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On quantum mechanical decay processes

Robert Grummt

Published Jan 1, 2014• 1 citation
Publisher

Abstract

This thesis is concerned with quantum mechanical decay processes and their mathematical description. It consists out of three parts: In the first part we look at Laser induced ionization, whose mathematical description is often based on the so-called dipole approximation. Employing it essentially means to replace the Laser's vector potential $\vec A(\vec r,t)$ in the Hamiltonian by $\vec A(0, t).$ Heuristically this is justified under usual experimental conditions, because the Laser varies only slowly in $\vec r$ on atomic length scales. We make this heuristics rigorous by proving the dipole approximation in the limit in which the Laser's length scale becomes infinite compared to the atomic length scale. Our results apply to $N$-body Hamiltonians. In the second part we look at alpha decay as described by Skibsted (Comm. Math. Phys. 104, 1986) and show that Skibsted's model satisfies an energy-time uncertainty relation. Since there is no self-adjoint time operator, the uncertainty relation for energy and time can not be proven in the same way as the uncertainty relation for position and momentum. To define the time variance without a self-adjoint time operator, we will use the arrival time distribution obtained from the quantum current. Our proof of the energy-time uncertainty relation is then based on the quantitative scattering estimates that will be derived in the third part of the thesis and on a result from Skibsted. In addition to that, we will show that this uncertainty relation is different from the well known {\it linewidth-lifetime relation}. The third part is about quantitative scattering estimates, which are of interest in their own right. For rotationally symmetric potentials having support in $[0,R_V]$ we will show that for $R\geq R_V$, the time evolved wave function $e^{-iHt}\psi$ satisfies \begin{align}\nonumber \|\1_R e^{-iHt}\psi\|_2^2\leq c_1t^{-1}+c_2t^{-2}+c_3t^{-3}+c_4t^{-4} \end{align} with explicit quantitative bounds on the constants $c_n$ in terms of the resonances of the $S$-Matrix. While such bounds on $\|\1_R e^{-iHt}\psi\|_2$ have been proven before, the quantitative estimates on the constants $c_n$ are new. These results are based on a detailed analysis of the $S$-matrix in the complex momentum plane, which in turn becomes possible by expressing the $S$-matrix in terms of the Jost function that can be factorized in a Hadamard product.

DOI
10.5282/edoc.16621

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This thesis is concerned with quantum mechanical decay processes and their mathematical description. It consists out of three parts: In the first part we look at Laser induced ionization, whose mathematical description is often based on the so-called dipole approximation. Employing it essentially means to replace the Laser's vector potential A⃗(r⃗,t)\vec A(\vec r,t)A(r,t) in the Hamiltonian by A⃗(0,t).\vec A(0, t).A(0,t). Heuristically this is justified under usual experimental conditions, because the Laser varies only slowly in r⃗\vec rr on atomic length scales. We make this heuristics rigorous by proving the dipole approximation in the limit in which the Laser's length scale becomes infinite compared to the atomic length scale. Our results apply to NNN-body Hamiltonians. In the second part we look at alpha decay as described by Skibsted (Comm. Math. Phys. 104, 1986) and show that Skibsted's model satisfies an energy-time uncertainty relation. Since there is no self-adjoint time operator, the uncertainty relation for energy and time can not be proven in the same way as the uncertainty relation for position and momentum. To define the time variance without a self-adjoint time operator, we will use the arrival time distribution obtained from the quantum current. Our proof of the energy-time uncertainty relation is then based on the quantitative scattering estimates that will be derived in the third part of the thesis and on a result from Skibsted. In addition to that, we will show that this uncertainty relation is different from the well known {\it linewidth-lifetime relation}. The third part is about quantitative scattering estimates, which are of interest in their own right. For rotationally symmetric potentials having support in [0,RV][0,R_V][0,RV​] we will show that for R≥RVR\geq R_VR≥RV​, the time evolved wave function e−iHtψe^{-iHt}\psie−iHtψ satisfies \begin{align}\nonumber |\1_R e^{-iHt}\psi|_2^2\leq c_1t^{-1}+c_2t^{-2}+c_3t^{-3}+c_4t^{-4} \end{align} with explicit quantitative bounds on the constants cnc_ncn​ in terms of the resonances of the SSS-Matrix. While such bounds on ∥\1Re−iHtψ∥2\|\1_R e^{-iHt}\psi\|_2∥\1R​e−iHtψ∥2​ have been proven before, the quantitative estimates on the constants cnc_ncn​ are new. These results are based on a detailed analysis of the SSS-matrix in the complex momentum plane, which in turn becomes possible by expressing the SSS-matrix in terms of the Jost function that can be factorized in a Hadamard product.
