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AIP conference proceedings

Singularities in the complex temperature plane at the first order phase transitions and critical points

Koo-Chul Lee

Published Jan 1, 2000• 1 citation
Publisher
DOI
10.1063/1.1291573

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At low temperature, a thermodynamic system undergoes a phase transition when a physical parameter passes through a singularity point of the free energy. This corresponds to the formation of a new order. At high temperature, thermal fluctuations destroy the order. Correspondingly, the free energy is a smooth function of the physical parameter and singularities only occur at complex values of the parameter. Since a complex valued parameter is unphysical, no phase transitions are expected when the physical parameter is varied. Here we show that the quantum evolution of a system, initially in thermal equilibrium and driven by a designed interaction, is equivalent to the partition function of a complex parameter. Therefore, we can access the complex singularity points of thermodynamic functions and observe phase transitions even at high temperature. We further show that such phase transitions in the complex plane are related to topological properties of the renormalization group flows of the complex parameters. This result makes it possible to study thermodynamics in the complex plane of physical parameters.
The critical temperature and the thermal scaling exponent of the square-lattice Blume-Capel model are obtained as functions of fugacity by calculating the partition function zeros in the complex temperature plane of the square-lattice Blume-Capel antiferromagnet for the first time. The thermal scaling exponent y t determines the specific-heat critical exponent and the correlation-length critical exponent. The value of y t = 2 indicates a strong first-order phase transition in two dimensions whereas y t = 1 corresponds to an Ising-class second-order phase transition. The full spectrum (from y t = 2 to y t = 1) of the thermal scaling exponent for the square-lattice Blume-Capel model is evaluated for the first time. The phase diagram of the square-lattice Blume-Capel model, including the tricritical point, is also obtained, and it is compared with other results in the literature.
The fermionic version of the two-dimensional Ising model in a uniform magnetic field is studied. Its approximate but rather accurate solution was obtained recently in a variational procedure based on the BCS ansatz for the ground state. Here, this solution is continued analytically into the complex H-plane in the vicinity of the origin. In the ferromagnetic phase an essential singularity in the free-energy is observed at the point H=0 of the type predicted by the droplet condensation theory. Simple phenomenological estimates for the radius of the critical droplet and for the rate of decay of metastable states are confirmed by microscopic calculations.