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Physical Review

Critical Correlations of Certain Lattice Systems with Long-Range Forces

George R. Stell, W. K. Theumann

Published Oct 10, 1969• 18 citations
Publisher

Abstract

We show the way perturbation procedures originated by Brout and Hemmer and further developed by Lebowitz and co-workers can be used to study the critical behavior of lattice systems with a potential $v(\mathrm{r})$ having a weak, long-ranged tail that approaches ${\ensuremath{\gamma}}^{d}\ensuremath{\phi}(\ensuremath{\gamma}\mathrm{r})$ as $\ensuremath{\gamma}$ approaches zero, where $d$ is dimensionality. We consider both the Ising and the spherical models, and note that the results for the latter model are also those that follow from the Ornstein-Zernike assumption that the direct correlation function behaves like $\ensuremath{-}\frac{v(\mathrm{r})}{\mathrm{kT}}$, when $v(\mathrm{r})\ensuremath{\ll}\mathrm{kT}$. We recover by a graph technique the previously known result that in one dimension, quantities of interest such as the inverse correlation length $\ensuremath{\kappa}$ cannot be expanded in $\ensuremath{\gamma}$ at the mean-field critical temperature ${T}_{0}$ and density ${\ensuremath{\rho}}_{0}$ that characterize the critical point in the $\ensuremath{\gamma}\ensuremath{\rightarrow}0$ limit. Instead, at (${T}_{0}, {\ensuremath{\rho}}_{0}$), $\ensuremath{\kappa}\ensuremath{\sim}{\ensuremath{\gamma}}^{\frac{4}{3}}$ as $\ensuremath{\gamma}\ensuremath{\rightarrow}0$. This is true for both the Ising and the spherical models. In the two-dimensional spherical model, we find $\ensuremath{\kappa}$ to vary as ${\ensuremath{\gamma}}^{2}{[\mathrm{ln}(\frac{1}{\ensuremath{\gamma}})]}^{\frac{1}{2}}$ when $\ensuremath{\gamma}\ensuremath{\rightarrow}0$, while in three dimensions $\ensuremath{\kappa}\ensuremath{\sim}{\ensuremath{\gamma}}^{\frac{5}{2}}$. In the Ising case for $d=1$, we characterize topologically the infinite sum of graphs that contribute to the $\ensuremath{\kappa}\ensuremath{\sim}{\ensuremath{\gamma}}^{\frac{4}{3}}$ term in the expansion of the pair correlation function. (In the spherical model, a chain graph gives the entire contribution to the pair correlation function for all $d$). For $d=3$ we do not attempt to deal with the correlation length in the Ising case, but instead consider the shift in the critical temperature as $\ensuremath{\gamma}\ensuremath{\rightarrow}0$. We find that the spherical-model result that gives a shift of order ${\ensuremath{\gamma}}^{3}$ is exact to that order in $\ensuremath{\gamma}$ for the Ising model. We also find that the lowest-order correction to the spherical-model result is of the form ($\mathrm{const}{\ensuremath{\gamma}}^{6}\mathrm{ln}(\mathrm{const}\ensuremath{\gamma})$, in agreement with recent work by Thouless; but in general we expect to find terms of order ${\ensuremath{\gamma}}^{4}$ and ${\ensuremath{\gamma}}^{5}$ from the spherical-model result dominating this correction.

