After a Rydberg wave packet forms, it is known to undergo a series of collapses and revivals within a time period called the revival time
trev, at the end of which it resembles its original shape. We study the behavior of Rydberg wave packets on time scales much greater than
trev. We find that after a few revival cycles the wave packet ceases to reform at multiples of the revival time. Instead, a new series of collapses and revivals commences, culminating after a time period
tsr≫trev with the formation of a wave packet that more closely resembles the initial packet than does the full revival at time
trev. Furthermore, at times that are rational fractions of
tsr, we show that the motion of the wave packet is periodic with periodicities that can be expressed as fractions of the revival time
trev. These periodicities indicate a new type of fractional revival, occurring for times much greater than
trev. We also examine the effects of quantum defects and laser detunings on the revival structure of Rydberg wave packets for alkali-metal atoms.
The revival structure and evolution of Rydberg wave packets are studied on a time scale much greater than the revival time
trev. We find a new level of revival structure and periodic motion different from that of the known fractional revivals. The new sequence of revivals culminates with the formation of a wave packet that more closely resembles the initial packet than does the full revival at time
trev. We refer to such a revival as a superrevival. We also show that an initial radial wave packet may be described as a type of squeezed state known as a radial squeezed state. Our results apply not only for hydrogenic wave packets, but for wave packets in alkali-metal atoms as well in the context of quantum defect theory.
This paper begins with an examination of the revival structure and long-term evolution of Rydberg wave packets for hydrogen. We show that after the initial cycle of collapse and fractional or full revival, which occurs on the time scale
trev, a new sequence of revivals begins. We find that the structure of the new revivals is different from that of the fractional revivals. The new revivals are characterized by periodicities in the motion of the wave packet with periods that are fractions of the revival time scale
trev. These long-term periodicities result in the autocorrelation function at times greater than
trev having a self-similar resemblance to its structure for times less than
trev. The new sequence of revivals culminates with the formation of a single wave packet that more closely resembles the initial wave packet than does the full revival at time
trev, i.e., a superrevival forms. Explicit examples of the superrevival structure for both circular and radial wave packets are given. We then study wave packets in alkali-metal atoms, which are typically used in experiments. The behavior of these packets is affected by the presence of quantum defects that modify the hydrogenic revival time scales and periodicities. Their behavior can be treated analytically using supersymmetry-based quantum-defect theory. We illustrate our results for alkali-metal atoms with explicit examples of the revival structure for radial wave packets in rubidium.