Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

NASA STI/Recon Technical Report N

Physics Utilizing Spin-Polarized Gases

W. Happer

Published Aug 8, 2002• 0 citations
OpenAlex

Abstract

We have completed a thorough study of masing action of hyperpolarized He-3 gas in inhomogeneous magnetic fields. The self interaction of the He-3 magnetization has a large effect on the maser gain. We have developed a simple new magnetic resonance method for investigating the interactions of Xe-129 spins with protons in polymers. We have shown that there are novel magnetic resonance transitions in alkali-metal vapors that have vanishing spin-exchange broadening in the limit of high spin polarization. Such transitions could be useful for miniaturized atomic clocks. We have shown that spin-axis interactions in triplet molecules are responsible for much of the spin destruction rate dense alkali-metal vapors.

Related papers

The Physics of Spin Polarized Gases.

G. D. Cates

Over the four year period covered by this grant, we have carried out extensive research involving polarized atoms and nuclei. Using laser optical pumping, high polarizations can be produced in alkali-metal vapors. From this starting point, angular momentum can be transferred to other atoms and nuclei through several different types of spin-exchange collisions. This powerful technique enables us to study a wide variety of spin interactions and spin related phenomena. Among the systems we work with are polarized nobel gases, which display extremely long spin-relaxation times that vary from several minutes to many weeks. The use of optical pumping and spin exchange has grown enormously over the past four years.

•Jan 2, 1993•0 citations

Theory of spin-exchange optical pumping of 3 He and 129 Xe

Stephan Appelt, Andrei Ben-Amar Baranga, Christopher Erickson +3 more

We present a comprehensive theory of nuclear spin polarization of ${}^{3}\mathrm{He}$ and ${}^{129}\mathrm{Xe}$ gases by spin-exchange collisions with optically pumped alkali-metal vapors. The most important physical processes considered are (1) spin-conserving spin-exchange collisions between like or unlike alkali-metal atoms; (2) spin-destroying collisions of the alkali-metal atoms with each other and with buffer-gas atoms; (3) electron-nuclear spin-exchange collisions between alkali-metal atoms and ${}^{3}\mathrm{He}$ or ${}^{129}\mathrm{Xe}$ atoms; (4) spin interactions in van der Waals molecules consisting of a Xe atom bound to an alkali-metal atom; (5) optical pumping by laser photons; (6) spatial diffusion. The static magnetic field is assumed to be small enough that the nuclear spin of the alkali-metal atom is well coupled to the electron spin and the total spin is very nearly a good quantum number. Conditions appropriate for the production of large quantities of spin-polarized ${}^{3}\mathrm{He}$ or ${}^{129}\mathrm{Xe}$ gas are assumed, namely, atmospheres of gas pressure and nearly complete quenching of the optically excited alkali-metal atoms by collisions with ${\mathrm{N}}_{2}$ or ${\mathrm{H}}_{2}$ gas. Some of the more important results of this work are as follows: (1) Most of the pumping and relaxation processes are sudden with respect to the nuclear polarization. Consequently, the steady-state population distribution of alkali-metal atoms is well described by a spin temperature, whether the rate of spin-exchange collisions between alkali-metal atoms is large or small compared to the optical pumping rate or the collisional spin-relaxation rates. (2) The population distributions that characterize the response to sudden changes in the intensity of the pumping light are not described by a spin temperature, except in the limit of very rapid spin exchange. (3) Expressions given for the radio-frequency (rf) resonance linewidths and areas can be used to make reliable estimates of the local spin polarization of the alkali-metal atoms. (4) Diffusion effects for these high-pressure conditions are mainly limited to thin layers at the cell surface and at internal resonant surfaces generated by radio-frequency magnetic fields when the static magnetic field has substantial spatial inhomogeneities. The highly localized effects of diffusion at these surfaces are described with closed-form analytic functions instead of the spatial eigenmode expansions that are appropriate for lower-pressure cells.

Physical Review A•Aug 1, 1998•443 citations

Precision measurements of spin interactions with high density atomic vapors

Georgios Vasilakis

•Dec 1, 2011•42 citations

Spin-Exchange Shift and Narrowing of Magnetic Resonance Lines in Optically Pumped Alkali Vapors

W. Happer, Haoqin Tang

We observe very narrow (\ensuremath{\sim}200 Hz) magnetic resonance lines in alkali vapors with atomic densities much greater than usual and with cell dimensions much smaller than usual. The Zeeman resonance frequency is shifted downward by a large factor, but the spin-exchange broadening vanishes in the high-density limit. This new regime affords important new possibilities for investigating basic interactions in dense alkali vapors, and it also opens the way to miniaturized optically pumped devices.

Physical Review Letters•Jul 30, 1973•324 citations

End-resonance clock and all-photonic clock

Yuan‐Yu Jau, W. Happer, Fei Gong +2 more

The end-resonance clock uses strong hyperfine end transition to stabilize the frequency of the local oscillator. Comparing to the conventional 0-0 atomic clock, end resonance has very small spin-exchange broadening effect. The spin-exchange rate is proportional to the number density of the alkali-metal atoms. By using the end resonance, we are able to use very high dense vapor to obtain a much better signal to noise ratio. On the other hand, the end resonance suffers from the first-order magnetic field dependence. This problem, however, can be solved by simultaneously using a Zeeman end resonance to stabilize the magnetic field. Here, we report the most recent result of the end-resonance clock. In addition, we report a whole new technique, push-pull laser-atomic oscillator, which can be thought as all-photonic clock. This new clock requires no local oscillator. It acts like a photonic version of maser, which spontaneously generates modulated laser light and modulated voltage signals. The modulation serves as the clock signal, which is automatically locked to the ground-state hyperfine frequency of alkali-metal atoms.

Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE•Jan 11, 2008•1 citation

Research on Magnetic Field Modulation Coils for Manipulating Spin-Polarized Atoms

Teng Tian, Yanjie Zhang, Long Zhao +5 more

Lecture notes in electrical engineering•Jan 1, 2026•0 citations
We have completed a thorough study of masing action of hyperpolarized He-3 gas in inhomogeneous magnetic fields. The self interaction of the He-3 magnetization has a large effect on the maser gain. We have developed a simple new magnetic resonance method for investigating the interactions of Xe-129 spins with protons in polymers. We have shown that there are novel magnetic resonance transitions in alkali-metal vapors that have vanishing spin-exchange broadening in the limit of high spin polarization. Such transitions could be useful for miniaturized atomic clocks. We have shown that spin-axis interactions in triplet molecules are responsible for much of the spin destruction rate dense alkali-metal vapors.
Over the four year period covered by this grant, we have carried out extensive research involving polarized atoms and nuclei. Using laser optical pumping, high polarizations can be produced in alkali-metal vapors. From this starting point, angular momentum can be transferred to other atoms and nuclei through several different types of spin-exchange collisions. This powerful technique enables us to study a wide variety of spin interactions and spin related phenomena. Among the systems we work with are polarized nobel gases, which display extremely long spin-relaxation times that vary from several minutes to many weeks. The use of optical pumping and spin exchange has grown enormously over the past four years.
We present a comprehensive theory of nuclear spin polarization of 3He{}^{3}\mathrm{He}3He and 129Xe{}^{129}\mathrm{Xe}129Xe gases by spin-exchange collisions with optically pumped alkali-metal vapors. The most important physical processes considered are (1) spin-conserving spin-exchange collisions between like or unlike alkali-metal atoms; (2) spin-destroying collisions of the alkali-metal atoms with each other and with buffer-gas atoms; (3) electron-nuclear spin-exchange collisions between alkali-metal atoms and 3He{}^{3}\mathrm{He}3He or 129Xe{}^{129}\mathrm{Xe}129Xe atoms; (4) spin interactions in van der Waals molecules consisting of a Xe atom bound to an alkali-metal atom; (5) optical pumping by laser photons; (6) spatial diffusion. The static magnetic field is assumed to be small enough that the nuclear spin of the alkali-metal atom is well coupled to the electron spin and the total spin is very nearly a good quantum number. Conditions appropriate for the production of large quantities of spin-polarized 3He{}^{3}\mathrm{He}3He or 129Xe{}^{129}\mathrm{Xe}129Xe gas are assumed, namely, atmospheres of gas pressure and nearly complete quenching of the optically excited alkali-metal atoms by collisions with N2{\mathrm{N}}_{2}N2​ or H2{\mathrm{H}}_{2}H2​ gas. Some of the more important results of this work are as follows: (1) Most of the pumping and relaxation processes are sudden with respect to the nuclear polarization. Consequently, the steady-state population distribution of alkali-metal atoms is well described by a spin temperature, whether the rate of spin-exchange collisions between alkali-metal atoms is large or small compared to the optical pumping rate or the collisional spin-relaxation rates. (2) The population distributions that characterize the response to sudden changes in the intensity of the pumping light are not described by a spin temperature, except in the limit of very rapid spin exchange. (3) Expressions given for the radio-frequency (rf) resonance linewidths and areas can be used to make reliable estimates of the local spin polarization of the alkali-metal atoms. (4) Diffusion effects for these high-pressure conditions are mainly limited to thin layers at the cell surface and at internal resonant surfaces generated by radio-frequency magnetic fields when the static magnetic field has substantial spatial inhomogeneities. The highly localized effects of diffusion at these surfaces are described with closed-form analytic functions instead of the spatial eigenmode expansions that are appropriate for lower-pressure cells.
We observe very narrow (\ensuremath{\sim}200 Hz) magnetic resonance lines in alkali vapors with atomic densities much greater than usual and with cell dimensions much smaller than usual. The Zeeman resonance frequency is shifted downward by a large factor, but the spin-exchange broadening vanishes in the high-density limit. This new regime affords important new possibilities for investigating basic interactions in dense alkali vapors, and it also opens the way to miniaturized optically pumped devices.
The end-resonance clock uses strong hyperfine end transition to stabilize the frequency of the local oscillator. Comparing to the conventional 0-0 atomic clock, end resonance has very small spin-exchange broadening effect. The spin-exchange rate is proportional to the number density of the alkali-metal atoms. By using the end resonance, we are able to use very high dense vapor to obtain a much better signal to noise ratio. On the other hand, the end resonance suffers from the first-order magnetic field dependence. This problem, however, can be solved by simultaneously using a Zeeman end resonance to stabilize the magnetic field. Here, we report the most recent result of the end-resonance clock. In addition, we report a whole new technique, push-pull laser-atomic oscillator, which can be thought as all-photonic clock. This new clock requires no local oscillator. It acts like a photonic version of maser, which spontaneously generates modulated laser light and modulated voltage signals. The modulation serves as the clock signal, which is automatically locked to the ground-state hyperfine frequency of alkali-metal atoms.