DOI
10.1103/physrev.186.581

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Physical Review•Jun 3, 1966•189 citations
We show the way perturbation procedures originated by Brout and Hemmer and further developed by Lebowitz and co-workers can be used to study the critical behavior of lattice systems with a potential v(r)v(\mathrm{r})v(r) having a weak, long-ranged tail that approaches \ensuremathγd\ensuremathϕ(\ensuremathγr){\ensuremath{\gamma}}^{d}\ensuremath{\phi}(\ensuremath{\gamma}\mathrm{r})\ensuremathγd\ensuremathϕ(\ensuremathγr) as \ensuremathγ\ensuremath{\gamma}\ensuremathγ approaches zero, where ddd is dimensionality. We consider both the Ising and the spherical models, and note that the results for the latter model are also those that follow from the Ornstein-Zernike assumption that the direct correlation function behaves like \ensuremath−v(r)kT\ensuremath{-}\frac{v(\mathrm{r})}{\mathrm{kT}}\ensuremath−kTv(r)​, when v(r)\ensuremath≪kTv(\mathrm{r})\ensuremath{\ll}\mathrm{kT}v(r)\ensuremath≪kT. We recover by a graph technique the previously known result that in one dimension, quantities of interest such as the inverse correlation length \ensuremathκ\ensuremath{\kappa}\ensuremathκ cannot be expanded in \ensuremathγ\ensuremath{\gamma}\ensuremathγ at the mean-field critical temperature T0{T}_{0}T0​ and density \ensuremathρ0{\ensuremath{\rho}}_{0}\ensuremathρ0​ that characterize the critical point in the \ensuremathγ\ensuremath→0\ensuremath{\gamma}\ensuremath{\rightarrow}0\ensuremathγ\ensuremath→0 limit. Instead, at (T0,\ensuremathρ0{T}_{0}, {\ensuremath{\rho}}_{0}T0​,\ensuremathρ0​), \ensuremathκ\ensuremath∼\ensuremathγ43\ensuremath{\kappa}\ensuremath{\sim}{\ensuremath{\gamma}}^{\frac{4}{3}}\ensuremathκ\ensuremath∼\ensuremathγ34​ as \ensuremathγ\ensuremath→0\ensuremath{\gamma}\ensuremath{\rightarrow}0\ensuremathγ\ensuremath→0. This is true for both the Ising and the spherical models. In the two-dimensional spherical model, we find \ensuremathκ\ensuremath{\kappa}\ensuremathκ to vary as \ensuremathγ2[ln(1\ensuremathγ)]12{\ensuremath{\gamma}}^{2}{[\mathrm{ln}(\frac{1}{\ensuremath{\gamma}})]}^{\frac{1}{2}}\ensuremathγ2[ln(\ensuremathγ1​)]21​ when \ensuremathγ\ensuremath→0\ensuremath{\gamma}\ensuremath{\rightarrow}0\ensuremathγ\ensuremath→0, while in three dimensions \ensuremathκ\ensuremath∼\ensuremathγ52\ensuremath{\kappa}\ensuremath{\sim}{\ensuremath{\gamma}}^{\frac{5}{2}}\ensuremathκ\ensuremath∼\ensuremathγ25​. In the Ising case for d=1d=1d=1, we characterize topologically the infinite sum of graphs that contribute to the \ensuremathκ\ensuremath∼\ensuremathγ43\ensuremath{\kappa}\ensuremath{\sim}{\ensuremath{\gamma}}^{\frac{4}{3}}\ensuremathκ\ensuremath∼\ensuremathγ34​ term in the expansion of the pair correlation function. (In the spherical model, a chain graph gives the entire contribution to the pair correlation function for all ddd). For d=3d=3d=3 we do not attempt to deal with the correlation length in the Ising case, but instead consider the shift in the critical temperature as \ensuremathγ\ensuremath→0\ensuremath{\gamma}\ensuremath{\rightarrow}0\ensuremathγ\ensuremath→0. We find that the spherical-model result that gives a shift of order \ensuremathγ3{\ensuremath{\gamma}}^{3}\ensuremathγ3 is exact to that order in \ensuremathγ\ensuremath{\gamma}\ensuremathγ for the Ising model. We also find that the lowest-order correction to the spherical-model result is of the form (const\ensuremathγ6ln(const\ensuremathγ)\mathrm{const}{\ensuremath{\gamma}}^{6}\mathrm{ln}(\mathrm{const}\ensuremath{\gamma})const\ensuremathγ6ln(const\ensuremathγ), in agreement with recent work by Thouless; but in general we expect to find terms of order \ensuremathγ4{\ensuremath{\gamma}}^{4}\ensuremathγ4 and \ensuremathγ5{\ensuremath{\gamma}}^{5}\ensuremathγ5 from the spherical-model result dominating this correction.
