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Progress in theoretical chemistry and physics

Spatially-Dependent-Mass Schrödinger Equations with Morse Oscillator Eigenvalues: Isospectral Potentials and Factorization Operators

Gerardo Ovando, José Juan Peña, J. Morales

Published Sep 17, 2011• 0 citations
Publisher
DOI
10.1007/978-94-007-2076-3_2

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Abstract Quantum chemical systems with a position‐dependent mass have attracted the attention due to their relevance in describing the features of many microstructures of current interest. In this work, the point canonical transformation method applied to Schrödinger equations with a position‐dependent mass (SEPDM) is presented. Essentially, the proposal is aimed to transform the Schrödinger equation with a position‐dependent mass into a standard Schrödinger‐like equation for constant mass in such a way that the position‐dependent mass distribution (PDMD) becomes incorporated into the effective potential. As an useful application of the proposal, it is considered as effective potential the one‐dimensional harmonic oscillator potential model, which leads to those isospectral potentials related to different forms of PDMD. For example, the exactly solvable isospectral potentials involved in the SEPDM for some PDMD such as , , , , , xα, and , are worked out explicitly including their raising and lowering operators that factorize the SEPDM for each PDMD allowing HO eigenvalues. However, the proposal is general and can be straightforwardly applied to other effective potential models as well as other PDMD that could be useful in quantum chemical applications. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008

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The harmonic oscillator and the position dependent mass Schrodinger equation: isospectral partners and factorization operators

J. Morales, Gerardo Ovando, José Juan Peña +4 more

One of the most important scientific contributions of Professor Marcos Moshinsky has been his study on the harmonic oscillator in quantum theory vis à vis the standard Schrödinger equation with constant mass [1].However, a simple description of the motion of a particle interacting with an external environment such as happen in compositionally graded alloys consist of replacing the mass by the so-called effective mass that is in general variable and dependent on position.Therefore, honoring in memoriam Marcos Moshinsky, in this work we consider the position-dependent mass Schrodinger equations (PDMSE) for the harmonic oscillator potential model as former potential as well as with equi-spaced spectrum solutions, i.e. harmonic oscillator isospectral partners.To that purpose, the point canonical transformation method to convert a general second order differential equation (DE), of Sturm-Liouville type, into a Schrödinger-like standard equation is applied to the PDMSE.In that case, the former potential associated to the PDMSE and the potential involved in the Schrödinger-like standard equation are related through a Riccati-type relationship that includes the equivalent of the Witten superpotential to determine the exactly solvable positions-dependent mass distribution (PDMD) m(x).Even though the proposed approach is exemplified with the harmonic oscillator potential, the procedure is general and can be straightforwardly applied to other DEs.

AIP conference proceedings•Jan 1, 2010•0 citations
Abstract Quantum chemical systems with a position‐dependent mass have attracted the attention due to their relevance in describing the features of many microstructures of current interest. In this work, the point canonical transformation method applied to Schrödinger equations with a position‐dependent mass (SEPDM) is presented. Essentially, the proposal is aimed to transform the Schrödinger equation with a position‐dependent mass into a standard Schrödinger‐like equation for constant mass in such a way that the position‐dependent mass distribution (PDMD) becomes incorporated into the effective potential. As an useful application of the proposal, it is considered as effective potential the one‐dimensional harmonic oscillator potential model, which leads to those isospectral potentials related to different forms of PDMD. For example, the exactly solvable isospectral potentials involved in the SEPDM for some PDMD such as , , , , , xα, and , are worked out explicitly including their raising and lowering operators that factorize the SEPDM for each PDMD allowing HO eigenvalues. However, the proposal is general and can be straightforwardly applied to other effective potential models as well as other PDMD that could be useful in quantum chemical applications. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008
One of the most important scientific contributions of Professor Marcos Moshinsky has been his study on the harmonic oscillator in quantum theory vis à vis the standard Schrödinger equation with constant mass [1].However, a simple description of the motion of a particle interacting with an external environment such as happen in compositionally graded alloys consist of replacing the mass by the so-called effective mass that is in general variable and dependent on position.Therefore, honoring in memoriam Marcos Moshinsky, in this work we consider the position-dependent mass Schrodinger equations (PDMSE) for the harmonic oscillator potential model as former potential as well as with equi-spaced spectrum solutions, i.e. harmonic oscillator isospectral partners.To that purpose, the point canonical transformation method to convert a general second order differential equation (DE), of Sturm-Liouville type, into a Schrödinger-like standard equation is applied to the PDMSE.In that case, the former potential associated to the PDMSE and the potential involved in the Schrödinger-like standard equation are related through a Riccati-type relationship that includes the equivalent of the Witten superpotential to determine the exactly solvable positions-dependent mass distribution (PDMD) m(x).Even though the proposed approach is exemplified with the harmonic oscillator potential, the procedure is general and can be straightforwardly applied to other DEs.