Although time measurements are routinely performed in laboratories, their theoretical description is still an open problem. Correspondingly, the status of the energy-time uncertainty relation is unsettled. In the first part of this work the necessity of positive operator valued measures (POVM) as descriptions of every quantum experiment is reviewed, as well as the suggestive role played by the probability current in time measurements. Furthermore, it is shown that no POVM exists, which approximately agrees with the probability current on a very natural set of wave functions; nevertheless, the choice of the set is crucial, and on more restrictive sets the probability current does provide a good arrival time prediction. Some ideas to experimentally detect quantum effects in time measurements are discussed. In the second part of the work the energy-time uncertainty relation is considered, in particular for a model of alpha decay for which the variance of the energy can be calculated explicitly, and the variance of time can be estimated. This estimate is tight for systems with long lifetimes, in which case the uncertainty relation is shown to be satisfied. Also the linewidth-lifetime relation is shown to hold, but contrary to the common expectation, it is found that the two relations behave independently, and therefore it is not possible to interpret one as a consequence of the other. To perform the mentioned analysis quantitative scattering estimates are necessary. To this end, bounds of the form ∥1Re−iHtψ∥22≤Ct−3\|1_Re^{-iHt}ψ\|_2^2 \leq C t^{-3}∥1R​e−iHtψ∥22​≤Ct−3 have been derived, where ψψψ denotes the initial state, HHH the Hamiltonian, RRR a positive constant, and CCC is explicitly known. As intermediate step, bounds on the derivatives of the SSS-matrix in the form $\|1_K S^{(n)}\|_\infty \leq C_{n,K} $ have been established, with n=1,2,3n=1,2,3n=1,2,3, and the constants Cn,KC_{n,K}Cn,K​ explicitly known.
We derive the expression for the energy uncertainty of the final state of a decay of an unstable quantum state prepared at initial time t=0t=0t=0. This expression is a function of the time ttt at which a measurement is performed to determine if the state has decayed and, if yes, in which one of the infinitely many possible final states. For large times the energy spread is, as expected, given by the decay width $\ensuremath{\Gamma}$ of the initial unstable state. However, if the measurement of the final state is performed at a time ttt comparable to (or smaller than) the mean lifetime of the state $1/\ensuremath{\Gamma}$, then the uncertainty in the energy of the final state is much larger than the decay width $\ensuremath{\Gamma}$. Namely, for short times an uncertainty of type 1/t1/t1/t dominates, while at long times the usual spread $\ensuremath{\Gamma}$ is recovered. Then we turn to a generic two-body decay process and describe the energy uncertainty of each of the two outgoing particles. We apply these formulas to the two-body decays of neutral and charged pions and to the spontaneous emission process of an excited atom. As the last step, we study a case in which the nonexponential decay is realized and show that for short times eventual asymmetric terms are enhanced in the spectrum.