Power-series expansions of the spin-pair correlation functions of the square, sc, and bcc Ising lattices have been obtained using the semi-invariant approach for general field HHH and temperature TTT. In three dimensions P\'ade-approximant analyses indicate $2{v}^{\ensuremath{'}}=1.285\ifmmode\pm\else\textpm\fi{}0.020$, in agreement with scaling, but $2{v}^{c}\ensuremath{\simeq}0.835\ifmmode\pm\else\textpm\fi{}0.02$ which is some (1-3)% above the scaling prediction ${v}^{c}=\frac{v}{\ensuremath{\beta}\ensuremath{\delta}}\ensuremath{\simeq}0.823$. However, ratio techniques reveal that this discrepancy can be attributed to significant confluent critical singularities. Cubic and quintic parametric representations of the critical equation of state, and corresponding expressions for the correlation length, ${\ensuremath{\xi}}_{1}(H, T)$, are developed, which are considerable improvements over the linear model. The universality and spherical symmetry of the critical scattering intensity $\stackrel{^}{\ensuremath{\chi}}(\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}, H, T)$ is confirmed to within (1-2)% by estimating suitable invariant combinations of amplitudes. The deviations from Ornstein-Zernike theory for general HHH and TTT are found to be considerably greater than for H=0H=0H=0, T>TcT>{T}_{c}T>Tc​. Complete parametric scaling representations of $\stackrel{^}{\ensuremath{\chi}}(\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}, H, T)$ are developed for three dimensions; corresponding scaling approximants are constructed in two dimensions but only for T=TcT={T}_{c}T=Tc​ and for $T\ensuremath{\gtrless}{T}_{c}$ with H=0H=0H=0.
The Ising-model correlation function $C({R}_{12})=〈{\ensuremath{\mu}}_{1}{\ensuremath{\mu}}_{2}〉$ is studied in terms of a novel NNN-fold integral representation. This formula stems from a procedure proposed by Montroll and Berlin. The integral is estimated by maximizing the integrand, an approximation related to the spherical-model assumptions. The correlation function is not of the Ornstein-Zernike type, just above the critical point, but rather $C(R)\ensuremath{\propto}{R}^{\ensuremath{-}1\ensuremath{-}\ensuremath{\eta}}$ for $R\ensuremath{\ll}\frac{1}{\ensuremath{\kappa}}$, and $C(R)\ensuremath{\propto}{\ensuremath{\kappa}}^{\ensuremath{\eta}}{R}^{\ensuremath{-}1}\mathrm{exp}(\ensuremath{-}\ensuremath{\kappa}R)$ for $R\ensuremath{\gg}\frac{1}{\ensuremath{\kappa}}$. The correlation length $\frac{1}{\ensuremath{\kappa}}$ becomes infinite at the critical point. The calculated value $\ensuremath{\eta}=0.646$ is too large, reflecting the omission of important terms in the evaluation of the integral. The unusual mechanism inducing the nonclassical behavior is carefully examined.
