This dissertation describes my detailed investigation of decoherence and defects in two Al/AlOx/Al Cooper-pair box (CPB) charge qubits. Both devices were coupled to thin-film lumped-element superconducting aluminum LC resonators at a temperature of 25 mK. Device 1 was previously found to have an exceptionally long energy relaxation time of T1=205 μs and a strong correlation between the lifetime T1 and the decoupling from the microwave drive line dVg,rms/dΩR,0. I determined the dephasing properties of this CPB though a series of experiments. I measured Ramsey fringes, extracted dephasing times Tφ in the range200-500 ns, and determined a corresponding bound of Sq(f=1 Hz)≤(3×10-3)2 e2/Hz on the amplitude of the 1/f charge noise affecting the qubit. I then carried out a spin echo experiment and found echo decay times Techo in the 2.4-3.3 μs range, implying a high frequency 1/f charge noise cutoff of ωc/2π≈0.2 MHz. I followed this up by fabricating and characterizing a nearly identical Device 2. This CPB had a reasonably long relaxation time T1≈4-30 μs and again the lifetime T1 and decoupling dVg,rms/dΩR,0 were correlated. Although the lifetime of Device 2 was shorter than that of Device 1, the results suggest that the exceptional relaxation time was somewhat reproducible and that this approach may lead to further improvements in qubit coherence. During my initial characterization of Device 2, I discovered that it displayed an anomalously twinned transition spectrum. I studied this feature in detail in parallel with my decoherence experiments. I found that above the resonator resonance at ω/2π=5.472 GHz the system spectrum was twinned but below it was quadrupled. This behavior was consistent with a pair of two-level systems (TLS) coupled non-resonantly to the CPB via both charge and critical current. I developed a model that matched this scenario and successfully fit the predicted spectrum to my data. Both the coherent non-resonant interaction and joint charge and critical current CPB-TLS coupling are novel observations. From the fits I extracted microscopic parameters of the fluctuators including the well asymmetry, tunneling rate, and a minimum hopping distance of 0.2-0.45 Å. I also found a large fractional change of the Josephson energy ΔEJ,k/EJ≈30-40%, consistent with a non-uniform tunnel barrier containing a few dominant conduction channels and a defect that modulates one of them.
This dissertation describes my detailed investigation of decoherence and defects in two Al/AlOx/Al Cooper-pair box (CPB) charge qubits. Both devices were coupled to thin-film lumped-element superconducting aluminum LC resonators at a temperature of 25 mK. Device 1 was previously found to have an exceptionally long energy relaxation time of T1=205 μs and a strong correlation between the lifetime T1 and the decoupling from the microwave drive line dVg,rms/dΩR,0. I determined the dephasing properties of this CPB though a series of experiments. I measured Ramsey fringes, extracted dephasing times Tφ in the range200-500 ns, and determined a corresponding bound of Sq(f=1 Hz)≤(3×10-3)2 e2/Hz on the amplitude of the 1/f charge noise affecting the qubit. I then carried out a spin echo experiment and found echo decay times Techo in the 2.4-3.3 μs range, implying a high frequency 1/f charge noise cutoff of ωc/2π≈0.2 MHz. I followed this up by fabricating and characterizing a nearly identical Device 2. This CPB had a reasonably long relaxation time T1≈4-30 μs and again the lifetime T1 and decoupling dVg,rms/dΩR,0 were correlated. Although the lifetime of Device 2 was shorter than that of Device 1, the results suggest that the exceptional relaxation time was somewhat reproducible and that this approach may lead to further improvements in qubit coherence. During my initial characterization of Device 2, I discovered that it displayed an anomalously twinned transition spectrum. I studied this feature in detail in parallel with my decoherence experiments. I found that above the resonator resonance at ω/2π=5.472 GHz the system spectrum was twinned but below it was quadrupled. This behavior was consistent with a pair of two-level systems (TLS) coupled non-resonantly to the CPB via both charge and critical current. I developed a model that matched this scenario and successfully fit the predicted spectrum to my data. Both the coherent non-resonant interaction and joint charge and critical current CPB-TLS coupling are novel observations. From the fits I extracted microscopic parameters of the fluctuators including the well asymmetry, tunneling rate, and a minimum hopping distance of 0.2-0.45 Å. I also found a large fractional change of the Josephson energy ΔEJ,k/EJ≈30-40%, consistent with a non-uniform tunnel barrier containing a few dominant conduction channels and a defect that modulates one of them.