The uncertainty principle is commonly regarded as a fundamental limitation ofquantum mechanics, often attributed directly to Heisenberg’s 1927 analysis.In this work, we revisit the original formulation of the principle and carefullydistinguish Heisenberg’s measurement–disturbance argument from the latermathematical uncertainty relations derived by Kennard, Robertson, andSchrödinger. We show that the standard variance-based formulation relies onthe prior introduction of fluctuation operators and ensemble averages, therebypresupposing statistical indeterminacy rather than deriving it from firstprinciples. From a physical perspective, Heisenberg’s argument is shown toreflect constraints imposed by invasive measurement techniques rather than auniversal prohibition on simultaneous knowledge of conjugate variables.Motivated by this distinction, we propose a conjecture that, in the absence ofmeasurement-induced energy transfer, the simultaneous determination ofposition and momentum may, in principle, be achievable. Our analysis suggeststhat quantum uncertainty, as traditionally formulated, encodes limitations ofcurrent observational methods rather than an intrinsic property of nature. \section{Heisenberg’s original observation and formulation (1927)} In his seminal 1927 paper \emph{Über den anschaulichen Inhalt der quantentheoretischen Kinematik und Mechanik} \cite{Heisenberg1927}, Werner Heisenberg sought to clarify the physical meaning of quantum mechanics rather than to establish a rigorous mathematical theorem. His analysis was based on thought experiments concerning the act of measurement, most notably the γ\gammaγ-ray microscope. Heisenberg argued that any attempt to localize a particle within a spatial region Δx\Delta xΔx requires radiation of wavelength comparable to Δx\Delta xΔx, which inevitably transfers an uncontrollable momentum Δp\Delta pΔp to the particle. As a consequence of this measurement-induced disturbance, he proposed that the product of the inaccuracies in position and momentum measurements satisfies a relation of the order\begin{equation}\Delta x\, \Delta p \sim h .\end{equation}Here, Δx\Delta xΔx and Δp\Delta pΔp denote operational measurement imprecisions arising from the interaction between the measuring apparatus and the system, rather than statistical variances of quantum observables. Heisenberg did not introduce operators, Hilbert space, or probability distributions, nor did he provide a formal inequality with a precise lower bound. The argument was explicitly heuristic and qualitative, emphasizing limitations imposed by the measurement process itself. Consequently, the original uncertainty principle was formulated as a statement about measurement disturbance and experimental resolution, not as a universal mathematical constraint on quantum states. \section{Standard mathematical proof of the position--momentum uncertainty relation} \subsection{Setup and definitions} Let H\mathcal{H}H be a Hilbert space and let ∣ψ⟩∈H|\psi\rangle \in \mathcal{H}∣ψ⟩∈H be anormalized state, ⟨ψ∣ψ⟩=1\langle \psi | \psi \rangle = 1⟨ψ∣ψ⟩=1. Let AAA and BBB beself-adjoint operators (observables) on a common dense domain containing∣ψ⟩|\psi\rangle∣ψ⟩, such that all expressions below are well-defined. Define expectation values\cite{Kennard1927,Robertson1929,Schrodinger1930,Ballentine1998,Sakurai1994}\begin{equation}\langle A \rangle := \langle \psi | A | \psi \rangle,\qquad\langle B \rangle := \langle \psi | B | \psi \rangle .