Degeneracy and Symmetry of the Infinite Potential Well
Yuanbei Sun
This paper solves the wavefunctions and energy level formulas of two types of three-dimensional infinite deep cubic potential wells and three-dimensional infinite deep spher-ical potential wells, and studies their degeneracy to elucidate how symmetry governs energy level degeneracy in quantum systems. For the cubic potential well, the potential energy inside the cube is zero, and outside the cube is infinite. Solving the Schrödinger equation shows that the energy is determined by the total of the squares of three quantum numbers (nx, ny, nz). Degeneracy occurs when different combinations of quantum numbers produce the same sum of squares, which reflects cubic symmetry, i.e., the equivalence of the x, y, and z directions, such that permuted states are physically identical. For the spherical potential well, the poten-tial energy inside the sphere is zero, and outside the sphere is infinite. The wavefunction can be devided into angular and radial parts. The energy depends on the radial quantum number n and the angular momentum quantum number l, and degeneracy arises from the magnetic quantum number m, which ranges from −l to l. Since the potential energy of the spherical potential well is independent of direction, it has spherical symmetry, which leads to degen-eracy of magnitude 2l + 1-fold. To summarize, the degeneracy of the cubic potential well originates from its cubic symmetry, while that of the spherical potential well originates from its spherical symmetry. This highlights the central role of symmetry in quantum energy level degeneracy.
Theoretical and Natural Science•Oct 23, 2025•0 citations