The theory of the correlations and critical scattering of two- and three-dimensional nearest-neighbor Ising models is discussed critically. A distinction is drawn between $\ensuremath{\kappa}(T)$, the true inverse range of exponential decay of the correlations, and ${\ensuremath{\kappa}}_{1}(T)$, the effective range determined from the low-angle scattering intensity. Ten to eleven terms of appropriate high-temperature series exapnsions for $\ensuremath{\kappa}$ and ${\ensuremath{\kappa}}_{1}$ are determined for the square and simple cubic lattices, and shorter series are given for the triangular, fcc, and bcc lattices. For the former lattices, the complete correlation expansions are obtained to the same order. It is shown that $\ensuremath{\kappa}$ and ${\ensuremath{\kappa}}_{1}$ vary as ${(T\ensuremath{-}{T}_{0})}^{\ensuremath{\nu}}$ when $T\ensuremath{\rightarrow}{T}_{c}$, with $\ensuremath{\nu}=1$ for dimensionality d=2d=2d=2, but $\ensuremath{\nu}=0.6430\ifmmode\pm\else\textpm\fi{}0.0025\ensuremath{\simeq}\frac{9}{14}$ for d=3d=3d=3. The asymptotic decay of correlation at T=TcT={T}_{c}T=Tc​ is found to be $\frac{1}{{r}^{d\ensuremath{-}2+\ensuremath{\eta}}}$, where $\ensuremath{\eta}$ is related to the exponent $\ensuremath{\gamma}$ of the divergence of the susceptibility by $(2\ensuremath{-}\ensuremath{\eta})\ensuremath{\nu}=\ensuremath{\gamma}$, Numerical values are $\ensuremath{\eta}=\frac{1}{4}$ for d=2d=2d=2 and $\ensuremath{\eta}=0.056\ifmmode\pm\else\textpm\fi{}0.008\ensuremath{\simeq}\frac{1}{18} \mathrm{for} d=3$. The relative scattering intensity $\stackrel{^}{\ensuremath{\chi}}$ as a function of wave number k is given to high accuracy for all T> TcT>~{T}_{c}T> Tc​ by $\stackrel{^}{\ensuremath{\chi}}(\mathbf{k},T)\ensuremath{\simeq}\left(\frac{a}{{r}_{1}}\right)\frac{^{2\ensuremath{-}\ensuremath{\eta}}[{({\ensuremath{\kappa}}_{1}a)}^{2}+{\ensuremath{\varphi}}^{2}{a}^{2}{K}^{2}(\mathbf{k})]^{\frac{\ensuremath{\eta}}{2}}}{[{({\ensuremath{\kappa}}_{1}a)}^{2}+\ensuremath{\psi}{a}^{2}{K}^{2}(\mathbf{k})]},$ where (i) aaa is the lattice spacing, (ii) ${a}^{2}{K}^{2}=2d[1\ensuremath{-}{q}^{\ensuremath{-}1}\ensuremath{\Sigma}\mathrm{exp}(i\mathbf{k}\ifmmode\cdot\else\textperiodcentered\fi{}\mathbf{r})]\ensuremath{\simeq}{(\mathrm{ka})}^{2}$, the sum being over the qqq nearest-neighbor lattice sites, (iii) r1(T){r}_{1}(T)r1​(T) is a slowly-varying decreasing function near Tc{T}_{c}Tc​, (iv) $\ensuremath{\psi}=1+\frac{1}{2}\ensuremath{\eta}{\ensuremath{\varphi}}^{2}$, and $(\mathrm{v}) \ensuremath{\varphi}(T)$ is slowly varying with a magnitude at Tc{T}_{c}Tc​ of 0.03 for d=2d=2d=2 and of 0.06 to 0.09 for d=3d=3d=3. Explicit formulas are given for ${\ensuremath{\kappa}}_{1}$, r1{r}_{1}r1​, and $\ensuremath{\varphi}$ as functions of TTT. The correlations and the scattering are isotropic near Tc{T}_{c}Tc​. The critical scattering isotherm is curved for low kkk according to ${\stackrel{^}{\ensuremath{\chi}}}^{\ensuremath{-}1}\ensuremath{\sim}{k}^{2\ensuremath{-}\ensuremath{\eta}}$ and it intersects the isotherms for T>TcT>{T}_{c}T>Tc​. Correspondingly, $\stackrel{^}{\ensuremath{\chi}}(\mathbf{k},T)$ exhibits a maximum for fixed k, at a temperature above Tc{T}_{c}Tc​; for d=2d=2d=2 the maxima are very well marked, but for d=3d=3d=3 they are smaller and occur closer to Tc{T}_{c}Tc​. The theory is compared favorably with recent neutron-scattering experiments on pure beta-brass.
