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Cambridge University Press eBooks

Classical mechanics vs. quantum mechanics

Carson L. Tang

Published Jun 23, 2005• 0 citations
Publisher

Abstract

What is quantum mechanics and what does it do ? In very general terms, the basic problem that both classical Newtonian mechanics and quantum mechanics seek to address can be stated very simply: if the state of a dynamic system is known initially and something is done to it, how will the state of the system change with time in response ? In this chapter, we will give a brief overview of, first, how Newtonian mechanics goes about solving the problem for systems in the macroscopic world and, then, how quantum mechanics does it for systems on the atomic and subatomic scale. We will see qualitatively what the differences and similarities of the two schemes are and what the domain of applicability of each is. Brief overview of classical mechanics To answer the question posed above systematically, we must first give a more rigorous formulation of the problem and introduce the special language and terminology (in double quotation marks) that will be used in subsequent discussions. For the macroscopic world, common sense tells us that, to begin with, we should identify the “system” that we are dealing with in terms of a set of “static properties” that do not change with time in the context of the problem. For example, the mass of an object might be a static property. The change in the “state” of the system is characterized by a set of “dynamic variables.

DOI
10.1017/cbo9781139165273.002

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What is quantum mechanics and what does it do ? In very general terms, the basic problem that both classical Newtonian mechanics and quantum mechanics seek to address can be stated very simply: if the state of a dynamic system is known initially and something is done to it, how will the state of the system change with time in response ? In this chapter, we will give a brief overview of, first, how Newtonian mechanics goes about solving the problem for systems in the macroscopic world and, then, how quantum mechanics does it for systems on the atomic and subatomic scale. We will see qualitatively what the differences and similarities of the two schemes are and what the domain of applicability of each is. Brief overview of classical mechanics To answer the question posed above systematically, we must first give a more rigorous formulation of the problem and introduce the special language and terminology (in double quotation marks) that will be used in subsequent discussions. For the macroscopic world, common sense tells us that, to begin with, we should identify the “system” that we are dealing with in terms of a set of “static properties” that do not change with time in the context of the problem. For example, the mass of an object might be a static property. The change in the “state” of the system is characterized by a set of “dynamic variables.
Newtonian mechanics is the foundation of Classical Physics. Newton’s mechanics, Thermodynamics, Wave theory of Optics and Maxwell’s electromagnetic theory belong to regime of Classical Physics and can be used to explain a wide range of phenomena in the Universe at macroscopic scale. These theories fail spectacularly when applied to phenomenain the atomic and nuclear regime, for example, proton-atom scattering or the flow of electrons in a semiconductor. Quantum mechanics is the most successful scientific theory that has ever been created and it has completely changed our view of the world. The failure of Classical Physics was highlighted by black body radiation and photoelectric effect. Max Planck and Albert Einstein provided explanations of both phenomena based on quantum hypothesis and are thus considered founders of Quantum Physics. The origin of quantum mechanics goes back to the mid-1920s.It was formulated first as matrix mechanics by Werner Heisenberg, Max Born and Pascual Jordan; then as wave mechanics by Louis de Broglie and Erwin Schrödinger; and later on asquantum statistics of subatomic particles by Fermi-Dirac and Bose-Einstein. Combining relativistic mechanics with quantum mechanics, Dirac formulated his relativistic quantum mechanics during 1930s. Uncertainty Principle is thecornerstone of Quantum Physics. The role of randomness in microscopic physical processes shatters the myth that the universe is deterministic. Quantum world is unpredictable in the classical sense and demolishes the idea of an objective universe. The Copenhagen interpretation remains the quantum mechanical formalism that is currently most widely accepted amongst physicists.Quantum theories support cosmic spirit pervading the cosmos and inter – relationship of individuals in the world society. Quantum philosophy is holistic and is going to revolutionize our world-view.
In the first two chapters we have examined the basic principles – superposition (p. 18), complementarity (p. 19), quantization (p. 44), statistical algorithm (p. 57), and correspondence (p. 72) (see also Subsec. 2.3.4) – and the basic entities, observables and states, of quantum mechanics, as well as the main differences with respect to classical mechanics. While what we have discussed so far is rather a static picture of observables and states, in this chapter we shall deal with quantum dynamics, i.e. with the time evolution of quantum-mechanical systems. Historically, after Bohr had provided a quantized description of the atom (see Subsec. 1.5.4), Einstein showed the quantized nature of photons (see Subsec. 1.2.1), and de Broglie hypothized the wave-like nature of matter (see Subsec. 1.5.5), the first building block of quantum mechanics was provided by the commutation relations, proposed by Heisenberg in 1925, whose consequence is represented by the uncertainty relation (see Subsec. 2.2.7 and Sec. 2.3). This was the subject of the previous chapters. The dynamical part of the theory was proposed by Schrödinger in 1926, and is known as the Schrödinger equation. It is also known as wave mechanics (see Subsec. 1.5.7). In this chapter we shall show that Heisenberg's and Schrödinger's formulations are only two different aspects of the same theory. We shall also come back to this point in Sec. 8.1.1. Here, first we shall derive the fundamental equation which rules quantum dynamics (Sec. 3.1), and, in Sec. 3.2, we shall summarize the main properties of the Schrödinger equation.
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.
More them any other topic in the foundations of physics, the problem of the arrow (or arrows!) of time seems to be characterized by a unique ‘slipperiness’: it is not only difficult to find answers to the questions once posed, but difficult to find meaningful questions to ask in the first place. Perhaps this is because an asymmetry with respect to the sense of time is built into us at an even deeper level than other ‘synthetic a priori’ conceptions about the world such as the continued existence of unknown objects. However that may be, in this situation, rather than trying to pose general questions which may turn out in the end to be ill-defined, there may be something to be said for trying to formulate much less speculative, indeed perhaps in retrospect trivial questions to which at least we have a hope of finding a definite answer. This is what I shall do in this essay: to be specific, I shall ask whether a test which is currently being designed concerning the validity of a certain ‘common-sense’ view of the macroscopic world (‘macrorealism’) would be affected if we were to relax our common-sense assumptions about the direction of causality in time. Let me start with a very brief review of established ideas concerning the formal (a)symmetry of the quantum theory with respect to the direction of time. The classic works on this subject are the paper of Aharonov et al. (‘ABL’) and the book by Belinfante. In these discussions the notion of ‘measurement’ is taken as primitive and undefined.
Quantum mechanics (or simply quantum physics) is the branch of physics that applies to particles and systems of particles, such as atoms and molecules. In that realm the laws of classical mechanics and classical electromagnetism break down, and only quantum mechanics provides the concepts and computational methods that explain observed phenomena. Quantum mechanics uses specially developed tools, such as wave functions, that contain all of the relevant information about particles and systems. is approach is needed to understand the true nature of electromagnetic radiation and how that radiation interacts with matter. e mathematics used in quantum mechanics is highly specialized and often complex. In this chapter we’ll address some of the key questions that require quantum mechanics without presenting the full mathematical formalism. e important questions we’ll address all deal with observable physical phenomena. We’ll discuss how quantum mechanics is used to answer these questions but will omit the advanced mathematical details.