Quantum simulation using ultracold fermions in optical lattices provides valuable insights for strongly correlated many-body phenomena in regimes challenging for classical simulations. In this dissertation, we report the design and construction of an apparatus capable of producing quantum degenerate Bose and Fermi gases. The atoms are then loaded into hexagonal optical superlattices created using two commensurate wavelengths. The apparatus lays the foundation for studying interacting fermions in geometrically frustrated lattices.We also report our experimental results on the characterization of the quantum geometry of Bloch band structures. Using rubidium Bose-Einstein condensates in the honeycomb lattice, we were able to measure the quantum distance around band touching points using parallel transport. Additionally, by simulating optical excitations using noninteracting fermions in a periodically modulated lattice, we observe quasimomentum-dependent optical selection rules, which stem from interband quantum geometry of the honeycomb lattice.
Quantum simulation is the study of one quantum mechanical system via analog with another. In this thesis we explore a simple model of interacting bosons on a lattice, known as the Bose-Hubbard model, by experimental investigation of ultracold rubidium atoms in an optical lattice made from laser light. We describe the construction and stabilization of an optical superlattice with threefold symmetry, and its use in studying the Bose-Hubbard model on triangular and trimerized kagome lattices. We study the short range phase coherence of a Mott insulator on the triangular lattice, and develop a scheme to mitigate out-of-equilibrium effects arising from the state preparation. We show the first experimental realization of an optical trimerized kagome lattice for cold atoms, and discuss experiments characterizing this lattice. Finally, we provide evidence for a Mott insulating state with fractional average particle number per site with measurements of the nearest-neighbor phase coherence of strongly interacting atoms in the trimerized kagome lattice.