaevskii limit. Here, we only sketch the main ideas; details will appear elsewhere.