We have investigated the decoherence of quantum states in two Al/AlOx/Al Cooper-pair boxes coupled to lumped element superconducting inductor-capacitor resonators. At 25 mK, the first qubit had an energy relaxation time T1 that varied from 30 μs to 200 μs between 4 and 8 GHz and displayed an inverse correlation between T1 and the coupling to the microwave drive line. The Ramsey fringe decay times T2* were in the [200–500] ns range while the spin echo envelope decay times Techo varied from 2.4–3.3 μs, consistent with 1/f charge noise with a high frequency cutoff of 0.2 MHz. A second Cooper-pair box qubit with similar parameters showed T1=4−30 μs between 4 and 7.3 GHz, and that the T1 and the coupling were again inversely correlated. Although the lifetime of the second device was shorter than that of the first device, the dependence on coupling in both devices suggests that further reduction in coupling should lead to improved qubit performance.
The quantum states of an Al/AlOx/Al Cooper pair box (CPB) qubit were measured at temperatures below 100 mK. Detailed spectroscopic measurements of the excited state of the CPB were made along with detailed measurements of the lifetime T1 of the first excited state. The CPB states were probed using radio-frequency (rf) techniques to read out using either an rf - single-electron transistor (rf-SET) or a low-loss superconducting resonator. Using an rf-SET, I measured the excited state spectrum of a CPB from 15 to 50 GHz. In this spectrum, a few anomalous avoided level crossings (ALC) were observed. These ALCs exhibited a strong gate voltage dependence and Josephson energy (Ej) dependence, consistent with a charge fluctuator coupled to the CPB island. A model Hamiltonian was used to fit the measured spectrum. Fitting parameters such as the charging energy Ec/h = 12.1 GHz and the Josephson energy Ej/h tuned between 2 GHz and 21 GHz for the CPB, and the well asymmetry, tunneling amplitude, and the minimum hopping distance for each fluctuator were extracted. The tunneling rates ranged from less than 3.5 to 13 GHz, i.e. values between 5 % and 150 % of the well asymmetry, and the dipole moments yield a minimum hopping distance of 0.3 to 0.8 Angstroms. I also made detailed measurements of the lifetime of the first excited state away from the CPB charge degeneracy point and found that the lifetime varied from less than 50 ns up to a few us as the Josephson energy Ej decreased, consistent with a charge noise (Sq~10-11 e2/Hz around 37 GHz to Sq~10-12 e2/Hz around 27 GHz) coupled to the qubit. I also found that at frequencies where an ALC was observed in the spectrum, a decrease in T1 occurred, suggesting that the discrete charge defects are a significant source of dissipation in the CPB. I also designed and fabricated a quasi-lumped element thin-film superconducting Al microwave resonator on sapphire to be used for a dispersive read-out of the CPB. The resonator consists of a meandering inductor and an interdigitated capacitor coupled to a transmission line. At T = 30 mK and on resonance at 5.578 GHz, the transmission through the transmission line decreased by 15 dB and the loaded quality factor was 60,000. I measured the temperature dependence of the resonator frequency and loss at temperatures as high as 500 mK and found reasonable agreement with the Mattis-Bardeen theory. Finally, I coupled a quasi-lumped element microwave resonator (f0~5.443 GHz), made of superconducting Al on sapphire, to an Al/AlOx/Al CPB qubit. Most of my measurements were made in the dispersive regime where Ej-hf0 is much larger than the coupling strength. In this case, the qubit causes a small state-dependent frequency shift in the resonator's resonant frequency. By sending down a second microwave tone (the pump), I was able to excite the CPB qubit. In zero magnetic field with the CPB far detuned from the resonator, I measured a 50 kHz decrease in f0 with the qubit in the ground state and biased near the degeneracy point of the CPB. The charging energy and Josephson energy of the CPB were determined from spectroscopy taken by saturating the CPB with a second microwave tone and measuring the transmission through the resonator. The first device had Ec/h = 12.5 GHz and maximum Ej/h = 9 GHz. The second device had Ec/h = 6.24 GHz and Ej/h tuned between 4 GHz and 8 GHz. By changing the external magnetic field, I could decrease the effective Ej of the CPB. From modeling, I extracted coupling strengths g/2&pi = 11 MHz and 5 MHz for the first and second device, respectively. Finally I did single and two-tone spectroscopy, and measured the relaxation and Rabi oscillations of the CPB. From the first device, I was able to obtain relaxation times T1 of 10.3 us at Ej/h = 7 GHz on the CPB degeneracy point and spectroscopic coherence times T2 *~ 100 ns. From the second device, I found relaxation times T1 of 200 us at Ej/h = 4 GHz to 4.5 GHz decreasing down to 4 us around 8 GHz. There was also a depression in T1 around the resonant frequency of the resonator. The Rabi decay times were found to be up to T'~ 330 ns.
