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Electronic structure and pairing of strongly correlated fermions: Fermi liquid versus spin liquid

Krzysztof Byczuk, Jan Karbowski, Józef Spałek, W. Wójcik

Published Apr 1, 1994• 0 citations
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Abstract

We summarize recent theoretical results of our group concerning the electronic states of the strongly correlated fermions at nonzero temperature. The state of almost localized fermions is discussed within a mean-field approach for auxiliary bosons, both in the narrow-band (Section 2) and in the hybridized band (Section 3) cases. This state represents a metallic state of correlated fermion systems (such as V{sub 2}O{sub 3}) below the Mott-Hubbard localization threshold. The Fermi liquid state does not describe properly the properties of narrow band electrons in the large Hubbard -- U limit beyond the localization threshold. Therefore, in Section 4 and 5 we introduce a phenomenological concept of statistical spin liquid which describes principal features of a crossover from a high-temperature superconductor to the Mott insulator for a two-dimensional system. It also reproduces the main features of the phase diagram for La{sub 2-x}Sr{sub x}CuO{sub 4} system, which is modelled by a planar structure.

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arXiv:0707.0142•Jul 2, 2007•2 citations
We summarize recent theoretical results of our group concerning the electronic states of the strongly correlated fermions at nonzero temperature. The state of almost localized fermions is discussed within a mean-field approach for auxiliary bosons, both in the narrow-band (Section 2) and in the hybridized band (Section 3) cases. This state represents a metallic state of correlated fermion systems (such as V{sub 2}O{sub 3}) below the Mott-Hubbard localization threshold. The Fermi liquid state does not describe properly the properties of narrow band electrons in the large Hubbard -- U limit beyond the localization threshold. Therefore, in Section 4 and 5 we introduce a phenomenological concept of statistical spin liquid which describes principal features of a crossover from a high-temperature superconductor to the Mott insulator for a two-dimensional system. It also reproduces the main features of the phase diagram for La{sub 2-x}Sr{sub x}CuO{sub 4} system, which is modelled by a planar structure.
We propose a novel statistical-mechanical approach to a system of strongly correlated electrons in a partially filled narrow band which reproduces rigorously the situation in the atomic limit. In this approach the doubly occupied configurations are excluded both in the real and in the reciprocal spaces. Employing this principle we calculate the thermodynamic properties of those electrons. The metallic state, corresponding to a partially-filled-band case, exhibits a Fermi-liquid--type behavior at low temperatures and transforms into a spin liquid at high temperatures. This feature of our results is reminiscent of the behavior in both magnetic metals and heavy-fermion systems. Additionally, the approach reproduces correctly the statistical properties of the system of localized moments in the limit of the half-filled band, corresponding to the Mott insulating phase. These results are not obtained if one starts from the Fermi-Dirac distribution for the quasiparticles. The last assertion is reinforced by an explicit derivation of a statistical distribution function for correlated electrons which reduces to the Fermi-Dirac distribution in the limit of weak interactions, as well as to the distribution for the spin liquid derived earlier in the limit of strong correlation between the particles.
The metallic phase of strongly correlated electrons is discussed within a novel statistical approach that correctly reproduces the principal features of the Mott insulating state when localization is reached at half-filled band (n=1). The entropy in the normal phase decomposes into a spinless-fermion part representing holes, and a part describing localized moments. The explicit form of the gap ${\ensuremath{\Delta}}_{\mathrm{k}}$ is derived; this solution is shown to disappear when n=1. Most of the results cannot be obtained by using the Fermi-Dirac distribution for single-particle states.
I summarize recent work on non-Fermi liquids within a certain generalized Anderson impurity model as well as in the large-dimensionality (D) limit of the two-band extended Hubbard model. The competition between local charge and spin fluctuations leads either to a Fermi liquid with renormalized quasiparticle excitations, or to non-Fermi liquids with spin - charge separation. These results provide new insights into the phenomenological similarities and differences between different correlated metals. While presenting these results, I outline a general strategy of local approach to non-Fermi liquids in correlated electron systems.
We study superfluidity in strongly correlated systems by focusing three features as follows. First, interplay between superfluidity and other order parameters near quantum critical points is studied. The onset positions of the order parameters with or without superconductivity determines how they interact with each other. For the spin density wave (SDW) transition, we find that the quantum critical point shifts by order |∆|, where ∆ is pairing amplitude, so that the region of SDW order is smaller in the superconductor than in the metal. This shift is larger than the |∆|2 shift predicted by theories of competing orders which ignore Fermi surface effects. Second, we study a doped antiferromagnetic Mott insulator motivated by copper based high temperature superconductors. Based on spin and charge fractionalization, the algebraic charge liquid phase whose bosonic spinons have energy gap but fermionic holons form Fermi surfaces and its superconductivity are studied. We show fluctuations of local SDW order orientation lead to d-wave superconductivity, and its quantum critical pairing mechanisms are investigated. Also, a theory of bound states between spinons and holons is studied. We show that the fractionalization induces a doubling electron-like quasiparticles, which naturally induces the fractionalized Fermi liquid. The bound state theory describes exotic properties of the underdoped Cuprates such as “nodal-antinodal dichotomy” at a mean field level description. At last, we study superfluidity of fermions in optical lattices near the Feshbach resonance. Due to divergence of scattering length at the resonance, universality is observed and characteristics of superfluidity has been studied. We extend such universal properties by considering superfluid-insulator transition with an even integer number of fermions per unit cell. The resulting insulator interpolates between a band insulator of fermions and a Mott insulator of fermion pairs.
We use the concept of generalized (almost localized) Fermi Liquid composed of nonstandard quasiparticles with spin-dependence effective masses and the effective field induced by electron correlations.This Fermi liquid is obtained within the so-called statistically-consistent Gutzwiller approximation (SGA) proposed recently [cf.J. Je ¸drak et al., arXiv: 1008.0021] and describes electronic states of the correlated quantum liquid.Particular emphasis is put on real space pairing driven by the electronic correlations, the Fulde-Ferrell state of the heavy-fermion liquid, and the d-wave superconducting state of high temperature cuprate superconductors in the overdoped limit.The appropriate phase diagrams are discussed showing in particular the limits of stability of the Bardeen-Cooper-Schrieffer (BCS) type of state.
The Hubbard model in the strong-coupling regime is mainly studied by Kondo-lattice theory or 1/d expansion theory, with d the spatial dimensionality. In two dimensions and higher, the ground state within the Hilbert subspace with no order parameter is a normal Fermi liquid except for n=1 and U/W=+infinity, with n the electron density per unit cell, U the on-site repulsion, and W the bandwidth; the cooperation between the Kondo effect, which favors a local singlet on each unit cell, and a resonating-valence-bond effect, which favors a local singlet on each pair of nearest-neighbor unit cells, stabilizes the Fermi liquid, whose ground state is a singlet as a whole, in the strong-coupling regime. In the whole Hilbert space with no restriction, the normal Fermi liquid is unstable at least against a magnetic or superconducting state. This analysis confirms an early Fermi-liquid theory of high-temperature superconductivity, F. J. Ohkawa, Jpn. J. Appl. Phys. 26, L652 (1987). The ground state for n=1 and U/W=+infinity is a Mott insulator. Actual metal-insulator transitions cannot be explained within the Hubbard model. In order to explain them, the electron-phonon interaction, multi-band or multi-orbital effects, and effects of disorder should be considered beyond the Hubbard model. The crossover between local-moment magnetism and itinerant-electron magnetism corresponds to that between a localized spin and a normal Fermi liquid in the Kondo effect and it is simply a Mott metal-insulator crossover.