\end{equation}Define the fluctuation (centered) operators\begin{equation}\Delta A := A - \langle A \rangle, \qquad \Delta B := B - \langle B \rangle .\end{equation}The variances are\begin{equation}\sigma_A^2 := \langle (\Delta A)^2 \rangle = \langle \psi | (\Delta A)^2 | \psi \rangle,\qquad\sigma_B^2 := \langle (\Delta B)^2 \rangle = \langle \psi | (\Delta B)^2 | \psi \rangle.\end{equation} \subsection{Key inequality: Cauchy--Schwarz in Hilbert space} Define vectors\begin{equation}|\phi\rangle := \Delta A |\psi\rangle, \qquad |\chi\rangle := \Delta B |\psi\rangle .\end{equation}By the Cauchy--Schwarz inequality,\begin{equation}\langle \phi|\phi\rangle \, \langle \chi|\chi\rangle \ge |\langle \phi|\chi\rangle|^2 .\end{equation}Compute each factor:\begin{equation}\langle \phi|\phi\rangle= \langle \psi| (\Delta A)^\dagger (\Delta A) |\psi\rangle= \langle \psi| (\Delta A)^2 |\psi\rangle= \sigma_A^2,\end{equation}and similarly ⟨χ∣χ⟩=σB2\langle \chi|\chi\rangle = \sigma_B^2⟨χ∣χ⟩=σB2​. Therefore\begin{equation}\sigma_A^2 \sigma_B^2 \ge \left| \langle \psi| \Delta A \Delta B |\psi\rangle \right|^2= |\langle \Delta A \Delta B \rangle|^2 .\label{eq:cs_step}\end{equation} \subsection{Robertson--Schr\"odinger decomposition} Decompose ΔAΔB\Delta A \Delta BΔAΔB into commutator and anticommutator parts:\begin{equation}\Delta A \Delta B=\frac{1}{2}\bigl[\Delta A,\Delta B\bigr]+\frac{1}{2}\bigl\{\Delta A,\Delta B\bigr\},\end{equation}where [X,Y]=XY−YX[X,Y]=XY-YX[X,Y]=XY−YX and {X,Y}=XY+YX\{X,Y\}=XY+YX{X,Y}=XY+YX. Taking expectation values gives\begin{equation}\langle \Delta A \Delta B \rangle=\frac{1}{2}\langle [\Delta A,\Delta B]\rangle+\frac{1}{2}\langle \{\Delta A,\Delta B\}\rangle .\label{eq:decomp_exp}\end{equation} Now note the following facts for self-adjoint A,BA,BA,B:\begin{itemize}\item The operator [ΔA,ΔB][\Delta A,\Delta B][ΔA,ΔB] is anti-self-adjoint, hence⟨[ΔA,ΔB]⟩\langle [\Delta A,\Delta B]\rangle⟨[ΔA,ΔB]⟩ is purely imaginary.\item The operator {ΔA,ΔB}\{\Delta A,\Delta B\}{ΔA,ΔB} is self-adjoint, hence⟨{ΔA,ΔB}⟩\langle \{\Delta A,\Delta B\}\rangle⟨{ΔA,ΔB}⟩ is real.\end{itemize}Therefore the two terms in \eqref{eq:decomp_exp} are orthogonal in the complex plane(real vs.\ imaginary), and we may write\begin{equation}|\langle \Delta A \Delta B \rangle|^2=\left(\frac{1}{2}|\langle [\Delta A,\Delta B]\rangle|\right)^2+\left(\frac{1}{2}\langle \{\Delta A,\Delta B\}\rangle\right)^2 .\label{eq:RS_identity}\end{equation} Substituting \eqref{eq:RS_identity} into \eqref{eq:cs_step} yields theSchr\"odinger uncertainty relation:\begin{equation}\boxed{\sigma_A^2 \sigma_B^2 \ge\left(\frac{1}{2}|\langle [\Delta A,\Delta B]\rangle|\right)^2+\left(\frac{1}{2}\langle \{\Delta A,\Delta B\}\rangle\right)^2}.\label{eq:schrodinger}\end{equation} Since constants commute with everything,\begin{equation}[\Delta A,\Delta B] = [A-\langle A\rangle,\; B-\langle B\rangle] = [A,B].\end{equation}Hence \eqref{eq:schrodinger} can be written as\begin{equation}\boxed{\sigma_A^2 \sigma_B^2 \ge\left(\frac{1}{2}|\langle [A,B]\rangle|\right)^2+\left(\frac{1}{2}\langle \{\Delta A,\Delta B\}\rangle\right)^2}.\end{equation} \subsection{Robertson inequality (weaker but widely quoted)} Dropping the nonnegative anticommutator term gives Robertson's inequality:\begin{equation}\boxed{\sigma_A \sigma_B \ge \frac{1}{2}|\langle [A,B]\rangle|}.