I report an investigation into using an rf Single Electron Transistor (rf-SET) to implement single shot readout of the quantum state of a Cooper pair box. I fabricated Al/AlOx/Al SETs and Cooper pair boxes using e-beam lithography and double-angle evaporation. The devices had typical charging energies of about 1 K and were measured at 30 mK in a dilution refrigerator. I built rf-SETs with an LC resonant circuit integrated on the chip and operating frequencies of 650 MHz and 1.5 GHz. The rf-SETs had a typical bandwidth of 30 MHz and the best achieved charge sensitivity was 8X10-6 erms/(Hz)1/2 at 1.5 GHz. The rf-SETs were used to measure the Coulomb staircase on the Cooper pair box. Measurements of the staircase show features due to quasiparticle poisoning that are dependent on temperature and SET bias. The data was compared to a theory I developed to extend existing theories of quasiparticle poisoning. My model is based on the calculation of tunneling rates to explain observations of parity effects in the Cooper pair box over a wide temperature range. Quantum state control of the Cooper pair box was demonstrated by using fast voltage pulses applied to the gate. Temporal oscillations of charge states and spectroscopy measurements reveal a dephasing time T2=200 ps at 30 mK, for a drive frequency of 30 GHz. The energy relaxation time T1=140 ns was determined from time domain measurements of the decay of the Cooper pair box charge. The fidelity of single shot measurements and the feasibility of this quantum readout scheme based on the results are discussed.
In this thesis the single Cooper pair box (SCB) is investigated with a radio frequency single electron transistor (RF-SET). The RF-SET is used as an electrometer to detect the charge of the SCB. The SCB can be regarded as a quantum two-level system and could therefore be a possible qubit. Both the SCB and the RF-SET have been fabricated with e-beam lithography followed by two-angle shadow evaporation of aluminium. The system has been measured in a dilution refrigerator at temperatures of ~30 mK. A charge sensitivity of 2.3 μe/square root of Hz was measured for an optimized RF-SET with a bandwidth of 7 MHz, operated in the superconducting state. In a phase sensitive measurement of the RF-SET reflected signal, the gate dependence of the quantum capacitance, due to avoided level crossing, was detected in a superconducting SET. Coulomb staircases for the SCB were obtained by changing the charge of the SCB by ramping a gate voltage and continuously measuring the charge with the RF-SET. To prevent quasiparticle poisoning of the SCB island, we have used a method of graded gaps. Here we exploit the greater reduction of the superconducting gap for the connecting leads with an external magnetic field applied, resulting in a higher gap for the island. This creates an effective barrier against quasiparticle tunnelling. The charging energy and the Josephson coupling energy of the SCB were measured with microwave spectroscopy. The SCBs were fabricated in a SQUID geometry, which made it possible to tune the Josephson coupling energy of the box. This tuning was verified through microwave spectroscopy. The effect of tuning could also be seen in the pure 2e Coulomb staircase, as a predicted smearing of the staircase, which was in excellent agreement with the independent spectroscopy data. Coherent quantum oscillation of the SCB charge state was measured by applying nonadiabatic DC-pulses to the SCB gate. The measured amplitude of the charge oscillations was higher than 70%. The deviation from 100% can be explained by the initial charge state purity and the finite rise time of the pulses. The longest decoherence time of the charge oscillations was T2 = 9 ns at the charge degeneracy point. It was found to be limited by relaxation. Away from the degeneracy point the decoherence time was limited by pure dephasing, due to low frequency charge fluctuators.
