aqora

Threshold resonances in ultracold chemical reactions

Robin C ot 'e, I. Simbotin, Subhas Ghosal

Bulletin of the American Physical SocietyJun 7, 20120 citations

Geometric Phase and Interference Effects in Ultracold Chemical Reactions

N. Balakrishnan, Brian K. Kendrick

Progress in theoretical chemistry and physicsJan 1, 20180 citations

Effect of p-wave resonances on the threshold behavior of ultracold chemical reactions

I. Simbotin, J. Wang, Subhas Ghosal

Bulletin of the American Physical SocietyJun 6, 20130 citations

Dynamics of chemical reactions at cold and ultracold temperatures

Philippe F. Weck, N. Balakrishnan

The main characteristics of cold and ultracold chemical reactions are reviewed through the illustrative study of the O(3P) + H2 reaction dynamics. Using separate analytic representations of the lowest H2O(3A'') electronic state which differ essentially by their descriptions of long-range forces, quantum-mechanical scattering calculations show the crucial role played by the van der Waals interaction potential in chemical reactions at low temperatures. Furthermore, the presence of zero-energy resonances is found to significantly enhance chemical reactivity in the ultracold regime. At translational energies comparable to the well depth of the van der Waals potential, initial-state-selected probabilities and excitation functions are characterized by Feshbach resonances arising from the decay of quasibound states supported by the van der Waals well in the entrance channel of the reaction.The main characteristics of cold and ultracold chemical reactions are reviewed through the illustrative study of the O(3P) + H2 reaction dynamics. Using separate analytic representations of the lowest H2O(3A'') electronic state which differ essentially by their descriptions of long-range forces, quantum-mechanical scattering calculations show the crucial role played by the van der Waals interaction potential in chemical reactions at low temperatures. Furthermore, the presence of zero-energy resonances is found to significantly enhance chemical reactivity in the ultracold regime. At translational energies comparable to the well depth of the van der Waals potential, initial-state-selected probabilities and excitation functions are characterized by Feshbach resonances arising from the decay of quasibound states supported by the van der Waals well in the entrance channel of the reaction.

Journal of Physics B Atomic Molecular and Optical PhysicsSep 25, 20069 citations

Importance of long-range interactions in chemical reactions at cold and ultracold temperatures

Philippe F. Weck, N. Balakrishnan

We review the recent progress achieved in the theoretical description of chemical reactions at low temperatures. In particular, we discuss the crucial role played by the van der Waals interaction potential in quantum-mechanical scattering calculations of atom–diatom collisions in the cold and ultracold regimes, where abstraction reactions proceed by tunnelling. The importance of zero-energy resonances in enhancing the reactivity in the zero-temperature limit is assessed. The impact of Feshbach resonances associated with the decay of metastable states of van der Waals complexes on reactive scattering is addressed through a series of examples. Finally, we discuss the sensitivity of the reaction dynamics to the topology of the van der Waals well. Importance of long-range interactions in chemical reactions at cold and ultracold temperaturesAll authorsPhilippe F. Weck & N. Balakrishnanhttps://doi.org/10.1080/01442350600791894Published online:22 February 2007Table Download CSVDisplay TableWe review the recent progress achieved in the theoretical description of chemical reactions at low temperatures. In particular, we discuss the crucial role played by the van der Waals interaction potential in quantum-mechanical scattering calculations of atom–diatom collisions in the cold and ultracold regimes, where abstraction reactions proceed by tunnelling. The importance of zero-energy resonances in enhancing the reactivity in the zero-temperature limit is assessed. The impact of Feshbach resonances associated with the decay of metastable states of van der Waals complexes on reactive scattering is addressed through a series of examples. Finally, we discuss the sensitivity of the reaction dynamics to the topology of the van der Waals well. Importance of long-range interactions in chemical reactions at cold and ultracold temperaturesAll authorsPhilippe F. Weck & N. Balakrishnanhttps://doi.org/10.1080/01442350600791894Published online:22 February 2007Table Download CSVDisplay Table

International Reviews in Physical ChemistryJul 1, 2006105 citations

Feshbach Resonances in Ultracold Gases

Eite Tiesinga, Cheng Chin, Rudolf Grimm +1 more

APSMay 1, 200911 citations

Interference of Feshbach and zero-energy resonances in ultracold chemical reactions

Related papers

Interference of Feshbach and zero-energy resonances in ultracold chemical reactions

Related papers