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Bulletin of the American Physical Society

Diode Laser Excitation of Rydberg Lithium Atoms for Collision Studies.

Paul Oxley, J.J. Daly

Published May 29, 2008• 0 citations
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We transfer the frequency stability from a diode laser, which was locked to Doppler-free saturation absorption resonance in lithium vapor cell, to a tunable Ti-sapphire laser. We get the laser linewidth < 100 kHz/100 ms and absolute frequency stability ±0.5 MHz. The uv laser system which included the stabilized Ti-sapphire laser and frequency doubler has output optical beam with power near 100 mW and wavelength 350 nm. This uv laser system will be used for excitation and study of Rydberg states in lithium atoms.
This thesis discusses an approach to excite potassium atoms to very highly excited states (Rydberg states), and then tune their energy levels to induce resonant collisions between atoms. Potassium gas is super-cooled to 1 mK and confined to a small volume in a magneto-optical trap. A 405 nm laser diode, electronically locked to a potassium vapor cell via Doppler free spectroscopy, excites these atoms from the 4s1/2 state (ground state) to the 5p3/2 state. A 978 nm laser then excites the 5p3/2 to nd3/2 or nd5/2 transition, creating Rydberg atoms. Since there is no ground state reference for this transition, an alternative method must be used to lock the laser's frequency. A scanning transfer cavity lock transfers the stability of a 632 nm HeNe reference laser to the unstable 978 nm laser diode by passing both lasers through a Fabry-Perot interferometer. Once Rydberg atoms have been created, their energy levels are tuned with an external electric field so that collisions between atoms cause resonant atomic transitions to different Rydberg states. The Rydberg atoms are ionized with a second, stronger electric field, and detected by microchannel plate detectors. Rydberg atoms with different principal quantum numbers ionize at different electric field strengths, so a successful collision signal has multiple peaks from the microchannel plates.