This thesis presents measurements of quantum coherence in a single Cooper pair box, where quantum oscillations of charge between a reservoir and a small superconducting island have been observed. The single Cooper pair box (SCB) consists of a small metallic island which is connected to a reservoir via a tunnel junction. In the superconducting state, Cooper pairs are free to tunnel to and from the island, whose potential can be controlled by a gate voltage. A graded gap method was used to prevent quasiparticles from tunneling onto the island. For this purpose, a magnetic field suppressed the superconducting gap in the SCB leads more than in the island. This created an additional energy barrier for quasiparticles to tunnel to the island, making the gate voltage modulation periodic in Cooper pair charge. For a limited range of gate voltage, the SCB was found to behave as a model two-level quantum mechanical system. A non-adiabatic change in the induced island charge was used to bring two charge states into resonance. The resulting time evolution showed clear charge oscillations between the ground and excited state, with a frequency given by the energy level separation divided by Planck's constant. These oscillations had a longest coherence time of T2=9 ns at a point where the pure charge states are degenerate. The coherence time at this point was found to be limited by the relaxation rate, ?1. Away from this point, the coherence time was limited by the dephasing rate, ??. Away from the charge degeneracy, the dependence of T2 on gate charge suggested that low frequency fluctuators were the main source of dephasing. The charge of the Cooper pair box was measured by coupling the SCB capacitively to a radio frequency single electron transistor (RF-SET). The RF-SET was used as an electrometer by measuring the amount of reflection from a resonant microwave circuit in which a single electron transistor (SET) was embedded. A best charge sensitivity of 2.3·10-6 e/sqrt(Hz) and a 7 MHz bandwidth was reached in an improved setup. Another part of this thesis concerns an investigation of electrical filters for use in single electronics experiments. The characteristics of seven different types of cryogenic filters were evaluated.
This dissertation examines the design, fabrication, and characterization of a superconducting lumped-element tunable LC resonator that is used to vary the coupling between two superconducting qubits. Some level of qubit-qubit coupling is needed to perform gating operations. However, with fixed coupling, single qubit operations become considerably more difficult due to dispersive shifts in their energy levels transitions that depend on the state of the other qubit. Ideally, one wants a system in which the qubit-qubit coupling can be turned off to allow for single qubit operations, and then turned back on to allow for multi-qubit gate operations. I present results on a device that has two fixed-frequency transmon qubits capacitively coupled to a tunable thin-film LC resonator. The resonator can be tuned in situ over a range of 4.14 GHz to 4.94 GHz by applying an external magnetic flux to two single-Josephson junction loops, which are incorporated into the resonator’s inductance. The qubits have 0-to-1 transition frequencies of 5.10 GHz and 4.74 GHz. To isolate the system and provide a means for reading out the state of the qubit readout, the device was mounted in a 3D Al microwave cavity with a TE101 mode resonance frequency of about 6.1 GHz. The flux-dependent transition frequencies of the system were measured and fit to results from a coupled Hamiltonian model. With the LC resonator tuned to its minimum resonance frequency, I observed a qubit-qubit dispersive shift of 2χ_qq≈ 0.1 MHz, which was less than the linewidth of the qubit transitions. This dispersive shift was sufficiently small to consider the coupling “off”, allowing single qubit operations. The qubit-qubit dispersive shift varied with the applied flux up to a maximum dispersive shift of 2χ_qq≈ 6 MHz. As a proof-of-principle, I present preliminary results on performing a CNOT gate operation on the qubits when the coupling was “on” with 2χ_qq≈ 4 MHz. This dissertation also includes observations of the temperature dependence of the relaxation time T1 of three Al/AlOx/Al transmons. We found that, in some cases, T1 increased by almost a factor of two as the temperature increased from 30 mK to 100 mK. We found that this anomalous behavior was consistent with loss due to non-equilibrium quasiparticles in a transmon where one electrode in the tunnel junction had a smaller volume and slightly smaller superconducting energy gap than the other electrode. At sufficiently low temperatures, non-equilibrium quasiparticles accumulate in the electrode with a smaller gap, leading to an increased density of quasiparticles at the junction and a corresponding decrease in the relaxation time. I present a model of this effect, use the model to extract the density of non-equilibrium quasiparticles in the device, and find the values of the two superconducting energy gaps.