The asymptotic and preasymptotic critical behavior in fluids, mixtures, and uniaxial magnets is believed to be described by an effective straight phi(4) scalar field theory with suitable, nonuniversal, coupling constants. The critical parameters as well as the extent of crossovers and corrections to the leading critical behavior in physical systems, crucially depends on the choice of these couplings. Here we propose a new method for deriving the effective scalar field theory appropriate to a microscopic model in this universality class. Use is made of the hierarchical reference theory, which implements the basic ideas of Wilson momentum space renormalization group to microscopic Hamiltonians. The effective low-energy field theory is then analyzed by the minimal subtraction scheme of Schloms and Dohm. We discuss the application of this method to the three-dimensional Ising model and to the liquid-vapor phase transition. We make comparison with high-temperature expansion results and with experimental data for rare gas.
The asymptotic and preasymptotic critical behavior in fluids, mixtures, and uniaxial magnets is believed to be described by an effective straight phi(4) scalar field theory with suitable, nonuniversal, coupling constants. The critical parameters as well as the extent of crossovers and corrections to the leading critical behavior in physical systems, crucially depends on the choice of these couplings. Here we propose a new method for deriving the effective scalar field theory appropriate to a microscopic model in this universality class. Use is made of the hierarchical reference theory, which implements the basic ideas of Wilson momentum space renormalization group to microscopic Hamiltonians. The effective low-energy field theory is then analyzed by the minimal subtraction scheme of Schloms and Dohm. We discuss the application of this method to the three-dimensional Ising model and to the liquid-vapor phase transition. We make comparison with high-temperature expansion results and with experimental data for rare gas.
We study how the formalism of the hierarchical reference theory (HRT) can be extended to inhomogeneous systems. HRT is a liquid-state theory which implements the basic ideas of the Wilson momentum-shell renormalization group (RG) to microscopic Hamiltonians. In the case of homogeneous systems, HRT provides accurate results even in the critical region, where it reproduces scaling and nonclassical critical exponents. We applied the HRT to study wetting critical phenomena in a planar geometry. Our formalism avoids the explicit definition of effective surface Hamiltonians but leads, close to the wetting transition, to the same renormalization group equation already studied by RG techiques. However, HRT also provides information on the nonuniversal quantities because it does not require any preliminary coarse graining procedure. A simple approximation to the infinite HRT set of equations is discussed. The HRT evolution equation for the surface free energy is numerically integrated in a semi-infinite three-dimensional Ising model and the complete wetting phase transition is analyzed. A renormalization of the adsorption critical amplitude and of the wetting parameter is observed. Our results are compared to available Monte Carlo simulations.
We give simple expressions for the mean of the max and min bounds of the critical-to-classical crossover functions, previously calculated [Bagnuls and Bervillier, Phys. Rev. E 65, 066132 (2002)] within the massive renormalization scheme of the Phi(d)4(n) model in three dimensions (d = 3) and scalar order parameter (n = 1) of the Ising-like universality class. The mean functions are determined relying on the properties of the theoretical functions in the two limiting three-dimensional (3D) Ising-like and mean-field-like descriptions close to the Wilson-Fisher fixed point and to the Gaussian fixed point, respectively. Such descriptions correspond to the preasymptotic domains near each fixed point where a Wegner expansion restricted to two terms (leading and first confluent terms) is valid. The Ising-like preasymptotic domain description includes the correlations between parameters due to the error-bar determination of the exponents and amplitude combinations very close to the Wilson-Fisher fixed point. Adding the equivalent description of the mean field preasymptotic domain close to the Gaussian fixed point leads to define each mean crossover function with three calculated parameters. Fixing a unique value of one parameter whatever the selected mean crossover function, we use this parameter as a relative sensor to estimate the dominant nature, either (Ising-like) critical, or (mean-field-like) classical, of the crossover behavior. Finally, we obtain an explicit criterion to measure the extension of the Ising-like preasymptotic domain which can then permit to coherently account for measurements performed in systems where the asymptotical approach to the critical point remains finite, using a well-controlled number of system-dependent parameters (like in the subclass of one-component fluids).
Nonuniversal scale transformations of the physical fields are extended to pure quantum fluids and used to calculate the susceptibility, the specific heat, and the order parameter density along the critical isochore of near its liquid-vapor critical point. Within the so-called preasymptotic domain, where the Wegner expansion restricted to the first term of confluent corrections to scaling is expected to be valid, the results are in agreement with the experimental measurements and recent predictions, either based on the minimal-substraction renormalization and the massive renormalization schemes within phi (4)(d = 3) (n = 1)the model, or based on the crossover parametric equation of state for Ising-like systems.
The phi4 scalar field theory in three dimensions, prototype for the study of phase transitions, is investigated by means of the hierarchical reference theory (HRT) in its smooth cutoff formulation. The critical behavior is described by scaling laws and critical exponents which compare favorably with the known values of the Ising universality class. The inverse susceptibility vanishes identically inside the coexistence curve, providing a first principle implementation of the Maxwell construction, and shows the expected discontinuity across the phase boundary, at variance with the usual sharp cutoff implementation of HRT. The correct description of first and second order phase transitions within a microscopic, nonperturbative approach is thus achieved in the smooth cutoff HRT.
We present a field-theoretical treatment of the critical behavior of a three-dimensional weakly diluted quenched Ising model. To this end we analyze in the replica limit $\stackrel{\ensuremath{\rightarrow}}{n}0$ the five-loop renormalization-group functions of the ${\ensuremath{\varphi}}^{4}$ theory with O(n)-symmetric and cubic interactions [H. Kleinert and V. Schulte-Frohlinde, Phys. Lett. B 342, 284 (1995)]. The minimal subtraction scheme allows one to develop either the $\sqrt{\ensuremath{\varepsilon}}$-expansion series or to proceed within the three-dimensional approach, performing expansions in terms of renormalized couplings. Doing so, we compare both perturbation approaches and discuss their convergence and possible Borel summability. To study the crossover effect we calculate the effective critical exponents. We report resummed numerical values for the effective and asymptotic critical exponents. The results obtained within the three-dimensional approach agree pretty well with recent Monte Carlo simulations. $\sqrt{\ensuremath{\varepsilon}}$ expansion does not allow reliable estimates for d=3.
Abstract In Chapter 14, the singular behavior of ferromagnetic systems with O(N) symmetry and short-range interactions, near a second order phase transition has been determined in the mean-field approximation, which is also a quasi-Gaussian approximation. The mean-field approximation predicts a set of universal properties, properties independent of the detailed structure of the microscopic Hamiltonian, the dimension of space, and, to a large extent, of the symmetry of systems. However, the leading corrections to the mean-field approximation, in dimensions smaller than or equal to four, diverge at the critical temperature, and the universal predictions of the mean-field approximation cannot be correct. Such a problem originates from the non-decoupling of scales and leads to the question of possible universality. In Chapter 9, the question has been answered in four dimensions using renormalization theory, and related renormalization group (RG) equations. Moreover, below four dimensions, in an expansion around the mean-field, the most singular terms near criticality can be also formally recovered from a continuum, low-mass φ4 field theory. More generally, following Wilson, to understand universality beyond the mean-field approximation, it is necessary to build a general renormalization group in the form of flow equations for effective Hamiltonians and to find fixed points of the flow equations. Near four dimensions, the flow equations can be approximated by the renormalization group of quantum field theory (QFT), and the fixed points and critical behaviours derived within the framework of the Wilson-Fisher ϵ expansion.