\label{eq:robertson}\end{equation} \subsection{Specialization to position and momentum} Take A=xA=xA=x and B=pB=pB=p (one spatial dimension), with canonical commutation relation\begin{equation}[x,p] = i\hbar.\end{equation}Therefore,\begin{equation}|\langle [x,p]\rangle|= |\langle i\hbar \rangle|= \hbar,\end{equation}and \eqref{eq:robertson} yields the standard position--momentum uncertainty relation\begin{equation}\boxed{\sigma_x \sigma_p \ge \frac{\hbar}{2}.}\end{equation} \subsection{Condition for equality (minimum-uncertainty states)} Equality in Cauchy--Schwarz holds iff the vectors are linearly dependent:\begin{equation}\Delta A|\psi\rangle = \lambda \, \Delta B|\psi\rangle\quad \text{for some complex } \lambda.\end{equation}For A=xA=xA=x and B=pB=pB=p, this condition leads (in the xxx-representation) to afirst-order differential equation whose normalized solutions are Gaussianwave packets. Hence Gaussian states saturate σxσp=ℏ/2\sigma_x \sigma_p = \hbar/2σx​σp​=ℏ/2. \subsection{Definition of fluctuation operators and their role in the uncertainty relation} In the mathematical formulation of quantum uncertainty developed after Heisenberg’s original 1927 heuristic proposal, the quantities entering the uncertainty relation were redefined in statistical terms. In particular, in his 1929 paper, Robertson introduced the operators. \noindent\textbf{Critical observation.}The introduction of the fluctuation operators \begin{center}\fcolorbox{red}{white}{ΔA=A−⟨A⟩,ΔB=B−⟨B⟩\Delta A = A - \langle A \rangle,\qquad\Delta B = B - \langle B \rangleΔA=A−⟨A⟩,ΔB=B−⟨B⟩}\end{center} \textbf{constitutes a nontrivial mathematicalassumption rather than a derived physical necessity. In the Robertson--Schrödinger formalism, the uncertainty of observables is defined \emph{a priori} in terms ofstatistical deviations from expectation values, thereby presupposing the verynotion of indeterminacy that the uncertainty principle is intended to justify.In other words, the operators ΔA\Delta AΔA and ΔB\Delta BΔB encode uncertainty byconstruction, since their variances measure ensemble spread relative to a mean.The subsequent derivation of a lower bound on σAσB\sigma_A \sigma_BσA​σB​ thereforeestablishes a constraint on these predefined statistical quantities, rather than demonstrating that physical observables must be uncertain from first principles.Consequently, the uncertainty relation obtained in this manner is logicallyconditional upon the initial choice of variance-based definitions and does not,by itself, prove the existence of intrinsic measurement indeterminacy or disturbance in individual quantum events.} \textit{They actully assumed and defined the spread and uncertainity initial in both the quantities and proved the uncertainity principle.} where AAA and BBB are self-adjoint operators representing observables and⟨A⟩=⟨ψ∣A∣ψ⟩\langle A \rangle = \langle \psi | A | \psi \rangle⟨A⟩=⟨ψ∣A∣ψ⟩ denotes the expectationvalue in a normalized quantum state ∣ψ⟩|\psi\rangle∣ψ⟩ \cite{Robertson1929}.These operators describe deviations of observables from their mean valuesand are introduced in direct analogy with classical statistical fluctuations.The corresponding variances,σA2=⟨(ΔA)2⟩\sigma_A^2 = \langle (\Delta A)^2 \rangleσA2​=⟨(ΔA)2⟩ andσB2=⟨(ΔB)2⟩\sigma_B^2 = \langle (\Delta B)^2 \rangleσB2​=⟨(ΔB)2⟩,measure the statistical spread of measurement outcomes over an ensembleof identically prepared systems