A version of the Ising model is developed in which the spin variables can be treated accurately in the continuum approximation. The perturbation series, both above and below the critical temperature Tc{T}_{c}Tc​, is examined, and it is shown that there is a shift of Tc{T}_{c}Tc​ from its mean-field value proportional to ${q}^{\ensuremath{-}2}\mathrm{ln}q$, as well as the well-known shift proportional to ${q}^{\ensuremath{-}1}$; here qqq is the number of mutually interacting particles. It is shown, using renormalization theory, that there is a perturbation series in ${q}^{\ensuremath{-}1}{|T\ensuremath{-}{T}_{c}|}^{\ensuremath{-}\frac{1}{2}}$ for which all terms are finite in the limit $q\ensuremath{\rightarrow}\ensuremath{\infty}$, if the shift of Tc{T}_{c}Tc​ is put in correctly. For the two-dimensional model, the shift is shown to be proportional to ${q}^{\ensuremath{-}1}\mathrm{ln}q$. Conditions are derived for a finite system to display critical behavior characteristic of three, two, one, or zero dimensions. It is shown how similar results can be obtained for a model similar to the Heisenberg model and for the standard Ising and Heisenberg models with interactions extending over many neighbors. A comparison is made between previously calculated numerical results for Tc{T}_{c}Tc​ and the asymptotic forms derived here.
We consider a one-dimensional model with infinite-range interaction, a two-dimensional model, and a three-dimensional model, whose free energies can be expressed in terms of the largest eigenvalue of an integral equation. High- and low-temperature expansions in powers of the reciprocal of the range of the exponential part of the interaction, with the classical Curie-Weiss theory as leading term, are developed and studied in the critical region. We find that to leading order in the critical region the resummed high- and low-temperature expansions are analytic at the classical critical point but are nonanalytic at a displaced critical point. The modified singularities, which are no longer of Curie-Weiss type, give critical exponents which are identical with those obtained by Brout and others, and are almost surely not the true exponents. The technique, however, suggests a possible general method of successive approximation to true critical behavior.
The behavior of the spherical model of a ferromagnet with an interaction energy between the magnetic spins which varies with distance as $\frac{1}{{r}^{d+\ensuremath{\sigma}}}$ (where ddd is the dimensionality of the lattice and $\ensuremath{\sigma}>0$) is analyzed. It is shown that the model exhibits a ferromagnetic transition in one and two dimensions, providing $0<\ensuremath{\sigma}<d$. (The usual spherical model with nearest-neighbor interactions does not have a transition in one and two dimensions.) The critical-point behavior is investigated. It is found that the singularities in the specific heat and susceptibility are dependent on $\ensuremath{\sigma}$ and ddd, but the behavior of the magnetization is independent of $\ensuremath{\sigma}$ and ddd. In three dimensions the susceptibility diverges as ${(T\ensuremath{-}{T}_{c})}^{\ensuremath{-}\ensuremath{\gamma}}$, where $\ensuremath{\gamma}=1$ for $0<\ensuremath{\sigma}<\frac{3}{2}$, $\ensuremath{\gamma}=\frac{\ensuremath{\sigma}}{(3\ensuremath{-}\ensuremath{\sigma})}$ for $\frac{3}{2}<\ensuremath{\sigma}<2$ and $\ensuremath{\gamma}=2$ for $\ensuremath{\sigma}>2$. The asymptotic form of the spin-spin correlation function $\ensuremath{\Gamma}(\mathrm{r})$ is studied in the neighborhood of the critical temperature Tc{T}_{c}Tc​. At T=TcT={T}_{c}T=Tc​, $\ensuremath{\Gamma}(\mathrm{r})$ decays for large rrr as $\frac{1}{{r}^{d\ensuremath{-}\ensuremath{\sigma}}}$. Several two-dimensional models with long-range interactions falling off as 1r2\frac{1}{{r}^{2}}r21​ in certain directions only are also investigated.